Standard Specification for High-Flash Aromatic Naphthas

ABSTRACT
This specification covers two types of aromatic hydrocarbon solvents, commonly referred to as high flash aromatic naphthas, namely: Type I (Aromatic 100) and Type II (Aromatic 150). These solvents are normally petroleum distillates having moderately low volatility and are used primarily by the coatings industry. The physical and chemical properties of high-flash aromatic naphthas shall conform to the requirements specified for the following: (1) appearance, (2) color, (3) amount of aromatics, (4) copper corrosion, (5) distillation range defined by the initial boiling point and dry point, (6) flash point, (7) Kauri-butanol value, (8) mixed aniline point, (9) odor, and (10) apparent specific gravity. The sampling and test methods to determine conformance to the specified properties are given.
SCOPE
1.1 This specification covers two types of aromatic hydrocarbon solvents, normally petroleum distillates, having high flash points, moderately low volatility, and a distillation range of approximately 30°C (50°F). These solvents are used primarily by the coatings industry and are commonly referred to as high-flash aromatic naphthas.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.4 For specific hazard information and guidance, see the supplier’s Safety Data Sheet for materials listed in this specification.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

General Information

Status
Published
Publication Date
31-Oct-2018

Relations

Effective Date
01-Nov-2018
Effective Date
01-Dec-2023
Effective Date
01-Dec-2023
Effective Date
01-Oct-2023
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01-Jun-2019
Effective Date
01-Jul-2016
Effective Date
01-Jun-2016
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01-Oct-2015
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01-Oct-2014
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01-May-2013
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01-Nov-2012
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01-Dec-2011
Effective Date
01-Feb-2011
Effective Date
01-Dec-2010
Effective Date
01-Dec-2009

Overview

ASTM D3734-05(2018): Standard Specification for High-Flash Aromatic Naphthas defines requirements for two types of high-flash aromatic hydrocarbon solvents – Type I (Aromatic 100) and Type II (Aromatic 150). These aromatic naphthas are petroleum distillates characterized by high flash points, moderately low volatility, and a controlled distillation range. Used predominantly in the coatings industry, high-flash aromatic naphthas offer performance, safety, and consistency for industrial applications. This standard ensures uniform quality by specifying key physical and chemical properties that must be met for these solvents.

Key Topics

  • Material Types:

    • Type I (Aromatic 100) - Minimum flash point of 38°C (100°F)
    • Type II (Aromatic 150) - Minimum flash point of 61°C (142°F)
  • Physical and Chemical Properties Specified:

    • Appearance: Clear, free of suspended matter and undissolved water
    • Color: Not darker than +28 (Saybolt scale) or 10 (platinum-cobalt scale)
    • Aromatics Content: Minimum 95% by volume
    • Copper Corrosion: No iridescence, discoloration, or black/gray deposit
    • Distillation Range: Controlled initial boiling and dry points
    • Flash Point: Must meet or exceed specified minimums for safety
    • Kauri-Butanol Value: Minimum solvent power specified
    • Mixed Aniline Point: Indicates solvent compatibility and strength
    • Odor: As agreed between supplier and purchaser
    • Apparent Specific Gravity: Within tight limits for consistency
  • Testing and Conformance:
    Conformance is determined using recognized ASTM test methods for color, distillation, flash point, specific gravity, and more. Results must be rounded as per ASTM Practice E29.

  • Safety and Compliance:
    Users are advised to consult supplier Safety Data Sheets (SDS) for hazard information. Packaging and marking must comply with regulatory and industry requirements.

Applications

High-flash aromatic naphthas specified by ASTM D3734-05(2018) are widely utilized across several industries, with a primary role in:

  • Coatings and Paints:

    • Excellent solvency for resins and binders
    • Controlled evaporation rates prevent defects and enhance finish quality
    • Improved storage and transport safety due to high flash points
  • Industrial Cleaners and Degreasers:

    • Safe, effective removal of industrial greases, oils, and contaminants
    • Suitable where lower volatility and high aromatic content are desired
  • Chemical Manufacturing:

    • Serve as intermediates or carriers in chemical syntheses and formulations
    • Used in ink production, adhesives, and other specialty formulations
  • Other Applications:

    • Metalworking fluids
    • Rubber processing

Their carefully controlled physical properties make high-flash aromatic naphthas valuable wherever regulatory compliance, worker safety, and end-product performance are priorities.

