C21 - Ceramic Whitewares and Related Products

SIGNIFICANCE AND USE
5.1 This test method provides a means for determining whether or not a lot of ceramic tile meets the warpage requirements that may appear in specifications to assure satisfactory tile installations. In accordance with this test method, warpage is calculated as a percentage of the length of the edge or diagonal being tested. It is realized that the percentage values based on the overall edge length, or on the overall diagonal length of a tile will be slightly lower than those based on the distance between reference points. However, the ratio of the overall lengths to the distance between reference points will be practically constant for any particular size of tile and, therefore, the percentage values will be comparable and equally indicative of warpage.
SCOPE
1.1 This test method covers procedures for measuring the corner, diagonal, and edge warpages of ceramic tile.  
1.1.1 Tile Requirements for Corner, Diagonal, and Edge Warpage Measurement
Tile should be nominally flat, uniform in overall thickness, smooth faced, and rectangular in shape, including square.  
1.1.2 Tile Requirements for Corner Warpage Measurement
All facial edge dimensions equal to or greater than 2.36 in. (60 mm) in length.  
1.1.3 Tile Requirements for Edge and Diagonal Warpage Measurement
All facial edge dimensions equal to or greater than 2 in. (51 mm) in length.  
1.1.4 Trim Tile meeting the descriptions in 1.1.1 – 1.1.3 except that only a part of the tile surface is flat. (Surface trim tile should be treated as flat tile whenever possible.)  
1.2 This test method is not applicable to tile having embossed surfaces that are not flat, or that have a combination of variable body thickness and an irregular face.  
1.3 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 This test method is useful to both sellers and purchasers of alumina and quartz powders for determining particle size distributions for materials specifications, manufacturing control, and development and research.
SCOPE
1.1 This test method, one of several found valuable for the measurement of particle size, covers the determination of the particle size distribution of alumina or quartz powders (0.6 μm to 56.0 μm) using electrical sensing zone particle size analyzers. These instruments use an electric current path of small dimensions which is modulated by individual particle passage through an aperture, and produces individual pulses of amplitude proportional to the particle volume.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 Some tile surfaces may exhibit variations under low angle conditions as part of the designed aesthetic.  
4.2 This practice is intended for tiles that are designed to have an overall uniform appearance under low angle conditions.
SCOPE
1.1 This practice replicates low angle viewing conditions on ceramic tile installations.  
1.2 The values stated in inch-pound units are to be regarded as the standard. The values in parentheses are for information only.  
1.3 This qualitative practice is intended to provide general guidance at the manufacturing level to determine if product will be acceptable under typical end use conditions.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method provides a means for testing combinations of tile, grout, installation materials and installation practices to determine grout retention behavior. This method can be used by installers to determine if installation materials and techniques are synergetic; by tile and grout manufacturers to evaluate product performance and as a forensic tool to determine if an installation system was appropriate.  
FIG. 1 Tile That Has Retained Grout After Testing  
4.2 It is acceptable for other (mainly unglazed) ceramic tile surfaces to have some grout retention if it is light and evenly distributed.
SCOPE
1.1 This test method covers the testing and evaluation of grout retention on glazed and unglazed ceramic tile surfaces and is intended to give the user a uniform procedure to make a comparative assessment of specific tile and grout systems.  
1.2 The values stated in inch-pound units are to be regarded as the standard. The values in parentheses are for information only.  
1.3 This qualitative method is intended to be used to visually detect abnormal grout retention for a specific tile and installation material system installed in a specified way.  
1.4 This method is intended to evaluate the specific grout and tile system specified and is not intended for test results to encompass other tile and grout combinations.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 Impact diameter may be used to interpret impact resistance.  
4.2 Maximum impact diameter may be a specified requirement for tile.
SCOPE
1.1 This test method covers procedures for measuring impact properties of ceramic tile, bonded to a standardized concrete substrate, from a falling 2-in. steel ball.  
1.2 This test method is intended solely for evaluating standardized laboratory test specimens and does not purport to simulate actual installed performance.  
1.3 Units—The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 Sieve analyses are carried out to determine the particle size distribution of powders which, in turn, are used to qualify those materials as to their usefulness in the process under consideration. Since particle size analyses have only relative significance, the results should be considered only where they correlate with process characteristics. The parameter that is being measured in this test is the amount of material that will pass through a cloth having theoretically square openings. It must be remembered that all the holes are not square, nor uniform in size, and the question of whether a given particle will go through is a statistical one. Since each particle size analysis method measures a unique physical parameter, the results from one method may not agree with those from another. Particle size distributions play a role in such properties as bulk density, dustiness, and handling characteristics. Care should be taken, however, when interpretations are made from one or two points (sieves) on the distribution curve.
SCOPE
1.1 This test method covers the determination of the particle size distribution of nonplastic ceramic powders such as alumina, silica, feldspar, pyrophyllite, nepheline syenite, talc, titanates, and zircon using wire cloth sieves.  
1.2 Materials containing a large amount of fines, containing agglomerates, or that are nonfree-flowing, are wet-sieved to remove excessive fines or to disperse agglomerates before performing the test. This technique is not applicable to materials that are, to any degree, water soluble.  
1.3 The values stated in SI units are to be regarded as standard. The values given in parentheses are mathematical conversions to inch-pound units, or are other customary units (in the case of sieve frame diameter and sieve number), that are provided for information only and are not considered standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method provides a standardized procedure for evaluating performance of ceramic floor tile installations under conditions similar to actual specific usages. It can be used to make comparisons between customary basic installation methods, to establish the influence of minor changes in a particular installation method, and to judge the merit of proposed novel methods.
SCOPE
1.1 This test method covers the evaluation of ceramic floor tile installation systems, using the Robinson2-type floor tester.  
