D01.35 - Solvents, Plasticizers, and Chemical Intermediates

ABSTRACT
This specification covers isophorone volatile solvents used in paints, varnishes, lacquers, and related products. Isoprophone should conform to the specified requirements on apparent specific gravity, color, distillation, purity, acidity as acetic acid, and water content.
SCOPE
1.1 This specification covers isophorone2 (98 % grade) for use in paint, varnish, lacquer, and related products.  
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For specific hazard information and guidance, see the supplier’s Safety Data Sheet for materials listed in this specification.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method is useful for determining low levels of acidity, below 0.05 %, in organic compounds and hydrocarbon mixtures. The total acidity is calculated as acetic acid or milligrams of sodium hydroxide per gram of sample.  
4.2 Acidity may be present as a result of contamination, decomposition during storage or distribution, or manufacture. This test method may be used in assessing compliance with a specification.
SCOPE
1.1 This test method covers the determination of total acidity as acetic acid, in concentrations below 0.05 %, in organic compounds and hydrocarbon mixtures used in paint, varnish, and lacquer solvents and diluents. It is known to be applicable to such mixtures as low molecular weight saturated and unsaturated alcohols, ketones, ethers, esters, hydrocarbon diluents, naphtha, and other light distillate petroleum fractions.  
1.2 For purposes of determining conformance of an observed value or a calculated value using this test method to relevant specifications, test result(s) shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.4 For specific hazard information and guidance consult supplier’s Safety Data Sheet.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers dipropylene glycol monomethyl ether (DPM). Dipropylene glycol monomethyl ether shall conform to the requirements specified for the following: (1) assay content, (2) distillation range defined by the initial boiling point and dry point, (3) apparent specific gravity, (4) platinum-cobalt scale color, (5) water content, and (6) acidity (free acid as acetic acid). The sampling and test methods to determine conformance to the specified properties are given.
SCOPE
1.1 This specification covers dipropylene glycol monomethyl ether (DPM).  
Note 1: Dipropylene glycol monomethyl ether (DPM) is a mixture of isomers, the predominant isomer being 1-(2-methoxy-1-methylethoxy)-2-propanol.  
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For specific hazard information and guidance, consult the supplier’s Safety Data Sheet for materials listed in this standard.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method provides a measurement of acidity (as formic acid) in formaldehyde solutions. The results of these measurements can be used for specification acceptance.
SCOPE
1.1 This test method covers the determination of the acidity of commercially available formaldehyde solutions.  
1.2 For purposes of determining conformance of an observed or a calculated value using this test method to relevant specifications, test result(s) shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For hazard information and guidance, see the supplier’s Safety Data Sheet.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Section 7.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification establishes the properties and requirements for ethyl acrylate for use in paint, varnish, lacquer, and related products. Specimens shall be sampled, undergo chemical tests, and conform accordingly to purity, water content, color, acidity, and methyl ether of hydroquinone content requirements.
SCOPE
1.1 This specification covers ethyl acrylate (99 % grade) for use in paint, varnish, lacquer, and related products.  
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For specification hazard information and guidance, see the supplier’s Safety Data Sheet for materials listed in this specification.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in 4.1.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers glacial acrylic acid (99.0% grade) for use in paint, varnish, lacquer and related products. The properties of the material shall be determined in accordance with the following test methods: purity; water; color; inhibitor; and dimer.
SCOPE
1.1 This specification covers glacial acrylic acid2 (99.0 % grade) for use in paint, varnish, lacquer and related products.  
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For hazard information and guidance, see the supplier’s Safety Data Sheet.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 6.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This procedure is designed to determine the purity of the two ketones, methyl isoamyl ketone and methyl amyl ketone, and to obtain the concentration of their various impurities, several of which are critical in the application of these solvents.
SCOPE
1.1 This test method covers the determination of the purity of methyl amyl ketone and methyl isoamyl ketone. In addition, the method determines total ketones and various impurities which may include acetone, isopropyl alcohol, methyl propyl ketone, methyl isobutyl ketone, methyl butyl ketone, methyl isobutyl carbinol, mesityl oxide, methyl isoamyl ketone, methyl butyl carbinol, methyl amyl ketone, and diisobutyl ketone.  