Related Standards

Several ASTM and federal standards are referenced in or closely related to ASTM D3734-05(2018), supporting the accurate testing and use of high-flash aromatic naphthas:

  • ASTM D86: Distillation of Petroleum Products
  • ASTM D56 / D3278: Flash Point Testing
  • ASTM D1319: Aromatic Content Determination
  • ASTM D1133: Kauri-Butanol Value
  • ASTM D611: Mixed Aniline Point
  • ASTM D849: Copper Corrosion Testing
  • ASTM D156 / D1209: Color Measurement
  • ASTM D891 / D4052: Specific Gravity Determination
  • ASTM E29: Rounding-off Method for Test Data
  • ASTM E300: Sampling of Industrial Chemicals
  • U.S. Fed. Spec PPP-C-2020: Packaging Requirements

Following ASTM D3734-05(2018) and its referenced standards helps ensure consistent quality, safety, and regulatory compliance in the selection and use of high-flash aromatic naphthas in industrial processes.

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Frequently Asked Questions

ASTM D3734-05(2018) is a technical specification published by ASTM International. Its full title is "Standard Specification for High-Flash Aromatic Naphthas". This standard covers: ABSTRACT This specification covers two types of aromatic hydrocarbon solvents, commonly referred to as high flash aromatic naphthas, namely: Type I (Aromatic 100) and Type II (Aromatic 150). These solvents are normally petroleum distillates having moderately low volatility and are used primarily by the coatings industry. The physical and chemical properties of high-flash aromatic naphthas shall conform to the requirements specified for the following: (1) appearance, (2) color, (3) amount of aromatics, (4) copper corrosion, (5) distillation range defined by the initial boiling point and dry point, (6) flash point, (7) Kauri-butanol value, (8) mixed aniline point, (9) odor, and (10) apparent specific gravity. The sampling and test methods to determine conformance to the specified properties are given. SCOPE 1.1 This specification covers two types of aromatic hydrocarbon solvents, normally petroleum distillates, having high flash points, moderately low volatility, and a distillation range of approximately 30°C (50°F). These solvents are used primarily by the coatings industry and are commonly referred to as high-flash aromatic naphthas. 1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only. 1.3 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29. 1.4 For specific hazard information and guidance, see the supplier’s Safety Data Sheet for materials listed in this specification. 1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT This specification covers two types of aromatic hydrocarbon solvents, commonly referred to as high flash aromatic naphthas, namely: Type I (Aromatic 100) and Type II (Aromatic 150). These solvents are normally petroleum distillates having moderately low volatility and are used primarily by the coatings industry. The physical and chemical properties of high-flash aromatic naphthas shall conform to the requirements specified for the following: (1) appearance, (2) color, (3) amount of aromatics, (4) copper corrosion, (5) distillation range defined by the initial boiling point and dry point, (6) flash point, (7) Kauri-butanol value, (8) mixed aniline point, (9) odor, and (10) apparent specific gravity. The sampling and test methods to determine conformance to the specified properties are given. SCOPE 1.1 This specification covers two types of aromatic hydrocarbon solvents, normally petroleum distillates, having high flash points, moderately low volatility, and a distillation range of approximately 30°C (50°F). These solvents are used primarily by the coatings industry and are commonly referred to as high-flash aromatic naphthas. 1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only. 1.3 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29. 1.4 For specific hazard information and guidance, see the supplier’s Safety Data Sheet for materials listed in this specification. 1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ASTM D3734-05(2018) is classified under the following ICS (International Classification for Standards) categories: 75.100 - Lubricants, industrial oils and related products; 75.140 - Waxes, bituminous materials and other petroleum products. The ICS classification helps identify the subject area and facilitates finding related standards.