1.2 This test method is intended solely for evaluating complete ceramic floor tile installation systems for failure under dynamic loads and not for evaluating particular characteristics of ceramic tile, such as abrasion resistance. This test method does not claim to provide meaningful results for other than evaluating complete ceramic floor tile installation systems.  
1.3 The values stated in inch-pound units are to be regarded as the standard. The metric (SI) units in parentheses are for information only.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 This test method describes the means of determining the LRV of a tile specimen. Certain building codes require the use of materials rated by LRV. Application of this test method provides the means for rating ceramic tile. LRVs reported for ceramic tile should include reference to the observer and illuminant for which the rating is valid.  
5.2 LRV is a property dependent on the overall color of a tile specimen. Control of LRV is achieved through control of color and adherence to color specifications will govern the acceptability of a product with respect to LRV. Therefore, a product cannot be judged as having an unacceptable LRV unless the color of the product is found to be unacceptable.  
5.3 Mixtures of several tile products are commonly installed on a surface, requiring a means to calculate LRV for a product mix. The rating obtained for an individual tile product can be used to calculate the LRV for a product mix using the following equation:
   where:  
  n  =  number of products included in the mix,    p1 to n  =  the proportion of the surface area taken up by each product; the sum of p1 to pn must equal one), and   LRV1 to n  =  the LRV for each product used.    For example, a mixture of two products is used on a surface. Two thirds of the surface area is covered by product A with a LRV of 75 %, and one third of the surface is covered by product B with an LRV of 60 % (see Fig. 2). Using the equation, the product mix is found to have an LRV of 70 %.  
FIG. 2 Example of Product Mix Used on Surface
5.4 The test method described herein provides instrumental means as the basis for judging color difference. Magnitude of color difference between pairs of ceramic tile can be determined and expressed in numerical terms.  
5.5 Based on interlaboratory investigation,3 color difference ΔE  of plain-colored tile, if determined in accordance with this test method, should give excellent reproducibility with a standard deviation of not more than σ = ±...
SCOPE
1.1 This test method covers the measurement of Light Reflectance Value (LRV) and visually small color difference between pieces of glazed or unglazed ceramic tile, using any spectrophotometer that meets the requirements specified in the test method. LRV and the magnitude and direction of the color difference are expressed numerically, with sufficient accuracy for use in product specification.  
1.2 LRV may be measured for either solid-colored tile or tile having a multicolored, speckled, or textured surface. For tile that are not solid-colored, an average reading should be obtained from multiple measurements taken in a pattern representative of the overall sample as described in 9.2 of this test method. Small color difference between tiles should only be measured for solid-color tiles. Small color difference between tile that have a multicolored, speckled, or textured surface are not valid.  
1.3 For solid colored tile, a comparison of the test specimen and reference specimen should be made under incandescent, fluorescent and daylight illuminant conditions. The use of multiple illuminants allows the color difference measurement to be made without the risk of wrongly accepting a match when the tiles being compared are metamers (see 3.1.4).  
1.4 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are provided for information only and are not considered standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standard...

SIGNIFICANCE AND USE
4.1 The test for resistance to freezing and thawing functions as a guide to the selection of ceramic and glass tiles suitable for outdoor service in geographic areas subjected to freezing. It can serve as a test method to verify compliance with specifications for ceramic and glass tiles, and provides a control test for determining the freeze/thaw resistance of tiles being manufactured for exterior installations.
SCOPE
1.1 This test method describes the procedures and equipment required to test either glazed or unglazed ceramic or glass tiles for resistance to repeated cycles of freezing and thawing. Tiles of any size or shape may be tested by this test method.  
1.2 The values stated in inch-pound units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method provides the means to measure the potential resistance to wear of unglazed ceramic tile intended for floor coverings. This test method does not consider physical appearance but is intended to measure durability. See Test Method C1027 for the determination of visible abrasion resistance of glazed ceramic tile.  
4.1.1 See Test Method C501 for an alternative method to determine deep abrasion.
SCOPE
1.1 This test method covers the deep abrasive wear by measuring the loss of volume resulting from abrasion of unglazed ceramic tile under given conditions by means of a rotating disc and the use of abrasive material.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This practice describes a procedure for developing precautionary labels for ceramic art materials and provides hazard and precautionary statements concerning chronic adverse health hazards known to be associated with a product or product component(s), when the component(s) is present in a physical form, volume, or concentration that in the opinion of a toxicologist has the potential to produce a chronic adverse health effect(s). Precautionary labels covered by this practice are intended for adult usage and does not assure completely the safe use of an art product. This practice does not specify test methods for determining whether a substance or product presents chronic adverse health hazards and does not apply to products appropriately labeled for known chronic adverse health hazards according to chemical substances labeling standards and practices, such as another national consensus standard, existing labeling statutes, regulations, or guidelines. Requirements for the conformance to this practice are given. Determination of labeling and labeling practices such as, signal word, list of potential chronic hazards, name of chronic hazard components, safe handling, instructions, list of sensitizing components, combined statements, information sources, and supplement information are detailed.
SCOPE
1.1 This practice describes a procedure for developing precautionary labels for ceramic art materials and provides hazard and precautionary statements based upon knowledge that exists in the scientific and medical communities. This practice concerns those chronic adverse health hazards known to be associated with a product or product component(s), when the component(s) is present in a physical form, volume, or concentration that in the opinion of a toxicologist has the potential to produce a chronic adverse health effect(s).  
1.2 This practice is intended to apply exclusively to ceramic art materials which are packaged in sizes intended for use by artists or crafts people, either individually, or in a small group or class.  
1.3 This practice applies to developing precautionary labeling for ceramic art materials intended for adult usage. Conformance to this practice does not imply that ceramic art materials will necessarily be labeled adequately or safe for use by children. Labeling determinations should consider reasonably foreseeable use or misuse by children and include as appropriate, in such instances, warnings to keep out of reach, or other specific precautionary statements. The responsibility for precautionary labeling rests with the ceramic producer or repackager who markets the material for art or craft use.  