1.2 Water and acid cannot be determined by this test method. They must be determined by other appropriate ASTM procedures, and the results used to normalize the chromatographic data.  
1.3 For purposes of determining conformance of an observed or a calculated value using this test method to relevant specifications, test result(s) shall be rounded “off to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 For hazard information and guidance, see the supplier’s Safety Data Sheet.  
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method provides a measurement of alkalinity in acetone. The results of this measurement can be used for specification acceptance.
SCOPE
1.1 This test method covers the determination in acetone of alkalinity calculated as ammonia (NH3).  
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For specific hazard information and guidance, consult the supplier’s Safety Data Sheet.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Section 7.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 Water-insoluble materials present in a solvent expected to be completely water miscible may interfere with many uses of the solvent. This test method provides a measure of the miscibility of water-soluble solvents with a polar medium-water. It also provides a qualitative indication of the presence or absence of water-immiscible contaminants.  
4.2 The results of this test method may be used in assessing compliance with a specification. Prior to agreeing to this test method as the basis of a specification requirement, it may be desirable that the interpretation of what constitutes cloudiness or turbidity be agreed upon between the supplier and the purchaser.
SCOPE
1.1 This test method covers the determination of the miscibility of water-soluble solvents with water. While written specifically for testing acetone, isopropyl alcohol (isopropanol), and methyl alcohol (methanol), the method is suitable for testing most water-soluble solvents.  
1.2 This test method serves to detect water-immiscible contaminants qualitatively; the level of detection of these impurities varies widely with both the type of solvent and the type of impurity.  
1.3 The level of detection of water-insoluble materials depends upon the solvent tested and the type of impurity or impurities present, that is paraffin, olefin, aromatic, high molecular weight alcohol, or ketone, etc. There is, therefore, no specific level of impurity detected by this procedure.  
Note 1: This test method is normally performed at ambient, but other temperatures may be used as specified by the consumer and supplier.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 For specific hazard information and guidance, consult the supplier’s Safety Data Sheet for materials listed in this test method.  
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification details the properties and requirements for isobutyl acetate. The specimens shall be sampled, go through chemical tests and conform accordingly to specified values of the following requirements: apparent specific gravity; color (Pt-Co units) distillation (initial boiling point and dry point); nonvolatile matter content; water content; acidity (free acid as acetic acid); and purity.
SCOPE
1.1 This specification covers isobutyl acetate (95 % grade).  
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For specific hazard information and guidance, see the supplier’s Safety Data Sheet for material listed in this specification.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method provides a measurement of commonly found impurities in commercially available methyl isobutyl ketone. The measurement of these impurities and the results thereof can individually or when totaled and subtracted from 100 (assay) be used for specification acceptance.
SCOPE
1.1 This test method covers the determination of the purity of methyl isobutyl ketone (MIBK) by gas chromatography and in addition provides a means for measuring certain impurities such as methyl isobutyl carbinol which are of interest. Impurities such as water and acidity are measured by other appropriate ASTM procedures and the results are used to normalize the chromatographic value.  
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the round-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 For specific hazard information and guidance, see the supplier’s Safety Data Sheet for the materials listed in this test method.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 The gas chromatographic determination of the boiling point distribution of hydrocarbon solvents can be used as an alternative to conventional distillation methods for control of solvents quality during manufacture, and specification testing.  
5.2 Boiling point distribution data can be used to monitor the presence of product contaminants and compositional variation during the manufacture of hydrocarbon solvents.  
5.3 Boiling point distribution data obtained by this test method are not equivalent to those obtained by Test Methods D86, D850, D1078, D2887, D2892, and D3710.
SCOPE
1.1 This test method covers the determination of the boiling point distribution of hydrocarbon solvents by capillary gas chromatography. This test method is limited to samples having a minimum initial boiling point of 37 °C (99 °F), a maximum final boiling point of 285 °C (545 °F), and a boiling range of 5 °C to 150 °C (9 °F to 270 °F) as measured by this test method.  
