oSIST prEN 1186-14:2006

SLOVENSKI STANDARD
01-december-2006
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Materials and articles in contact with foodstuffs - Plastics - Part 14: Test methods for
'substitute tests' for overall migration from plastics intended to come into contact with
fatty foodstuffs using test media iso-octane and 95 % ethanol
Werkstoffe und Gegenstände in Kontakt mit Lebensmitteln - Kunststoffe - Teil 14:
Prüfverfahren für 'Ersatzprüfungen' für die Gesamtmigration aus Kunststoffen, die für
den Kontakt mit fettigen Lebensmitteln bestimmt sind, unter Verwendung der Prüfmedien
Iso-Octan und 95 %igem Ethanol
Matériaux et objets en contact avec les denrées alimentaires - Matiere plastique - Partie
14 : Méthodes de replacement pour la vérification de la migration globale des matieres
plastiques en contact avec des denrées alimentaires grasses dans l'iso-octane et
l'éthanol a 95 %
Ta slovenski standard je istoveten z: prEN 1186-14
ICS:
67.250 Materiali in predmeti v stiku z Materials and articles in
živili contact with foodstuffs
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EUROPEAN STANDARD
DRAFT
NORME EUROPÉENNE
EUROPÄISCHE NORM
October 2006
ICS 67.250 Will supersede EN 1186-14:2002
English Version
Materials and articles in contact with foodstuffs - Plastics - Part
14: Test methods for 'substitute tests' for overall migration from
plastics intended to come into contact with fatty foodstuffs using
test media iso-octane and 95 % ethanol
Matériaux et objets en contact avec les denrées Werkstoffe und Gegenstände in Kontakt mit Lebensmitteln
alimentaires - Matière plastique - Partie 14 : Méthodes - Kunststoffe - Teil 14: Prüfverfahren für 'Ersatzprüfungen'
d'essai pour 'des tests de substitution' pour la migration für die Gesamtmigration aus Kunststoffen, die für den
globale des matières destinées au contact avec les Kontakt mit fettigen Lebensmitteln bestimmt sind, unter
denrées alimentaires gras en utilisant les 'test media' tels Verwendung der Prüfmedien Iso-Octan und 95 %igem
que l'isoctane et l'éthanol à 95 % Ethanol
This draft European Standard is submitted to CEN members for enquiry. It has been drawn up by the Technical Committee CEN/TC 194.
If this draft becomes a European Standard, CEN members are bound to comply with the CEN/CENELEC Internal Regulations which
stipulate the conditions for giving this European Standard the status of a national standard without any alteration.
This draft European Standard was established by CEN in three official versions (English, French, German). A version in any other language
made by translation under the responsibility of a CEN member into its own language and notified to the Management Centre has the same
status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,
Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania,
Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are aware and to
provide supporting documentation.
Warning : This document is not a European Standard. It is distributed for review and comments. It is subject to change without notice and
shall not be referred to as a European Standard.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre: rue de Stassart, 36  B-1050 Brussels
© 2006 CEN All rights of exploitation in any form and by any means reserved Ref. No. prEN 1186-14:2006: E
worldwide for CEN national Members.

Contents Page
Foreword.3
1 Scope.5
2 Normative references.5
3 Total immersion method .5
3.1 Principle.5
3.2 Reagents.6
3.3 Apparatus.6
3.4 Preparation of test specimens .7
3.5 Procedure.7
3.6 Expression of results.8
3.7 Precision.8
3.8 Test report.8
4 Cell method.9
4.1 Principle.9
4.2 Reagents.9
4.3 Apparatus.9
4.4 Preparation of test specimens .10
4.5 Procedure.10
4.6 Expression of results.11
4.7 Precision.11
4.8 Test report.11
5 Pouch method.12
5.1 Principle.12
5.2 Reagents.12
5.3 Apparatus.12
5.4 Preparation of test specimens .13
5.5 Procedure.13
5.6 Expression of results.14
5.7 Precision.14
5.8 Test report.15
6 Article filling method .15
6.1 Principle.15
6.2 Reagents.15
6.3 Apparatus.15
6.4 Preparation of test specimens .16
6.5 Procedure.16
6.6 Expression of results.17
6.7 Precision.17
6.8 Test report.17
Annex A (informative) Precision data.19
Annex B (informative)  Example of a pouch holder .20
Annex ZA (informative)  Relationship of this European Standard with Regulation 1935/2004 and
Commission Directive 2002/72/EC and associated Directives .21
Bibliography .23

Foreword
This document (prEN 1186-14:2006) has been prepared by Technical Committee CEN/TC 194 “Utensils in
contact with food”, the secretariat of which is held by BSI.
This document is currently submitted to the CEN Enquiry.
This document has been prepared under a mandate given to CEN by the European Commission and the
European Free Trade Association, and supports essential requirements of EU Directive(s).
For relationship with EU Directive(s), see informative Annex ZA, which is an integral part of this document.
This document supersedes EN 1186-14:2002.
WARNING — Both iso-octane and ethanol are volatile flammable solvents. Take care to ensure that
the test specimens are well stoppered, closed and covered to prevent solvent volatilizing into the
interior of the oven, incubator or refrigerator and generating an explosive mixture. Care should be
taken at all times when handling these solvents to prevent contact with sources of ignition.
EN 1186-14 should be read in conjunction with EN 1186-1, EN 1186-3, EN 1186-5, EN 1886-7, and EN 1186-
9.
Further Parts of this standard have been prepared concerned with the determination of overall migration from
plastics materials into food simulants. Their titles are as follows:
EN 1186 Materials and articles in contact with foodstuffs – Plastics –
Part 1 Guide to the selection of conditions and test methods for overall migration
Part 2 Test methods for overall migration into olive oil by total immersion
Part 3 Test methods for overall migration into aqueous food simulants by total immersion
Part 4 Test methods for overall migration into olive oil by cell
Part 5 Test methods for overall migration into aqueous food simulants by cell
Part 6 Test methods for overall migration into olive oil using a pouch
Part 7 Test methods for overall migration into aqueous food simulants using a pouch
Part 8 Test methods for overall migration into olive oil by article filling
Part 9 Test methods for overall migration into aqueous simulants by article filling
Part 10 Test methods for overall migration into olive oil (modified method for use in case where
incomplete extraction of olive oil occurs)
Part 11 Test methods for overall migration into mixtures of C-labelled synthetic triglyceride
Part 12 Test methods for overall migration at low temperatures
Part 13 Test methods for overall migration at high temperatures
Part 15 Alternative test methods to migration into fatty food simulants by rapid extraction into iso-octane
and/or 95 % ethanol
1 Scope
This European Standard specifies test methods for 'substitute tests' performed with volatile test media, iso-
octane and 95 % v/v aqueous ethanol, for the determination of overall migration from plastics intended to
come into contact with fatty foodstuffs at all temperatures and for any period of time.
These test methods are suitable for plastics samples in a wide variety of forms.
NOTE 1 The iso-octane and 95 % v/v aqueous ethanol volatile test media used in these test methods are those
specified for 'substitute tests' in Commission Directive 82/711/EEC [3] and its subsequent amendments [4], [5]. In addition
to the use of iso-octane and 95 % v/v aqueous ethanol as test media for 'substitute tests', Commission Directive
82/711/EEC and its subsequent amendments specifies the use of modified polyphenylene oxide as a test medium for use
at temperatures of 100 °C and above. For a test method for overall migration from plastics intended to come into contact
with fatty foodstuffs using modified polyphenylene oxide as a test medium, see EN 1186-13.
NOTE 2 These test methods can also be used for the 'alternative tests' described in Council Directive 82/711/EEC and
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