1.4 This practice does not specify test methods for determining whether a substance or product presents chronic adverse health hazards.  
1.5 This practice does not apply to products appropriately labeled for known chronic adverse health hazards according to chemical substances labeling standards and practices, such as another national consensus standard, existing labeling statutes, regulations, or guidelines.  
1.6 Since knowledge about chronic adverse health hazards is incomplete and warning cannot cover all uses of any product, it is not possible for precautionary labeling to assure completely safe use of an art product.  
1.7 Manufacturers or repackagers may wish to determine individually or collectively precautionary labeling for ceramic art materials in accordance with this practice. Compliance may be certified by a certifying organization. Guidelines for a certifying organization are given in Appendix X1.  
1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.9 This international standard was developed in accordance with international...

SIGNIFICANCE AND USE
3.1 These test methods provide a means for determining the modulus of rupture and the modulus of elasticity, which may be required in product specifications.
SCOPE
1.1 These test methods cover determination of the modulus of rupture and the modulus of elasticity of fired ceramic whitewares bodies, formed by any fabrication method, and are applicable to both glazed and unglazed test specimens.  
1.2 The values stated in inch-pound units are to be regarded as the standard. The metric equivalents of inch-pound units may be approximate.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 Sampling of decorated glass containers for the TCLP can vary greatly, resulting from the size and shape of the article relative to the amount of ceramic decoration on the ware. Breaking the glass can cause some of the pieces to have no decoration on them, and others to be heavily decorated and more likely to leach lead and cadmium under the TCLP test. This method provides an effective tool to homogenize the glass containers so that reproducible results can be attained from the TCLP test.
SCOPE
1.1 This test method defines the way in which container glassware should be prepared before performing the Toxicity Characteristic Leaching Procedure (TCLP). The method covers the homogenization of the sample, and the selection of a representative portion of the sample to test and get reproducible results.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 Measurement of density, porosity, and specific gravity is a tool for determining the degree of maturation of a ceramic body, or for determining structural properties that may be required for a given application.
SCOPE
1.1 These test methods covers procedures for determining water absorption, bulk density, apparent porosity, and apparent specific gravity of non-tile fired unglazed ceramic whiteware2 products, glazed or unglazed ceramic tiles, and glass tiles.  
1.2 The values stated in metric units are normative. The values given in parentheses are mathematical conversions to inch-pound units that are provided for information only and are not normative.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 Both sellers and purchasers of alumina and quartz will find the test method useful to determine the specific surface area and indirectly as a measure of the particle size for material specifications, manufacturing control, and research and development.
SCOPE
1.1 This test method covers the determination of the specific surface area of aluminas and silicas used in the manufacture of ceramics. The test method is a general one, permitting the use of any modern commercial nitrogen adsorption apparatus but strictly defining the outgassing procedure. Calculations are based on the Brunauer-Emmett-Teller (BET) equation.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This test method details the standard procedures for the determination of the particle size distribution of alumina or quartz powders using X-ray monitoring of gravity sedimentation. This test procedure shall make use of an X-ray sedimentation apparatus, and ultrasonic probe or bath. An aqueous homogeneous dispersion of the specimen is permitted to settle in a cell. The decrease in particle concentration over a programmed settling distance is monitored by an X-ray beam passing through the sedimenting dispersion to a detector. The specimen concentration at any given sedimentation distance is inversely proportional to the X-ray flux and the equivalent diameter (spherical) is calculated from Stokes' law.
SCOPE
1.1 This test method covers the determination of the particle size distribution of alumina or quartz powders in the range from 0.5 μm to 50 μm and having a median particle diameter from 2.5 μm to 10 μm using a sedimentation method. This test method is one of several found valuable for the measurement of particle size. Instruments used for this test method employ a constant intensity X-ray beam that is passed through a sedimenting dispersion of particles.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 7.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This test method covers the determination of free moisture in ceramic whiteware clays. Whiteware clays may be shipped as a bulk shipment in lumps, a bulk shipment of shredded or coarsely ground clay, or in bagged lots of ground or airfloated clay. Directions are given in this test method for obtaining representative samples of the clay shipment to be used in subsequent tests for the properties of the clay in the shipment. Percentage of free moisture shall be calculated to the nearest 0.1%.
SCOPE
1.1 This test method covers the determination of free moisture in ceramic whiteware clays. Whiteware clays may be shipped as a bulk shipment in lumps, a bulk shipment of shredded or coarsely ground clay, or in bagged lots of ground or airfloated clay. Directions are given in this test method for obtaining representative samples of the clay shipment to be used in subsequent tests for the properties of the clay in the shipment.  
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This test method covers the procedures for determining soluble sulfate ions present in water or a filtrate using a photometer to measure the turbidity of precipitated barium sulfate. This test method also details a method for standardizing the photometer to be used. The soluble sulfate ions may be removed from clays or clay-water slurries by leaching with water during mixing and then filter pressing. An impractical number of washings would be needed to remove all sulfate ions, therefore, this test method should be considered only as a control test and not a quantitative analysis for sulfate ions. Test apparatus include a balance, high speed mixer, filter press, glass beakers, transfer pipets, spectrophotometer, measuring spoon, and other laboratory equipment. All reagents to be used should be of the required purity and concentration.
SCOPE
1.1 This test method covers the determination of soluble sulfate ions present in water or a filtrate by means of a photometer measuring the turbidity of precipitated barium sulfate. A method of standardizing the photometer for this test method is also given.  