1.2 For purposes of determining conformance of an observed or calculated value using this test method to relevant specifications, test result(s) shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are standard. The values given in parentheses are for information purposes only.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers glacial acetic acid for use in paint, varnish, lacquer, and related products. Glacial acetic acid shall be tested for purity, freezing point, color, water content, iron content, acetaldehyde content, and formic acid content, and shall conform to the requirements of the specification. Test methods, sampling, and packaging shall be in accordance with ASTM standard methods.
SCOPE
1.1 This specification covers glacial (99.8 %) acetic acid for use in paint, varnish, lacquer, and related products.  
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 For specific hazard information and guidance, see the supplier’s Safety Data Sheet for materials listed in this specification.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 The comparative odor characteristics can be used, combined with other tests, for product identification and assessing compliance with a specification.  
3.2 The residual odor characteristics can be used to judge the presence of relatively nonvolatile materials that may be associated with manufacture or contamination during distribution. Since volatile solvents and diluents are used in a wide variety of chemical processes and residual materials may affect the efficiency of such processes, this test method provides a comparative test for manufacturing control and assessing compliance with a specification.
SCOPE
1.1 This test method covers a comparative procedure for observing the characteristic and residual odors of volatile organic solvents and diluents to determine their odor acceptability in a solvent system.  
1.2 It is not intended that this test method be employed to determine subtle odor differences between materials or to determine odor intensity.  
1.3 It is recommended that this test method not be employed to determine the residual odor of a liquid if its time for evaporation to dryness at room temperature exceeds 30 min or as agreed upon.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 4.  
1.6 For specific hazard information, see the supplier's Material Safety Data Sheet (MSDS).  
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 VAM is an organic vinyl ester compound. This colorless liquid is the precursor to polyvinyl acetate, an important industrial polymer. VAM may be subject to rapid spontaneous polymerization if the inhibitor is not present or becomes depleted during prolonged storage.  
4.2 VAM is typically shipped with a HQ inhibitor as free radical scavenger. VAM should be evaluated to ensure that appropriate systems (for example, temperature and inhibitor quantity) are assured during storage, transportation, and getting prolonged shelf life.  
4.3 Most VAM shipped from the manufacturer will contain an inhibitor, typically 3 to 5 ppm HQ for regional shipments and up to 25 ppm HQ for long-range shipments.
SCOPE
1.1 This test method covers the determination of hydroquinone (HQ) in colorless vinyl acetate monomer (VAM). This test method is applicable to the determination of HQ in the concentration range from 1 to 25 ppm.  
1.2 For purposes of determining conformance of an observed or a calculated value using this test method to relevant specifications, test result(s) shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit in accordance with Practice E29.  
1.3 For ensuring safety, hazard information and guidance, follow the manufacturer’s material safety data sheet.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 Benzene is classed as a toxic and carcinogenic material. A knowledge of the concentration of this compound may be an aid in evaluating the possible health hazards to persons handling and using hydrocarbon solvents, but this test method is not intended to evaluate such hazards.
SCOPE
1.1 This test method covers the determination by gas chromatography of benzene at levels from 0.01 to 1 volume % in hydrocarbon solvents.
Note 1: For benzene levels lower than 0.01 volume %, use Test Method D6229.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 For purposes of determining conformance of an observed or a calculated value using this test method to relevant specifications, test result(s) shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.4 For hazard information and guidance, see the supplier's Material Safety Data Sheet. For specific hazard statements, see Section 7.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers high-gravity glycerin (98.7 weight%, minimum) for use in the manufacture of alkyd and other synthetic resins. The following properties of glycerin shall be determined: color, Pt-Co scale, sulfate ash content(weight%), and acid value.
SCOPE
1.1 This specification covers high-gravity glycerin (98.7 weight %, minimum) for use in the manufacture of alkyd and other synthetic resins.  
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value, shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.4 For specific hazard information and guidance, see the supplier's Material Safety Data Sheet for materials listed in this specification.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers hydrocarbon solvents, normally petroleum distillates, used in coatings and dry-cleaning industries. These solvents are also known as mineral spirits and as Stoddard solvents when used in dry cleaning. The following are the types of mineral spirits: Type I, Type II, Type III, Type IV, Class A, Class B, and Class C. The physical and chemical properties of mineral spirits shall conform to the requirements specified for: aromatic content, commercial reference, appearance, flash point, color, kauri-butanol value, bromine number, odor, doctor test, distillation, residue for distillation, copper corrosion, and apparent specific gravity. These properties shall be tested with the specified test methods.
