G01.04 - Corrosion of Metals in Natural Atmospheric and Aqueous Environments
Corrosion of Metals in Natural Atmospheric and Aqueous Environments
General Information
SIGNIFICANCE AND USE
3.1 This practice provides a methodology for measuring the duration of wetness on a sensing element mounted on a surface in a location of interest. Experience has shown that the sensing element reacts to factors that cause wetness in the same manner as the surface on which it is mounted.
3.2 Surface moisture plays a critical role in the corrosion of metals and the deterioration of nonmetallics. The deposition of moisture on a surface can be caused by atmospheric or climatic phenomena such as direct precipitation of rain or snow, condensation, the deliquescence (or at least the hygroscopic nature) of corrosion products or salt deposits on the surface, and others. A measure of atmospheric or climatic factors responsible for moisture deposition does not necessarily give an accurate indication of the TOW. For example, the surface temperature of an object may be above or below both the ambient and the dew point temperatures. As a result condensation will occur without an ambient meteorological indication that a surface has been subjected to a condensation cycle.
3.3 Structural design factors and orientation can be responsible for temperature differences and the consequent effect on TOW as discussed in 4.2. As a result, some surfaces may be shielded from rain or snow fall; drainage may be facilitated or prevented from given areas, and so forth. Therefore various components of a structure can be expected to perform differently depending on mass, orientation, air flow patterns, and so forth. A knowledge of TOW at different points on large structures can be useful in the interpretation of corrosion or other testing results.
3.4 In order to improve comparison of data obtained from test locations separated on a macrogeographical basis, a uniform orientation of sensor elements boldly exposed in the direction of the prevailing wind, at an angle of 30° above the horizontal is recommended. Elevation of the sensor above ground level should be recorded.
3.5 Although this...
SCOPE
1.1 This practice covers a technique for monitoring time-of-wetness (TOW) on surfaces exposed to cyclic atmospheric conditions which produce depositions of moisture.
1.2 The practice is also applicable for detecting and monitoring condensation within a wall or roof assembly and in test apparatus.
1.3 Exposure site calibration or characterization can be significantly enhanced if TOW is measured for comparison with other sites, particularly if this data is used in conjunction with other site-specific instrumentation techniques.
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard7 pagesEnglish language
SIGNIFICANCE AND USE
3.1 The procedures described herein can be used to evaluate the corrosion resistance of metals when exposed to the weather, as well as to evaluate the relative corrosivity of the atmosphere at specific locations. Because of the variability and complexity of weather effects and the industrial and natural factors influencing the atmospheric corrosivity of a test site, a multi-year exposure period should be considered to minimize their influence. Also, as corrosivity may vary at a site from season to season, exposures should be made either at the same time of the year to minimize variability or these differences should be established by multiple exposures.
3.2 Control specimens should always be employed in weathering tests. The control specimens should be from a material having established weathering characteristics. A substantial amount of corrosion data shall have been accumulated for the control specimens. It is also good practice to retain samples of all materials exposed so that possible effects of long-term aging can be measured.
SCOPE
1.1 This practice covers and defines conditions for exposure of metals and alloys to the weather. It sets forth the general procedures that should be followed in any atmospheric test. It is presented as an aid in conducting atmospheric corrosion tests so that some of the pitfalls of such testing may be avoided. As such, it is concerned mainly with panel exposures to obtain data for comparison purposes.
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of whoever uses this standard to consult and establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard6 pagesEnglish language
- Standard6 pagesEnglish language
SIGNIFICANCE AND USE
4.1 This practice gives suggested procedures for characterization of atmospheric test sites. It can be useful to researchers, manufacturers, engineering firms, architects, and construction contractors to provide corrosion and environmental data, materials selection information, and a materials storage practice.
4.2 This practice does not give specific parameters for classifying the type of test site.
SCOPE
1.1 This practice covers procedures for the characterization of atmospheric test sites. Continuous characterization can provide corrosion data, environmental data, or both which will signal changes in corrosivity of the atmospheric environment. This practice can also provide guidance for classification of future test sites.