1.2 Soluble sulfate ions may be removed from clays or clay-water slurries by leaching with water during mixing and subsequent filter pressing. To remove all the sulfate ions would require an impractical number of washings; therefore, this test method should be considered a control test and not a quantitative analysis for SO4 ions.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This guide covers the wet sieve analysis of ceramic whiteware clays. This guide is intended for use in testing shipments of clay as well as for plant control tests. The apparatus to be used include stirring device and sieves. The following procedure shall be followed in the analysis of the ceramic whiteware clays: transferring of duplicate portions of the dried clay sample; agitating of the slurry by means of a mechanical stirrer to ensure complete separation of clay from nonplastic impurities; transferring of the slaked and stirred sample, without loss, to the finest sieve to be employed in the test; washing of the residue remaining on the finest sieve into the pan; nesting the top sieve on the pan, which shall contain a certain amount of clear water; refilling of the pan with the proper amount of water, then nesting the top sieve and its residue on the pan; carefully blotting each sieve on its underside with a soft, damp sponge, and placing the sieve either in a drying oven or under infrared lamps until thoroughly dry; nesting the dried residues and sieves in the proper order, with due care to prevent dusting of the residues; and separating the nested sieves and carefully brushing the residue from each onto a weighing paper.
SCOPE
1.1 This guide covers the wet sieve analysis of ceramic whiteware clays. This guide is intended for use in testing shipments of clay as well as for plant control tests.  
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This standard test method covers the rate determination of clay-water paste layer formation from a clay-water slip under pressure filtration. Filter pressing of clay shall be in accordance to the procedure indicated in this specification. Calculation of filtration rate and void fraction shall depend on thickness of wet filter cake and filtration time. Void fraction in the filter cake shall depend on filter cake weight, filter press cross-sectional area, and wet filter cake thickness.
SCOPE
1.1 This test method covers the determination of the rate at which a layer of clay-water paste is formed from a clay-water slip under pressure filtration. The filtration rate is directly related to such whiteware operations as filter pressing, slip casting, and drying of ware in which water permeability through a clay-water paste is the controlling mechanism.  
1.2 A straight-line relationship exists between the time of filter pressing and the square of the thickness of the paste layer. The filtration rate is directly related to the filter press pressure and the void fraction of the paste layer, and is inversely related to the square of the clay surface area, the ratio of solids to liquid in the slip, and the viscosity of water at the testing temperature.  
1.3 The values stated in acceptable metric units are to be regarded as the standard. The values given in parentheses are for information only.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 This test method is intended for determining the breaking strength and modulus of rupture of ceramic tiles and glass tiles for compliance with requirements that may appear in specifications.
SCOPE
1.1 This test method covers the determination of breaking strength and modulus of rupture of ceramic tiles and glass tiles by three-point loading.  
1.2 Units—The values stated in SI units are to be regarded as standard. The values given in parentheses are mathematical conversions to inch-pound units that are provided for information only and are not considered standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SCOPE
1.1 This terminology pertains to the terminology used in ceramic whitewares and related products.  
1.2 Words adequately defined in standard dictionaries are not included. Included are words that are peculiar to this industry. Double words, hyphenated words, or phrases are listed alphabetically under the first word; additional important words are cross-referenced.  
1.3 For definitions of terms relating to surface imperfections on ceramics, refer to Terminology F109.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This test method covers the establishment of an abrasive wear index by determination of the loss of weight resulting from abrasion of unglazed ceramic tile by Taber Abraser. The test method consists of mounting the tile specimens in suitable holders, attaching the mounted holders to the spindle of the Taber Abraser, and subjecting the specimens to a prescribed number of revolutions under abrasive wheels of specified coarseness and under a definite applied load. The apparatus consists of Taber abrading machine, vacuum pick-up, revolution counter, wheel refacer, and balance. The procedure of sampling and mounting the test specimen are detailed. The formula for calculating the abrasive wear index from the loss of weight due to abrasion is given.
SIGNIFICANCE AND USE
5.1 This test method provides a means to quantify the abrasion resistance of unglazed ceramic tile and may be related to end-use performance, or used to comparatively rank material performance, or both.
SCOPE
1.1 This test method covers the establishment of an abrasive wear index by determination of the loss of weight resulting from abrasion of unglazed ceramic tile. It is applicable to tile described in Definitions C242.  
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SCOPE
1.1 This terminology describes and illustrates imperfections observed on whitewares and related products. For additional definitions of terms relating to whitewares and related products, refer to Terminology C242. To observe these defects, examination shall be performed visually, with or without the aid of a dye penetrant, as described in Test Method C949. Agreement by the manufacturer and the purchaser regarding specific techniques of observation is strongly recommended.  
1.2 This terminology does not cover every defect or imperfection possible for whitewares or related products. The standard is not intended to be an all inclusive document for ceramic imperfections. New defect types may be created as ceramic processes, materials, and technology evolve.  
1.3 Some of the imperfection photos utilize magnification for clarity in documentation. Unless otherwise noted, typical observation conditions for detection of tile imperfections/defects shall consist of current ANSI A137.1 viewing criteria for the specific defect type  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 Resistance to compression is the measure of the greatest strength of a ceramic material. Ideally, ceramics should be stressed this way in use. This test is a measure of the potential load-bearing usefulness of a ceramic.
SCOPE
1.1 This test method covers two test procedures (A and B) for the determination of the compressive strength of fired whiteware materials.  
1.2 Procedure A is generally applicable to whiteware products of low- to moderately high-strength levels (up to 150 000 psi or 1030 MPa).  
1.3 Procedure B is specifically devised for testing of high-strength ceramics (over 100 000 psi or 690 MPa).  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
2.1 This test method provides an indication of service life under detergent exposure.
SCOPE
1.1 This test method2 covers the determination and evaluation of the resistance of overglaze decorations on ceramic whitewares to attack by normal household soaps and liquid detergents under normal household conditions.  