SCOPE
1.1 This specification covers four types of hydrocarbon solvents, normally petroleum distillates, used primarily in the coatings and dry-cleaning industries. “Mineral spirits” is the most common name for these solvents. They are also called “Stoddard Solvents” when used for dry cleaning.  
1.2 For specific hazard information and guidance, see the supplier's Material Safety Data Sheet for materials listed in this specification.  
1.3 The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.  
1.4 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.5 The following hazard caveat pertains only to the test method portion, 6.1.10, of this specification. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers methyl isobutyl ketone (99.0 % grade). The properties specified for methyl isobutyl ketone shall be determined in accordance with the following test methods: apparent specific gravity; color; distillation range; nonvolatile matter; odor; water; acidity; and alcohol and purity.
SCOPE
1.1 This specification covers methyl isobutyl ketone (99.0 % grade).  
1.2 For specific hazard information and guidance, see the supplier's Material Safety Data Sheet for materials listed in this specification.  
1.3 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers the properties and requirements for 50 % uninhibited formaldehyde and 37 % uninhibited and inhibited formaldehyde. Specimens shall be suitably sampled and tested, and shall meet the specified values of the following properties: apparent specific gravity; formaldehyde content; acidity; color (Pt-Co scale); iron content; methanol content; and appearance.
SCOPE
1.1 This specification covers 50 % uninhibited formaldehyde and 37 % uninhibited and inhibited formaldehyde.  
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For specific hazard information and guidance, see the supplier's Material Safety Data Sheet for materials listed in this specification.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method provides a measurement of formaldehyde content (assay) of formaldehyde solutions. The results of these measurements can be used for specification acceptance.
SCOPE
1.1 This test method covers the determination of the formaldehyde content of commercially available formaldehyde solutions ranging in concentration from 36 to 55 weight %.  
1.2 For purposes of determining conformance of an observed value or a calculated value using this test method to relevant specifications, test result(s) shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For hazard information and guidance, see the supplier's Material Safety Data Sheet.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 Volatile solvents are used in a variety of chemical processes which may be affected by water. Therefore, this test method provides a test procedure for assessing compliance with a specification.
SCOPE
1.1 This test method covers the determination of water in volatile solvents and chemical intermediates used in paint, varnish, lacquer, and related products.  
1.2 This test method is not applicable in the presence of mercaptans, peroxides, or appreciable quantities of aldehydes or amines.  
1.3 For purposes of determining conformance of an observed or a calculated value using this test method to relevant specifications, test result(s) shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 For hazard information and guidance, see the supplier’s Material Safety Data sheet.  
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification establishes the properties and requirements for various grades of n-butyl acetate suitable for use as solvents in paint and related coatings. Specimens shall be sampled and tested as appropriate, and shall adhere accordingly to specified values for purity, alcohol content, color (Pt-Co units), distillation range, nonvolatile matter content, odor, water content, acidity, and apparent specific gravity.
SCOPE
1.1 This specification covers the various grades of n-butyl acetate suitable for use as solvents in paint and related coatings.  
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For specific hazard information and guidance, see the supplier's Material Safety Data Sheet for material listed in this specification.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 A brief discussion of each test method is given with the intent of helping the user in the selection of the most applicable procedure where more than one is available.
SCOPE
1.1 This guide covers procedures for the sampling and testing of volatile solvents used in the manufacture of paint, lacquer, varnish, and related products. The test methods are listed in Table 1.  
1.2 For specific hazard information and guidance, see Suppliers' Material Safety Data Sheet for materials listed in this guide.  
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification establishes the properties and requirements for ethylene glycol for use in the preparation of surface coatings. The material shall be appropriately sampled and tested, and shall conform to the following specified requirements: apparent specific gravity; color (Pt-Co units); distillation range (initial boiling point and dry point); water content; acidity as acetic acid; diethylene glycol content; and iron content.
SCOPE
1.1 This specification covers ethylene glycol for use in the preparation of surface coatings.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.4 For specific hazard information and guidance, consult the supplier's Material Safety Data Sheet.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method provides a measurement of iron content of formaldehyde solutions. The results of these measurements can be used for specification acceptance.