1.2 Two methods are defined in this practice for the characterization of atmospheric test sites. The methods are identified as characterization Methods A and B. The preferred characterization technique would require using both Method A and B for concurrent data collection.
1.2.1 Method A is to be used when atmospheric corrosion is monitored on a continuing basis at a test site using specified materials and exposure configurations.
1.2.2 Method B is specified when atmospheric factors are monitored on a continuing basis.
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard5 pagesEnglish language
- Standard5 pagesEnglish language
SIGNIFICANCE AND USE
4.1 The procedures described herein are recommended for evaluating the corrosion or marine fouling behavior, or both, of materials exposed to quiescent or local tidal flow conditions, or both.
4.1.1 This practice is not intended to cover the influence of high seawater velocity or the behavior of materials in seawater which has been transported from its source.
4.1.2 Some aspects of this practice may be applicable to testing in tanks and troughs, which are continuously provided with surface seawater pumped directly from the source. Additionally, some aspects may also be applicable to deep ocean testing.
Note 1: Guide G78 provides guidance for conducting crevice corrosion tests under controlled seawater test conditions.
4.2 While the duration of testing may be dictated by the test objectives, exposures of more than six months or one year are commonly used to minimize the effects of environmental variables associated with seasonal changes or geographic location, or both. Refer also to 7.3 for test duration recommendations.
4.3 The procedures described are applicable for the exposure of simple test panels, welded test panels, or those configured to assess the effects of crevices, or both, such as those described in Guide G78. In addition, they are useful for testing of actual components and fabricated assemblies.
4.4 It is prudent to include control materials with known resistance to seawater corrosion or fouling, or both, as described in Test Method D3623.
Note 2: Materials which have been included in ASTM Worldwide Seawater Corrosivity Studies include UNS K01501 (carbon steel), UNS C70600 (90/10 CuNi) and UNS A95086 (5086-H116 Al).2, 4
Note 3: In the case of evaluations of aluminum alloys, care should be exercised in the location of specimens near copper or high copper-containing alloys. In some instances, it is not sufficient to simply electrically isolate specimens to prevent bi-metallic (galvanic) corrosion; copper ions from nearby corroding co...
SCOPE
1.1 This practice covers conditions for the exposure of metals, alloys, and other materials in natural surface seawater such as those typically found in bays, harbors, channels, and so forth,2 as contrasted with deep ocean testing.3 This practice covers full immersion, tidal zone and related splash, and spray zone exposures.2, 4
1.2 This practice sets forth general procedures that should be followed in conducting seawater exposure tests so that meaningful comparisons may be made from one location to another.
1.3 This practice identifies recommended procedures for evaluating the effects of natural surface seawater on the materials exposed.
1.4 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard4 pagesEnglish language
- Standard4 pagesEnglish language
SIGNIFICANCE AND USE
3.1 Use of this practice will maximize the benefits to be gained from atmospheric testing of metallic-coated steel. It will also aid in comparing results from one location to another where similar tests have been conducted.
SCOPE
1.1 This practice covers a procedure for recording data of atmospheric corrosion tests of metallic-coated steel specimens. Its objective is the assurance of (1) complete identification of materials before testing, (2) objective reporting of material appearance during visual inspections, and (3) adequate photographic, micrographic, and chemical laboratory examinations at specific stages of deterioration, and at the end of the tests.
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard3 pagesEnglish language
SIGNIFICANCE AND USE
4.1 This guide covers procedures for crevice-corrosion testing of iron-base and nickel-base stainless alloys in seawater. The guidance provided may also be applicable to crevice corrosion testing in other chloride containing natural waters and various laboratory prepared aqueous chloride environments.
4.1.1 While this guide focuses on testing of iron-base and nickel-base stainless alloys, the procedures and evaluations methods described herein have been successfully applied to characterize the crevice corrosion performance of other alloy systems (see, for example, Aylor et al.3).
Note 1: In the case of copper alloys, the occurrence of crevice-related corrosion associated with different corrosion mechanisms takes place immediately adjacent to the crevice former rather than within the occlusion.
4.2 This guide describes the use of a variety of crevice formers including the nonmetallic, segmented washer design referred to as the multiple crevice assembly (MCA) as described in 9.2.2.