1.2 This test method applies primarily to overglaze decorations applied to dinnerware for domestic use wherein household soaps and detergents are used for cleaning the soiled ware by either hand or machine operations.  
1.3 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 Unless there is a proper match between the expansions of the glaze and the body, all glazed whitewares may contain residual stresses from the firing that bonded the glaze to the body. In addition, whitewares are increasingly subjected to thermal stresses in service. Hence, an important use criterion for a glazed whiteware is adequate resistance to repeated abrupt thermal changes. In most cases, the result of inadequate resistance to thermal shock is the appearance of a craze pattern in the glaze. This craze pattern is visible by inspection with oblique lighting and application of a suitable ink or dye.  
3.2 This test method is applicable to vitreous whitewares that have negligible crazing as a result of moisture expansion. For nonvitreous and semivitreous bodies, refer to Test Method C424.
SCOPE
1.1 This test method covers the determination of the resistance to crazing of fired, glazed, ceramic whitewares when stresses residual after glost firing may cause a tendency to craze, such stresses being induced by factors other than moisture expansion.  
1.2 This test is not intended to induce moisture expansion, which fact should be kept in mind if the materials to be evaluated may exhibit moisture expansion.  
Note 1: Test Method C424 covers a method for determining resistance to crazing induced by moisture expansion. Its use is generally confined to testing nonvitreous and semivitreous ceramic whitewares because these products may be subject to such expansion. For whitewares with negligible moisture expansion (such as vitreous and impervious ware), the thermal shock method described herein is generally to be preferred.  
1.3 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For a specific hazard statement, see Warning  in 6.3.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This test method details the standard and precise procedures for the determination of lead and cadmium extracted by acetic acid from glazed ceramic surfaces. The apparatus needed for this procedure include an atomic absorption spectrometer, lead and cadmium lamps, and glassware of chemical resistant borosilicate glass. The water, detergent wash, and reagents such as acetic acid, lead nitrate solution, hydrochloric acid, and cadmium solution should conform to chemical purity specified. Measurement procedures, precision, and bias are discussed thoroughly.
SCOPE
1.1 This test method covers the precise determination of lead and cadmium extracted by acetic acid from glazed ceramic surfaces. The procedure of extraction may be expected to accelerate the release of lead from the glaze and to serve, therefore, as a severe test that is unlikely to be matched under the actual conditions of usage of such ceramic ware. This test method is specific for lead and cadmium.  
1.2 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 This test method defines the thermal expansion of glaze frits by the interferometric method. This determination is critical in avoiding crazing (cracking) of these glass coatings due to mismatching of the thermal expansion between the coating and substrate materials.
SCOPE
1.1 This test method covers the interferometric determination of linear thermal expansion of premelted glaze frits and fired ceramic whiteware materials at temperatures lower than 1000 °C (1830 °F).  
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SCOPE
1.1 This specification covers the requirements for fabricated alumina parts suitable for electronic and electrical applications and ceramic-to-metal seals as used in electron devices. This specification specifies limits and methods of test for electrical, mechanical, thermal, and general properties of the bodies used for these fabricated parts, regardless of part geometry.  
1.2 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 The most direct and accessible methods for obtaining the color coordinates of ceramic glazes and related whitewares are by instrumental measurement using spectrophotometers or colorimeters with either hemispherical or bidirectional optical measuring systems. This test method provides procedures for such measurement by reflectance spectrophotometry using a hemispherical optical measuring system.  
5.2 This test method is especially suitable for measurement of the following types of specimens for the indicated uses (see Practice E805).  
5.2.1 All types of ceramic glaze and related whiteware specimens to obtain data for use in computer colorant formulation.  
5.2.2 Ceramic glaze and related whiteware specimens for color assessment.
5.2.2.1 For the measurement of plane-surface high-gloss specimens, the specular component should generally be excluded during the measurement.
5.2.2.2 For the measurement of plane-surface intermediate-gloss (satin) specimens, where the first-surface reflection component may be distributed over a wide range of angles, measurement may be made with the specular component included, but the resulting color coordinates may not correlate best with visual judgments of the color. Measurement with specular excluded may lead to better correlations.
5.2.2.3 For the measurement of plane-surface, low-gloss (matte) specimens, the specular component may either be excluded or included, as no significant difference in the results should be apparent.  
5.3 An estimate of gloss may be obtained by measuring the reflection both with the specular component of reflection included and excluded, and then calculating the difference between the two measurements at several wavelengths across the visible spectrum, as described in 10.2.
SCOPE
1.1 This test method describes the instrumental measurement of the reflection properties and color of ceramic glazes and other whitewares by the use of a spectrophotometer or spectrocolorimeter with a hemispherical optical measuring system, such as an integrating sphere.  
1.2 The test method is suitable for use with most specimens having an exterior flat surface large enough to cover the spectrophotometer sample port.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
2.1 This test method provides information useful in understanding and quantifying such parameters as thermal shock resistance and ability to conduct or dissipate heat.
SCOPE
1.1 This test method covers a general procedure2 for determining the thermal conductivity of whiteware ceramics over the temperature range from 100 to 300 °F (40 to 150 °C).  
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 Measurement of thermal expansion is useful for predicting stress within joined materials or single materials under conditions of changing or nonuniform temperature. It can also serve as an indicator of phase composition or changes in structure.
SCOPE
1.1 This test method covers the determination of the linear thermal expansion of premelted frit (porcelain enamel and glaze) and ceramic whiteware products by the thermal dilatometer method. This test method is applicable to apparatus meeting the reproducibility and accuracy requirements of this test method, which are to produce percent linear expansion accuracy of ±3 % or better and coefficient of linear expansion accuracy of ±5 % or better.  
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 This test method is for evaluating ceramic products that are intended for reheating in a Consumer based microwave oven. It is not intended for evaluating products that will be used in commercial type microwaves.  