SCOPE
1.1 This test method covers the determination of the total iron content of formaldehyde solutions.  
1.2 For purposes of determining conformance of an observed or a calculated value using this test method to relevant specifications, test result(s) shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For hazard information and guidance, see the supplier's Material Safety Data Sheet.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method provides a measurement of total acidity in vinyl acetate and acetaldehyde. The results of these measurements can be used for specification acceptance.
SCOPE
1.1 This test method covers the determination of total acidity as acetic acid in refined vinyl acetate and acetaldehyde.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 For purposes of determining conformance of an observed value or a calculated value using this test method to relevant specifications, test result(s) shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.4 For hazard information and guidance, see the supplier's Material Safety Data Sheet.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 8.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method is used to determine the purity value and ethyl methyl pentanol content of 2-ethylhexanol.
SCOPE
1.1 This test method covers the determination of ethyl methyl pentanol content and purity value of 2-ethylhexanol.  
1.2 Water and acid cannot be determined by this test method and must be determined in accordance with Test Methods D1613 and E203 and those results used to normalize the chromatographic data.  
1.3 For purposes of determining conformance of an observed or a calculated value using this test method to relevant specifications, test result(s) shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 For hazard information and guidance, see the supplier's Material Safety Data Sheet.  
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For a specific hazard statement, see 6.1.1.  
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification the properties and requirements for regular and monomer grade 2-ethylhexanol. Specimens shall be appropriately sampled and tested to evaluate their conformance to specified values of the following physical and chemical properties: acidity (free acid as acetic acid); apparent specific gravity; assay content; color (Pt-Co scale); carbonyl as 2-ethylhexanal; ethyl methyl pentanol content; sulfuric acid color; and water content.
SCOPE
1.1 This specification covers regular and monomer grade 2-ethylhexanol.  
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For specific hazard information and guidance, see the supplier's Material Safety Data Sheet for materials listed in this specification.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers four types of moderately volatile hydrocarbon solvents that are mainly aliphatic in composition and normally petroleum distillates, and are commonly referred to as VM&P naphthas used primarily by the coatings industry. Materials shall be available in the following types: Type I, regular; Type II, high flash; Type III, odorless; and Type IV, low aromatics. Specimens shall undergo tests that shall examine their conformance with specified values of the following physical and chemical properties: appearance; bromine number; color (Pt-Co units); aromatics; copper corrosion; distillation (initial boiling point, 50 % recovered, and dry point); flash point; Kauri-butanol value; odor; and apparent specific gravity.
SCOPE
1.1 This specification covers four types of moderately volatile hydrocarbon solvents, mainly aliphatic in composition and normally petroleum distillates. These solvents are used primarily by the coatings industry and are commonly referred to as VM&P naphthas.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded-off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.4 For specific hazard information and guidance, see the supplier's Material Safety Data Sheet for materials listed in this specification.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 These test methods were developed to measure the types and amounts of aromatics in mineral spirits to determine compliance with air pollution regulations that restrict the aromatic content of solvents. They have been demonstrated to be workable and to produce accurate results. However, due to the sensitivity of the tests to operating variables, some laboratories having limited experience with gas chromatographic analyses of hydrocarbons may experience difficulty in performing the tests.
SCOPE
1.1 These test methods cover the determination of ethylbenzene and total eight-carbon (C8) and heavier aromatics in the concentration range from 0.1 to 30 % in mineral spirits having a distillation range from 149 to 210 °C (300 to 410 °F) as determined by Test Method D86. The procedures permit the identification and calculation of concentrations of aromatic components to 0.1 volume %.  
1.2 It is recognized by analytical chemists that a single column gas chromatography analysis of an unknown sample is risky. In such cases, multiple and different analytical techniques must be used for absolutely positive identification, for example, several different gas chromatography columns, gas chromatography/mass spectrometer, or gas chromatography/infrared, etc. In these test methods the material is known and is clearly defined.  
1.3 Oxygenated compounds, if present, may interfere and cause erroneous results. Such oxygenated compounds are not normally present in mineral spirits.  