4.3 In-service performance data provide the most reliable determination of whether a material would be satisfactory for a particular end use. Translation of laboratory data from a single test program to predict service performance under a variety of conditions should be avoided. Terms, such as immunity, superior resistance, etc., provide only a general and relatively qualitative description of an alloy's corrosion performance. The limitations of such terms in describing resistance to crevice corrosion should be recognized.
4.4 While the guidance provided is generally for the purpose of evaluating sheet and plate materials, it is also applicable for crevice-corrosion testing of other product forms, such as tubing and bars.
4.5 The presence or absence of crevice corrosion under one set of conditions is no guarantee that it will or will not occur under other conditions. Because of the many interrelated metallurgical, environmental, and geometric factors known to affect crevice...
SCOPE
1.1 This guide covers information for conducting crevice-corrosion tests and identifies factors that may affect results and influence conclusions.
1.2 These procedures can be used to identify conditions most likely to result in crevice corrosion and provide a basis for assessing the relative resistance of various alloys to crevice corrosion under certain specified conditions.
1.3 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For a specific warning statement, see 7.1.
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Guide7 pagesEnglish language
- Guide7 pagesEnglish language
SIGNIFICANCE AND USE
5.1 The small size of the wire compared to the short galvanic interaction distance in atmospheric exposures gives a large cathode-to-anode area ratio which accelerates the galvanic attack. The area between the wire and the threads creates a long, tight crevice, also accelerating the corrosion. For these reasons, this practice, with a typical exposure period of 90 days, is the most rapid atmospheric galvanic corrosion test, particularly compared to Test Method G104. The short duration of this test means that seasonal atmospheric variability can be evaluated. (If average performance over a 1-year period is desired, several staggered exposures are required with this technique.) Reproducibility of this practice is somewhat better than other atmospheric galvanic corrosion tests.
5.2 The major disadvantage of this test is that the anode material must be available in wire form and the cathodic material must be available in the form of a threaded rod. This should be compared to Test Method G104 where plate or sheet material is used exclusively.
5.3 An additional limitation is that the more anodic material of the pair must be known beforehand (from information such as in Guide G82) or assemblies must be made with the material combinations reversed.
5.4 The morphology of the corrosion attack or its effect on mechanical properties of the base materials cannot be assessed by this practice. Test Method G104 is preferable for this purpose.
5.5 This test has been used under the names CLIMAT and ATCORR to determine atmospheric corrosivity by exposing identical specimens made from 1100 aluminum (UNS A91100) wire wrapped around threaded rods of nylon, 1010 mild steel (UNS G10100 or G10080), and CA110 copper (UNS C11000). Atmospheric corrosivity is a function of the material that is corroding, however. The relative corrosivity of atmospheres could be quite different if a different combination of materials is chosen.
SCOPE
1.1 This practice covers the evaluation of atmospheric galvanic corrosion of any anodic material that can be made into a wire when in contact with a cathodic material that can be made into a threaded rod.
1.2 When certain materials are used for the anode and cathode, this practice has been used to rate the corrosivity of atmospheres.
1.3 The wire-on-bolt test was first described in 1955 (1),2 and has since been used extensively with standard materials to determine corrosivity of atmospheres under the names CLIMAT Test (CLassify Industrial and Marine ATmospheres) (2-5) and ATCORR (ATmospheric CORRosivity) (6-9).
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard5 pagesEnglish language
SIGNIFICANCE AND USE
5.1 In the past, ASTM specifications for low-alloy weathering steels, such as Specifications A242/A242M, A588/A588M, A606/A606M Type 4, A709/A709M Grade 50W, HPS 70W, and 100W, A852/A852M, and A871/A871M stated that the atmospheric corrosion resistance of these steels is “approximately two times that of carbon structural steel with copper.” A footnote in the specifications stated that “two times carbon structural steel with copper is equivalent to four times carbon structural steel without copper (Cu 0.02 maximum).” Because such statements relating the corrosion resistance of weathering steels to that of other steels are imprecise and, more importantly, lack significance to the user (1 and 2),4 the present guide was prepared to describe more meaningful methods of estimating the atmospheric corrosion resistance of weathering steels.