5.2 This test method is not intended to evaluate metallic or polymeric based products.  
5.3 Ceramic products intended for microwave use must also be evaluated for thermal shock resistance and pass the 325 °F criteria as described in Test Method C554, before being tested for microwave safety. This would include specific tests for dinnerware, cookware, drinkware and ancillary items intended for use with hot foods, such as gravy boats or any product intended for microwave use.  
5.4 Dishes having a metallic glaze, decoration or paint should not be used in this test or microwave ovens unless it is specifically designed for and marked as microwave safe.
SCOPE
1.1 This test method determines the suitability of ceramicware for use in microwave re-heating applications. Microwave ovens are mainly used for reheating and defrosting frozen foods. Severe thermal conditions can occur while reheating foods. Typical reheating of foods requires one to 5 min in the microwave at the highest power settings. Longer periods than 5 min are considered cooking. Cooking test methods and standards are not addressed in this test method. Most ceramicware is minimally absorbing of the microwave energy and will not heat up significantly. Unfortunately there are some products that absorb microwave energy to a greater extent and can become very hot in the microwave and pose a serious hazard. Additionally, the nature of microwave heating introduces radiation in a non-uniform manner producing temperature differentials in the food being cooked as well as the ceramic container holding it. The differential may become great enough to thermal shock the ware and create dangerous conditions.  
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
2.1 This test method provides means to determine increases in physical dimension of fired whiteware materials which develop from the reaction of water and water vapor at elevated pressures and temperatures. These reactions can occur in time at normal atmospheric pressures and temperatures; changes in physical dimensions from water can influence the integrity and stability of an installation. In the case of glazed ware, moisture expansion can lead to crazing.
SCOPE
1.1 This test method covers the determination of the elongation of whiteware bodies caused by rehydration as a result of autoclave treatment.  
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
2.1 This test method is particularly useful for porous materials that can exhibit moisture expansion.  
2.2 This test method is a primary test method that is suitable for use in specifications, quality control, and research and development. It can also serve as a referee test method in purchasing contracts or agreements.
SCOPE
1.1 This test method covers the determination of the crazing resistance of fired glazed whitewares using the autoclave treatment and under the conditions specified in this test method.  
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 For any given ceramic composition, one or more of the properties covered herein may be of more importance for a given insulating application than the other properties. Thus, it may be appropriate that selected properties be specified for testing these ceramic materials.  
3.2 Pertinent statements of the significance of individual properties may be found in the sections pertaining to such properties.
SCOPE
1.1 These test methods outline procedures for testing samples of vitrified ceramic materials that are to be used as electrical insulation. Where specified limits are mentioned herein, they shall not be interpreted as specification limits for completed insulators.  
1.2 These test methods are intended to apply to unglazed specimens, but they may be equally suited for testing glazed specimens. The report section shall indicate whether glazed or unglazed specimens were tested.  
1.3 The test methods appear as follows:    
Section  
Test Method  
Related
Standard(s)  
6  
Compressive Strength  
C773  
13  
Dielectric Strength  
D618, D149  
8  
Elastic Properties  
C623  
15  
Electrical Resistivity  
D618, D257, D1829  
7  
Flexural Strength  
C674, F417  
9  
Hardness  
C730, E18  
5  
Porosity  
C373  
14  
Relative Permittivity and Dissipation
Factor  
D150, D2149, D2520  
4  
Specific Gravity  
C20, C329, F77  
10  
Thermal Conductivity  
C177, C408  
12  
Thermal Expansion  
C539, E288  
11  
Thermal Shock Resistance  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific warning statements are given in 11.3, 13.5, and 15.3.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 Toxic effects of lead and cadmium are well known and release of these elements from foodware is regulated by many countries. Regulatory decisions are based on results of 24-h leaching with acetic acid because results of this test method are precise and accurate and this test method is easy to use. Concentrations of lead and cadmium extracted by food may be different from results of this method, however, because acidity, contact time, and temperature typical of consumer use are different from those of this test method.  
5.2 This test method is intended for application only in contamination-free settings and should be performed by well-qualified technical personnel. It is recognized that it is not a practical or appropriate method to use in a nonlaboratory environment for quality assurance and control of the ceramic process. Users are advised to use Test Method C738 (flame AAS) for purposes of the latter.
SCOPE
1.1 This test method covers procedures for using graphite furnace atomic absorption spectroscopy (GFAAS) to quantitatively determine lead and cadmium extracted by acetic acid at room temperature from the food-contact surface of foodware. The method is applicable to food-contact surfaces composed of silicate-based materials (earthenware, glazed ceramicware, decorated ceramicware, decorated glass, and lead crystal glass) and is capable of determining lead concentrations greater than 0.005 to 0.020 μg/mL and cadmium concentrations greater than 0.0005 to 0.002 μg/mL, depending on instrument design.  
1.2 This test method also describes quality control procedures to check for contamination and matrix interference during GFAAS analyses and a specific sequence of analytical measurements that demonstrates proper instrument operation during the time period in which sample solutions are analyzed.  
1.3 Cleaning and other contamination control procedures are described in this test method. Users may modify contamination control procedures provided that the modifications produce acceptable results and are used for both sample and quality control analyses.  
1.4 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 Measurement of specific gravity is a tool for determining the degree of maturation of a ceramic body.
SCOPE
1.1 This test method covers the determination of specific gravity of fired ceramic whiteware materials under prescribed conditions.  
Note 1: This test method is not applicable to materials attacked by water.  
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 The purpose of this test method is to predict product resistance to impact breakage in service.