1.4 Three test methods are covered as follows:  
1.4.1 Test Method A, measurement of ethylbenzene content, C8 plus higher aromatics (except ethylbenzene), and total aromatics by means of a single packed column gas chromatographic analysis.  
1.4.2 Test Method B, measurement of ethylbenzene content by means of a rapid packed column gas chromatographic analysis.  
1.4.3 Test Method C, measurement of ethylbenzene content, C8 plus higher aromatics (except ethylbenzene) and total aromatics by means of a capillary column gas chromatographic analysis.  
1.5 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.6 For purposes of determining conformance of an observed or a calculated value using this test method to relevant specifications, test result(s) shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.7 For hazard information and guidance, see the supplier’s Material Safety Data Sheet.  
1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.9 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method provides a measurement of inhibitor level in vinyl acetate. The results of these measurements can be used for specification acceptance.
SCOPE
1.1 This test method covers the determination of hydroquinone in the range from 1 to 20 ppm in refined, commercially available, vinyl acetate.  
1.2 For purposes of determining conformance of an observed or a calculated value using this test method to relevant specifications, test result(s) shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For hazard information and guidance, see the supplier's Material Safety Data Sheet.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method provides a measurement of commonly found impurities in commercially available methyl ethyl ketone. The measurement of these impurities and the results thereof can individually or when totaled and subtracted from 100 (assay) be used for specification purposes.
SCOPE
1.1 This test method covers the determination of the purity of methyl ethyl ketone by gas chromatography. Impurities including water, acidity, and nonvolatile matter are measured by appropriate ASTM procedures and the results are used to normalize the chromatographic value.  
1.2 For purposes of determining conformance of an observed value or a calculated value using this test method to relevant specifications, test result(s) shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For hazard information and guidance, see the supplier's Material Safety Data Sheet.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method is useful for identifying and for determining the quantity of various impurities in acetate esters.  
4.2 Total purity of the acetate esters must be determined by use of other appropriate ASTM procedures with this test method.
SCOPE
1.1 This test method covers the determination by gas chromatography of the ester content and the corresponding alcohol content of acetate esters. This test method has been applied to ethyl, n-propyl, isopropyl, n-butyl, isobutyl, and 2-ethoxyethyl acetates.  
1.2 Water, and in some cases acetic acid, cannot be determined by this test method and must be measured by other appropriate ASTM procedures and the results used to normalize the chromatographic value.  
1.3 For purposes of determining conformance of an observed or a calculated value using this test method to relevant specifications, test result(s) shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 For specific hazard information and guidance, see the supplier’s Material Safety Data Sheet for material listed in this specification.  
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method provides a measurement of acetaldehyde content in vinyl acetate. The results of these measurements can be used for specification acceptance.
SCOPE
1.1 This test method covers the determination of trace quantities of acetaldehyde, in the range from 0.00 to 0.05 %, contained in 99 % grade vinyl acetate.  
1.2 For purposes of determining conformance of an observed or a calculated value using this test method to relevant specifications, test result(s) shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For hazard information and guidance, see the supplier's Material Safety Data Sheet.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements see Section 8.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method is useful in determining the assay of solvents and thinners which are esters or solutions of esters of carboxylic acid. The ester value is calculated as percent ester. This test method has its greatest application where the solvent or thinner is not a pure ester. This test method may be used in assessing compliance to specification.
SCOPE
1.1 This test method covers the determination of the ester value of solvents and thinners used in lacquers and other coatings.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 For purposes of determining conformance of an observed or a calculated value using this test method to relevant specifications, test result(s) shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.4 For hazard information and guidance, see the supplier’s Material Safety Data Sheet.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For a specific hazard statement, see 8.6.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers vinyl acetate. The vinyl acetate shall conform to the requirements specified for: (1) distillation range, (2) apparent specific gravity, (3) Pt-Co scale color (for HQ grade only), (4) water content, (5) acetaldehyde content, (6) acidity (weight percentage of acetic acid), and (7) inhibitor content. The sampling and test methods to determine conformance to the specified properties are given.