5.2 The first method of this guide is intended for use in estimating the expected long-term atmospheric corrosion losses of specific grades of low-alloy steels in various environments, utilizing existing short-term atmospheric corrosion data for these grades of steel.
5.3 The second method of this guide is intended for use in estimating the relative atmospheric corrosion resistance of a specific heat of low-alloy steel, based on its chemical composition.
5.4 It is important to recognize that the methods presented here are based on calculations made from test data for flat, boldly exposed steel specimens. Atmospheric corrosion rates can be much higher when the weathering steel remains wet for prolonged periods of time, or is heavily contaminated with salt or other corrosive chemicals. Therefore, caution must be exercised in the application of these methods for prediction of long-term performance of actual structures.
SCOPE
1.1 This guide presents two methods for estimating the atmospheric corrosion resistance of low-alloy weathering steels, such as those described in Specifications A242/A242M, A588/A588M, A606/A606M Type 4, A709/A709M grades 50W, HPS 70W, and 100W, A852/A852M, and A871/A871M. One method gives an estimate of the long-term thickness loss of a steel at a specific site based on results of short-term tests. The other gives an estimate of relative corrosion resistance based on chemical composition.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Guide9 pagesEnglish language
SIGNIFICANCE AND USE
3.1 This test method is capable of generating quantitative values of atmospheric chloride deposition specifying milligrams of chloride ions per square metre per day (or other units derived from such values).
Note 1: Chlorides in the atmosphere exist as a suspension of liquid droplets or solid particles. They are transported to solid surfaces by gravity, wind, or brownian motions. These transport mechanisms are direction-sensitive so that a vertical cylinder will not necessarily receive the same flux as a horizontal plate, or objects with different sizes and orientations. Therefore, the use of this approach to provide an indication of the deposition of chlorides on objects in atmospheric exposures may not be quantitatively accurate; however, this technique has been successful in classifying the severity of exposure in a variety of marine locations.
3.2 The sites where samples are to be taken and the sampling time periods should be established. A continuous program of monthly or 30-day exposures is recommended for site characterization. Seasonal monitoring may be performed if there are specific periods of interest.
SCOPE
1.1 This test method covers a wet candle device and its use in measuring atmospheric chloride deposition (amount of chloride salts deposited from the atmosphere on a given area per unit time).
1.2 Data on atmospheric chloride deposition can be useful in classifying the corrosivity of a specific area, such as an atmospheric test site. Caution must be exercised, however, to take into consideration the season because airborne chlorides vary widely between seasons.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard4 pagesEnglish language
SIGNIFICANCE AND USE
5.1 Atmospheric corrosion of metallic materials is a function of many weather and atmospheric variables. The effect of specific corrodants, such as sulfur dioxide, can accelerate the atmospheric corrosion of metals significantly. It is important to have information available for the level of atmospheric SO2 when many metals are exposed to the atmosphere in order to determine their susceptibility to corrosion damage during their life time in the atmosphere.
5.2 Volumetric analysis of atmospheric SO2 concentration carried out on a continuous basis is considered by some investigators as the most reliable method of estimating the effects caused by this gas. However, these methods require sophisticated monitoring devices together with power supplies and other equipment that make them unsuitable for many exposure sites. These methods are beyond the scope of this practice.
5.3 The sulfation plate method provides a simple technique to independently monitor the level of SO2 in the atmosphere to yield a weighted average result. The lead peroxide cylinder is similar technique that produces comparable results, and the results are more sensitive to low levels of SO2.
5.4 Sulfation plate or lead peroxide cylinder results may be used to characterize atmospheric corrosion test sites regarding the effective average level of SO2 in the atmosphere at these locations.
5.5 Either sulfation plate or lead peroxide cylinder testing is useful in determining microclimate, seasonal, and long term variations in the effective average level of SO2.
5.6 The results of these sulfur dioxide deposition rate tests may be used in correlations of atmospheric corrosion rates with atmospheric data to determine the sensitivity of the corrosion rate to SO2 level.
5.7 The sulfur dioxide monitoring methods may also be used with other methods, such as Practice G84 for measuring time of wetness and Test Method G140 for atmospheric chloride deposition, to characterize the atmosphere at sites w...