SCOPE
1.1 This test method covers the following tests:  
1.1.1 Impact tests at the center of both flatware and hollow ware and at the rim of hollow ware, and  
1.1.2 Chipping tests at the rim of flatware. Specimens may be either glazed or unglazed.  
Note 1: The impact test at the center of the specimen is used to determine: (1) the magnitude of a blow that will produce initial fracture, and (2) the amount of energy necessary to produce complete failure. In the first case, the initial fracture shows on the side of the piece opposite from that being struck and appears to be a function of the square of the thickness and of the inherent brittleness of the body or body-glaze combination; it is relatively independent of the size or design of the specimen. The second factor is more dependent upon design and often is subject to wide variation within a given group of pieces.
Note 2: The impact test at the rim of hollow ware is similar to a chipping test, and the type of failure that is obtained is useful in evaluating the effect of the shape of the object.
Note 3: In addition to the inherent strength of the body, chipping test results are greatly affected by contour of rim and to a lesser extent by thickness of rim, inclination of leaf, and fit of glaze.  
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 This test method provides a means for readily determining if a ceramic is properly fired (matured). Penetration of any extent may negate the usefulness of the ceramic, or, arbitrarily, some degree of penetration may be acceptable for the use or commercial quality of the item being tested.
SCOPE
1.1 This test method covers procedures for detecting pores, cracks, or other voids that may be present in otherwise impermeable whiteware ceramics, or as porosity in underfired ware.  
Note 1: This test method was partially derived from ANSI C29.1.  
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 This test system has advantages in certain respects over the use of static loading systems in the measurement of ceramic whitewares.  
3.1.1 Only minute stresses are applied to the specimen, thus minimizing the possibility of fracture.  
3.1.2 The period of time during which stress is applied and removed is of the order of hundreds of microseconds, making it feasible to perform measurements at temperatures where delayed elastic and creep effects proceed on a much-shortened time scale.  
3.2 This test method is suitable for detecting whether a material meets specifications, if cognizance is given to one important fact: ceramic whiteware materials are sensitive to thermal history. Therefore, the thermal history of a test specimen must be known before the moduli can be considered in terms of specified values. Material specifications should include a specific thermal treatment for all test specimens.
SCOPE
1.1 This test method covers the determination of the elastic properties of ceramic whiteware materials. Specimens of these materials possess specific mechanical resonance frequencies which are defined by the elastic moduli, density, and geometry of the test specimen. Therefore the elastic properties of a material can be computed if the geometry, density, and mechanical resonance frequencies of a suitable test specimen of that material can be measured. Young’s modulus is determined using the resonance frequency in the flexural mode of vibration. The shear modulus, or modulus of rigidity, is found using torsional resonance vibrations. Young’s modulus and shear modulus are used to compute Poisson’s ratio, the factor of lateral contraction.  
1.2 All ceramic whiteware materials that are elastic, homogeneous, and isotropic may be tested by this test method.2 This test method is not satisfactory for specimens that have cracks or voids that represent inhomogeneities in the material; neither is it satisfactory when these materials cannot be prepared in a suitable geometry.  
Note 1: Elastic here means that an application of stress within the elastic limit of that material making up the body being stressed will cause an instantaneous and uniform deformation, which will cease upon removal of the stress, with the body returning instantly to its original size and shape without an energy loss. Many ceramic whiteware materials conform to this definition well enough that this test is meaningful.
Note 2: Isotropic means that the elastic properties are the same in all directions in the material.  
1.3 A cryogenic cabinet and high-temperature furnace are described for measuring the elastic moduli as a function of temperature from −195 to 1200 °C.  
1.4 Modification of the test for use in quality control is possible. A range of acceptable resonance frequencies is determined for a piece with a particular geometry and density. Any specimen with a frequency response falling outside this frequency range is rejected. The actual modulus of each piece need not be determined as long as the limits of the selected frequency range are known to include the resonance frequency that the piece must possess if its geometry and density are within specified tolerances.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 The Knoop indentation hardness is one of many properties that is used to characterize ceramic whitewares. Attempts have been made to relate Knoop indentation hardness to tensile strength, grinding speeds, and other hardness scales, but no generally accepted methods are available. Such conversions are limited in scope and should be used with caution, except for special cases where a reliable basis for the conversion has been obtained by comparison tests.
SCOPE
1.1 This test method covers the determination of the Knoop indentation hardness of ceramic whitewares and the verification of Knoop indentation hardness testing machines using standard glasses.  
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The traditional method of preparing glazes and slurries has been to add stains (pigments), stabilizers, viscosity control agents, bactericides, and so forth, to the pebble mill batch along with normal batch materials such as clay, frit, quartz, feldspar, whiting (calcium carbonate), zinc oxide, opacifier, and so forth. This method had the disadvantage of over grinding some of the materials of the batch and under grinding other materials. While part of the disadvantage could be alleviated by double or triple batching (where the pebble mill was stopped at one or two points in the cycle and one or more materials added), the practice was labor intensive and not always well controlled. Another disadvantage of the traditional method was that it was necessary to thoroughly wash out the mill between batches of different colors. An obvious advantage, however, was that small components of the batch (such as pigments) were thoroughly dispersed in the batch and even today it is necessary to use this procedure when small quantities of strongly colored pigments are to be used.  
4.2 With the advent of high speed intensive mixers using a rotating shaft-mounted impeller, it is now the usual practice to add pigments, conditioners, and so forth, to the batch from the pebble mill and accomplish the same uniform dispersion as would be the case if the pigments were milled in rather than “stirred” in. In addition, the pigments tend to yield a stronger color in the glaze because they have not been over ground in the pebble mill. It is not uncommon to make a reduction in the amount of pigment needed to develop the desired color when the pigment is stirred in rather than milled in. An even greater benefit is using the “stirred in” technique is that a single large batch of a base glaze (for example, clear) can be made by milling, and individual colors developed by stirring appropriate pigments and conditioners into small amounts of the base glaze. In this way, a large pebble mill can be...