SCOPE
1.1 This specification covers vinyl acetate.  
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For specific hazard information and guidance, see the supplier’s Material Safety Data Sheet for materials listed in this specification.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers commercial hexanes used in the preparation of adhesives, coatings, and printing inks, as raw materials in chemical synthesis, and as solvents in various kinds of extraction operations. The commercial hexanes should conform to the specified requirements for aniline point, apparent specific gravity, bromine index, color Pt-Co, distillation range, kauri-butanol value, nonvolatile matter content, odor, sulfur content, and benzene content.
SCOPE
1.1 This specification covers the range of products commonly referred to as hexanes, which find uses in the preparation of adhesives, coatings, and printing inks, as raw materials in chemical synthesis operations, and as solvents in various kinds of extraction operations.  
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 For specific hazard information and guidance consult supplier’s Material Safety Data Sheet.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers methyl amyl acetate2 (95 % grade) for use in paint, varnish, and related products. The apparent specific gravity, color property, distillation range, non-volatile matter, odor property, water property, acidity, and ester value shall be tested to meet the requirements prescribed.
SCOPE
1.1 This specification covers methyl amyl acetate2 (95 % grade) for use in paint, varnish, and related products.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 For specific hazard information and guidance, see the supplier’s Material Safety Data Sheet for materials listed in this specification.  
1.4 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers the properties and requirements for 2-butoxyethanol. Specimens shall be suitably sampled and tested, and shall meet specified values of the following properties: apparent specific gravity; color (Pt-Co scale); distillation range (initial boiling point and dry point); water content; and acidity (free acid as acetic acid).
SCOPE
1.1 This specification covers 2-butoxyethanol.  
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For specific hazard information and guidance, see the supplier’s Material Safety Data Sheet for materials listed in this specification.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers 2-methoxyethanol. 2-methoxyethanol shall conform to the requirements specified for the following: (1) apparent specific gravity, (2) Pt-Co scale color, (3) distillation range defined by the initial boiling point and dry point, (4) water content, and (5) acidity (free acid as acetic acid). The sampling and test methods to determine conformance to the specified properties are given.
SCOPE
1.1 This specification covers 2-methoxyethanol.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.4 For hazard information and guidance, see the supplier’s Material Safety Data Sheet for materials listed in this specification.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 This test method describes the analytical measurement of residual matter in solvents that are intended to be 100 % volatile at 105 °C ± 5 °C. Volatile solvents are used in the manufacture of paint, varnish, lacquer, and other related products, and the presence of any residue may affect the product quality or efficiency of the process. This test method is useful in manufacturing control and assessing compliance with specifications.
SCOPE
1.1 This test method covers the determination of the nonvolatile matter in volatile solvents for use in paint, varnish, lacquer, and related products.  
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For hazard information and guidance, see the supplier’s Material Safety Data Sheet for materials listed in this test method.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 5.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers the properties and requirements for 98 % grade methyl isoamyl ketone for use in paint, varnish, lacquer, and related products. The material shall be sampled and tested appropriately, and shall conform to properties as to apparent specific gravity, color (Pt-Co scale), distillation (initial boiling and dry points), water content, acidity as acetic acid, and purity.
SCOPE
1.1 This specification covers methyl isoamyl ketone (98 % grade) for use in paint, varnish, lacquer, and related products.  
1.2 The following applies to all specified limits in this standard: for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For specific hazard information and guidance, see the supplier’s Material Safety Data Sheet.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers acetone (99.5 % grade). Acetone shall be subjected to the following tests: acidity test, aldehyde test, alkalinity test, apparent specific gravity test, assay test, color test, distillation range test, nonvolatile matter test, odor test, permanganate time test, water test, and water miscibility test.
SCOPE
1.1 This specification covers acetone (99.5 % grade).  
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in 1.5 and 4.1.  
1.5 This specification specifies the use of a U.S. Occupational Safety and Health Administration (OSHA)-designated hazardous chemical, acetone. For hazard information and guidance see the supplier’s Material Safety Data Sheet.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification establishes the properties and requirements for isopropyl acetate. Specimens shall be sampled and tested as appropriate, and adhere accordingly to specified values of the following properties: apparent specific gravity; color (Pt-Co scale); distillation range (initial boiling point and dry point); nonvolatile matter content; odor; water content; acidity (free acid as acetic acid); and purity.