SCOPE
1.1 This practice covers two methods of monitoring atmospheric sulfur dioxide, SO2 deposition rates with specific application for estimating or evaluating atmospheric corrosivity as it applies to metals commonly used in buildings, structures, vehicles and devices used in outdoor locations.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
- Standard6 pagesEnglish language
SIGNIFICANCE AND USE
4.1 The procedures described herein are recommended for evaluating the corrosion or marine fouling behavior, or both, of materials exposed to quiescent or local tidal flow conditions, or both.
4.1.1 This practice is not intended to cover the influence of high seawater velocity or the behavior of materials in seawater which has been transported from its source.
4.1.2 Some aspects of this practice may be applicable to testing in tanks and troughs which are continuously provided with fresh surface seawater. Additionally, some aspects may also be applicable to deep ocean testing.
Note 1: Guide G78 provides guidance for conducting crevice corrosion tests under controlled seawater test conditions.
4.2 While the duration of testing may be dictated by the test objectives, exposures of more than six months or one year are commonly used to minimize the effects of environmental variables associated with seasonal changes or geographic location, or both.
4.3 The procedures described are applicable for the exposure of simple test panels, welded test panels, or those configured to assess the effects of crevices, or both, such as those described in Guide G78. In addition, they are useful for testing of actual components and fabricated assemblies.
4.4 It is prudent to include control materials with known resistance to seawater corrosion or fouling, or both, as described in Test Method D3623.
Note 2: Materials which have been included in ASTM Worldwide Seawater Corrosivity Studies include UNS K01501 (carbon steel), UNS C70600 (90/10 CuNi) and UNS A95086 (5086-H116 Al).2, 4
Note 3: In the case of evaluations of aluminum alloys, care should be exercised in the location of specimens near copper or high copper-containing alloys. In some instances, it is not sufficient to simply electrically isolate specimens to prevent bi-metallic (galvanic) corrosion; copper ions from nearby corroding copper or copper-base alloys can deposit on aluminum and accelerate its corrosion.
SCOPE
1.1 This practice covers conditions for the exposure of metals, alloys, and other materials in natural surface seawater such as those typically found in bays, harbors, channels, and so forth,2 as contrasted with deep ocean testing.3 This practice covers full immersion, tidal zone and related splash, and spray zone exposures.2, 4
1.2 This practice sets forth general procedures that should be followed in conducting seawater exposure tests so that meaningful comparisons may be made from one location to another.
1.3 This practice identifies recommended procedures for evaluating the effects of natural surface seawater on the materials exposed.
1.4 The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard4 pagesEnglish language
- Standard4 pagesEnglish language
SIGNIFICANCE AND USE
4.1 This practice gives suggested procedures for characterization of atmospheric test sites. It can be useful to researchers, manufacturers, engineering firms, architects, and construction contractors to provide corrosion and environmental data, materials selection information, and a materials storage practice.
4.2 This practice does not give specific parameters for classifying the type of test site.
SCOPE
1.1 This practice gives suggested procedures for the characterization of atmospheric test sites. Continuous characterization can provide corrosion data, environmental data, or both which will signal changes in corrosivity of the atmospheric environment. This practice can also provide guidance for classification of future test sites.
1.2 Two methods are defined in this practice for the characterization of atmospheric test sites. The methods are identified as characterization Methods A and B. The preferred characterization technique would require using both Method A and B for concurrent data collection.
1.2.1 Method A is to be used when atmospheric corrosion is monitored on a continuing basis at a test site using specified materials and exposure configurations.
1.2.2 Method B is specified when atmospheric factors are monitored on a continuing basis.
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard5 pagesEnglish language
- Standard5 pagesEnglish language
SIGNIFICANCE AND USE
3.1 The procedures described herein can be used to evaluate the corrosion resistance of metals when exposed to the weather, as well as to evaluate the relative corrosivity of the atmosphere at specific locations. Because of the variability and complexity of weather effects and the industrial and natural factors influencing the atmospheric corrosivity of a test site, a multi-year exposure period should be considered to minimize their influence. Also, as corrosivity may vary at a site from season to season, exposures should be made either at the same time of the year to minimize variability or these differences should be established by multiple exposures.