SCOPE
1.1 In preparing ceramic glazes and slurries for use, it is often necessary to add pigments to develop a desired fired color, to incorporate viscosity control agents for developing, or providing to develop the desired thickness of the glaze on the ware, to add materials which stabilize the suspension, control bacterial growth, and develop the desired hardness of the glaze on the ware to allow moving and handling before firing. While it is convenient to add these materials to the glaze or slurry in the dry form, it is often possible to use slurries where these materials are dispersed in a slurry and the slurry then added to the liquid glaze. Regardless of the state of the additions (dry or slurry), the dispersion can be done efficiently and effectively by the use of a high intensity mixer (sometimes referred to as a dissolver) and the procedure used is described here.  
1.2 The values stated in SI units are to be regarded as the standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The estimation of average particle size has two chief functions: (1) as a guide to the degree of fineness or coarseness of a powder as this, in turn, is related to the flow and packing properties, and (1) as a control test on the uniformity of a product.  
4.2 These test methods provide procedures for determining the envelope-specific surface area of powders, from which is calculated an “average” particle diameter, assuming the particles are monosize, smooth surface, nonporous, spherical particles. For this reason, values obtained by these test methods will be reported as an average particle size or Fisher Number. The degree of correlation between the results of these test methods and the quality of powders in use will vary with each particular application and has not been fully determined.  
4.3 These test methods are generally applicable to alumina and silica powders, for particles having diameters between 0.2 and 75 μm (MIC SAS) or between 0.5 and 50 μm (FSSS). They may be used for other similar ceramic powders, with caution as to their applicability. They should not be used for powders composed of particles whose shape is too far from equiaxed—that is, flakes or fibers. In these cases, it is permissible to use the test methods described only by agreement between the parties concerned. These test methods shall not be used for mixtures of different powders, nor for powders containing binders or lubricants. When the powder contains agglomerates, the measured surface area may be affected by the degree of agglomeration. Methods of de-agglomeration may be used if agreed upon between the parties concerned.  
4.4 When an “average” particle size of powders is determined using either the MIC SAS or the FSSS, it should be clearly kept in mind that this average size is derived from the determination of the specific surface area of the powder using a relationship that is true only for powders of uniform size and spherical shape. Thus, the results of these methods are ...
SCOPE
1.1 These test methods cover the estimation of the average particle size in micrometres of alumina and silica powders using an air permeability method. The test methods are intended to apply to the testing of alumina and silica powders in the particle size range from 0.2 to 75 μm.  
1.2 The values stated in SI units are to be regarded as standard, with the exception of the values for density and the mass used to determine density, for which the use of the gram per cubic centimetre (g/cm3) and gram (g) units is the long-standing industry practice; and the units for pressure, cm H2O—also long-standing practice.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This test method details the standard procedures for the determination of the resistance to staining of ceramic tile surfaces. A unsanded contrasting tile grout, black carbon lamp, waterproof black ink, washable ink, potassium permanganate solution, and methylene blue solutions are the staining agents required for this test method. Also, the following materials and apparatuses are needed: plain end glass test tubes; glass pipets; an oven; lintless, absorbent clothes or paper towels; distilled or deionized water; a light source; cleaning agents; hot water; weak commercial cleaning agent not containing abrasive; strong commercial cleaning agent containing abrasive; and suitable solvents such as hydrochloric acid and potassium hydroxide solution. The resistance to staining is determined by maintaining test solutions in contact with ceramic tile surfaces for a specified period of time. After exposure, the surface is cleaned in a defined manner, and the test specimens are inspected visually for change.
SIGNIFICANCE AND USE
3.1 This test method is intended to determine the resistance to staining of tile surfaces. This test method is suitable for use in specifications, quality control, and research and development.
SCOPE
1.1 This test method covers a procedure for determining whether ceramic tiles and glass tiles are affected by prolonged exposure to staining agents.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 This test method is intended for testing tiles that are to be used for food counters, lavatories, and similar residential, medical, and commercial installations, where they may come in contact with food, chemical, and waste substances and for tile in areas where they may be exposed to contact with strong cleaning agents.
SCOPE
1.1 This test method covers a procedure for determining whether, and to what degree, ceramic tiles and glass tiles are affected by prolonged exposure to chemical substances that are commonly used in the household or for cleaning purposes as well as other more severe conditions.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.2.1 The units used for concentration in this standard are v/v, which refers to the volume of reagent/1 L of solution, and g/L, which refers to the weight of reagent, in g, to be dissolved in 1 L of water.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 This test method is intended for testing glazed ceramic tile that are to be used in areas in which they may be subjected to rapid or severe temperature changes.
SCOPE
1.1 This test method covers the determination of the resistance to thermal shock of glazed ceramic tiles under normal conditions of use.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 This test method provides a means of determining whether or not tile of the types indicated in 1.1 can be bonded with adequate strength to portland cement paste. Tile specifications can refer to this test method in order to establish minimum bond strength limits appropriate to the service conditions that are anticipated.  
5.2 Separation between bond coat and setting bed, or breakage of the setting bed itself shall not be considered failures of tile bond.
SCOPE
1.1 This test method covers the determination of the ability of ceramic tile, ceramic mosaic tile, quarry tile, porcelain tile, and paver tile to be bonded to portland cement paste. Tiles may be glazed or unglazed. This test method includes both face-mounted and back-mounted tile.  
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test method provides a means of determining whether a lot of tile meets specifications of variations in size and thickness. In specifications, the nominal size always refers to the minor facial dimension and the nominal thickness of a tile always refers to the major thickness.
SCOPE
1.1 This test method covers the determination of the facial dimensions and thickness of flat, rectangular ceramic wall and floor tile. This test method covers tile as defined in Terminology C242.  
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.