SCOPE
1.1 This specification covers isopropyl acetate (99 % grade).  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 For specific hazard information and guidance, see the supplier’s Material Safety Data Sheet for materials listed in this specification.  
1.4 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification establishes the properties and requirements for hexyl acetate used as an active tail high boiling solvent in lacquers, automotive coatings, maintenance paints, and other related coatings. Specimens shall be sampled and tested as appropriate, and shall meet specified values of the following properties: acidity (free acid as acetic acid); apparent specific gravity; color (Pt-Co units); distillation range (initial boiling point and 95 % point); Ransburg electrical resistivity; ester value; and water content.
SCOPE
1.1 This specification covers hexyl acetate, which is used as an active tail high boiling solvent in lacquers, automotive coatings, maintenance paints, and other related coatings.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.4 For specific hazard information and guidance, see the supplier’s Material Safety Data Sheet.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The kauri-butanol value is used as a measure of solvent power of hydrocarbon solvents. High kauri-butanol values indicate relatively strong solvency.
SCOPE
1.1 This test method covers the determination of the relative solvent power of hydrocarbon solvents used in paint and lacquer formulations. This test method is suitable for use with solvents having an initial boiling point over 40 °C and a dry point under 300 °C when determined in accordance with the procedures in Note 1.  
Note 1: Test Method D86 is used to determine the initial boiling point and dry point for mineral spirits and similar petroleum solvents. Test Method D1078 is used for pure compounds and narrow boiling range cuts.  
1.2 For purposes of determining conformance of an observed or a calculated value using this test method to relevant specifications, test result(s) shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 For specific hazard information and guidance, consult the supplier's Material Safety Data Sheet.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The permanganate time can be used to judge the presence of oxidizable materials that may be associated with manufacture or contamination during distribution and to assess compliance with a specification.  
4.2 Many chemical processes that use acetone or methanol, or both, involve catalyst, metals, or ligand complexes that are sensitive to oxidation. Since oxidizable contaminants may affect the efficiency of these processes, this test method provides a comparative test for manufacturing control and assessing compliance with a specification.
SCOPE
1.1 This test method covers the detection in acetone and methanol of the presence of impurities that reduce potassium permanganate.  
1.2 For purposes of determining conformance of an observed or a calculated value using this test method to relevant specifications, test result(s) shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.4 For specific hazard information and guidance, consult the supplier's Material Safety Data Sheet.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers two types of methyl ethyl ketone (or 2-butanone), namely: Type I (regular grade) and Type II (urethane grade), that are used primarily as solvents in lacquers and industrial coatings, but also in adhesives, printing inks, lube oil dewaxing, and as chemical intermediates. The physical and chemical properties of methyl ethyl ketone shall conform to the requirements specified for the following: (1) acidity, (2) weight percentage of alcohol, (3) color (Pt-Co scale), (4) distillation range defined by the initial boiling point and dry point, (5) nonvolatile matter content, (6) purity, (7) apparent specific gravity, and (8) weight percentage of water. The sampling and test methods for determining conformance to the specified physical and chemical properties are given.
SCOPE
1.1 This specification covers two types of methyl ethyl ketone that are used primarily as solvents in lacquers and industrial coatings, but also in adhesives, printing inks, lube oil dewaxing, and as chemical intermediates.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 The following applies to all specified limits in this standard: for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.4 For specific hazard information and guidance, see the supplier's Material Safety Data Sheet for materials listed in this specification.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 This test method provides a measurement of methanol content of formaldehyde solutions. The results of these measurements can be used for specification acceptance.  
3.2 This test method is applicable to 37 % formaldehyde solutions containing 0 to 2 %, 6 to 8 %, or 12 to 15 % methanol.
SCOPE
1.1 This test method provides for the calculation of the methanol content of commercially available 37 % formaldehyde solutions and is based on the relationship of specific gravity to formaldehyde and methanol content.2 Separate equations are given for three ranges of methanol: 0 to 2 %, 6 to 8 %, and 12 to 15 %.  
1.2 For purposes of determining conformance of an observed or a calculated value using this test method to relevant specifications, test result(s) shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For hazard information and guidance, see the supplier's Material Safety Data Sheet.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Section 4.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.