ASTM D3734-05(2018) has the following relationships with other standards: It is inter standard links to ASTM D3734-05(2010), ASTM D86-23a, ASTM D86-23ae1, ASTM D156-23, ASTM D849-15(2019)e1, ASTM D86-16, ASTM D56-16, ASTM D849-15, ASTM D1319-14, ASTM D1319-13, ASTM D156-12, ASTM D86-11b, ASTM D849-11, ASTM D1133-10, ASTM D849-09. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.

ASTM D3734-05(2018) is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.

Standards Content (Sample)


This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation:D3734 −05(Reapproved 2018)
Standard Specification for
High-Flash Aromatic Naphthas
This standard is issued under the fixed designation D3734; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope D156 Test Method for Saybolt Color of Petroleum Products
(Saybolt Chromometer Method)
1.1 This specification covers two types of aromatic hydro-
D268 Guide for Sampling and Testing Volatile Solvents and
carbon solvents, normally petroleum distillates, having high
Chemical Intermediates for Use in Paint and Related
flash points, moderately low volatility, and a distillation range
Coatings and Material
of approximately 30°C (50°F).These solvents are used primar-
D611 Test Methods for Aniline Point and Mixed Aniline
ily by the coatings industry and are commonly referred to as
Point of Petroleum Products and Hydrocarbon Solvents
high-flash aromatic naphthas.
D849 Test Method for Copper Strip Corrosion by Industrial
1.2 The values stated in SI units are to be regarded as the
Aromatic Hydrocarbons
standard. The values given in parentheses are for information
D891 TestMethodsforSpecificGravity,Apparent,ofLiquid
only.
Industrial Chemicals
D1133 Test Method for Kauri-Butanol Value of Hydrocar-
1.3 The following applies to all specified limits in this
standard; for purposes of determining conformance with this bon Solvents
D1209 Test Method for Color of Clear Liquids (Platinum-
standard, an observed value or a calculated value shall be
rounded off “to the nearest unit” in the last right-hand digit Cobalt Scale)
D1296 Test Method for Odor of Volatile Solvents and
used in expressing the specification limit, in accordance with
the rounding-off method of Practice E29. Diluents
D1319 Test Method for Hydrocarbon Types in Liquid Petro-
1.4 For specific hazard information and guidance, see the
leum Products by Fluorescent Indicator Adsorption
supplier’s Safety Data Sheet for materials listed in this speci-
D3278 Test Methods for Flash Point of Liquids by Small
fication.
Scale Closed-Cup Apparatus
1.5 This international standard was developed in accor-
D4052 Test Method for Density, Relative Density, and API
dance with internationally recognized principles on standard-
Gravity of Liquids by Digital Density Meter
ization established in the Decision on Principles for the
E29 Practice for Using Significant Digits in Test Data to
Development of International Standards, Guides and Recom-
Determine Conformance with Specifications
mendations issued by the World Trade Organization Technical
E300 Practice for Sampling Industrial Chemicals
Barriers to Trade (TBT) Committee.
2.2 U.S. Federal Specification:
PPP-C-2020 Chemicals, Liquid, Dry, and Paste: Packaging
2. Referenced Documents 3
of
2.1 ASTM Standards:
3. Classification
D56 Test Method for Flash Point by Tag Closed Cup Tester
D86 Test Method for Distillation of Petroleum Products and
3.1 High-flash aromatic naphthas shall be of the following
Liquid Fuels at Atmospheric Pressure
types, as specified:
3.1.1 Type I—Aromatic 100 (Note 1), having a flash point
not less than 38°C (100°F).
This specification is under the jurisdiction of ASTM Committee D01 on Paint 3.1.2 Type II—Aromatic 150 (Note 2), having a flash point
and Related Coatings, Materials, andApplications and is the direct responsibility of
not less than 61°C (142°F).
Subcommittee D01.35 on Solvents, Plasticizers, and Chemical Intermediates.
Current edition approved Nov. 1, 2018. Published November 2018. Originally
NOTE 1—Aromatic 100 consists primarily of C aromatic hydrocar-
approved in 1978. Last previous edition approved in 2010 as D3734 – 05 (2010).
bons.
DOI: 10.1520/D3734-05R18.
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org.
...

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