3.2 Control specimens should always be employed in weathering tests. The control specimens should be from a material having established weathering characteristics. A substantial amount of corrosion data shall have been accumulated for the control specimens. It is also good practice to retain samples of all materials exposed so that possible effects of long-term aging can be measured.
SCOPE
1.1 This practice covers and defines conditions for exposure of metals and alloys to the weather. It sets forth the general procedures that should be followed in any atmospheric test. It is presented as an aid in conducting atmospheric corrosion tests so that some of the pitfalls of such testing may be avoided. As such, it is concerned mainly with panel exposures to obtain data for comparison purposes.
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of whoever uses this standard to consult and establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard6 pagesEnglish language
- Standard6 pagesEnglish language
SIGNIFICANCE AND USE
5.1 The small size of the wire compared to the short galvanic interaction distance in atmospheric exposures gives a large cathode-to-anode area ratio which accelerates the galvanic attack. The area between the wire and the threads creates a long, tight crevice, also accelerating the corrosion. For these reasons, this practice, with a typical exposure period of 90 days, is the most rapid atmospheric galvanic corrosion test, particularly compared to Test Method G104. The short duration of this test means that seasonal atmospheric variability can be evaluated. (If average performance over a 1-year period is desired, several staggered exposures are required with this technique.) Reproducibility of this practice is somewhat better than other atmospheric galvanic corrosion tests.
5.2 The major disadvantage of this test is that the anode material must be available in wire form and the cathodic material must be available in the form of a threaded rod. This should be compared to Test Method G104 where plate or sheet material is used exclusively.
5.3 An additional limitation is that the more anodic material of the pair must be known beforehand (from information such as in Guide G82) or assemblies must be made with the material combinations reversed.
5.4 The morphology of the corrosion attack or its effect on mechanical properties of the base materials cannot be assessed by this practice. Test Method G104 is preferable for this purpose.
5.5 This test has been used under the names CLIMAT and ATCORR to determine atmospheric corrosivity by exposing identical specimens made from 1100 aluminum (UNS A91100) wire wrapped around threaded rods of nylon, 1010 mild steel (UNS G10100 or G10080), and CA110 copper (UNS C11000). Atmospheric corrosivity is a function of the material that is corroding, however. The relative corrosivity of atmospheres could be quite different if a different combination of materials is chosen.
SCOPE
1.1 This practice covers the evaluation of atmospheric galvanic corrosion of any anodic material that can be made into a wire when in contact with a cathodic material that can be made into a threaded rod.
1.2 When certain materials are used for the anode and cathode, this practice has been used to rate the corrosivity of atmospheres.
1.3 The wire-on-bolt test was first described in 1955 (1),2 and has since been used extensively with standard materials to determine corrosivity of atmospheres under the names CLIMAT Test (CLassify Industrial and Marine ATmospheres) (2-5) and ATCORR (ATmospheric CORRosivity) (6-9).
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard5 pagesEnglish language
- Standard5 pagesEnglish language
SIGNIFICANCE AND USE
3.1 Use of this practice will maximize the benefits to be gained from atmospheric testing of metallic-coated steel. It will also aid in comparing results from one location to another where similar tests have been conducted.
SCOPE
1.1 This practice covers a procedure for recording data of atmospheric corrosion tests of metallic-coated steel specimens. Its objective is the assurance of (1) complete identification of materials before testing, (2) objective reporting of material appearance during visual inspections, and (3) adequate photographic, micrographic, and chemical laboratory examinations at specific stages of deterioration, and at the end of the tests.
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard3 pagesEnglish language
- Standard3 pagesEnglish language
SIGNIFICANCE AND USE
5.1 In the past, ASTM specifications for low-alloy weathering steels, such as Specifications A242/A242M, A588/A588M, A606 Type 4, A709/A709M Grade 50W, HPS 70W, and 100W, A852/A852M, and A871/A871M stated that the atmospheric corrosion resistance of these steels is “approximately two times that of carbon structural steel with copper.” A footnote in the specifications stated that “two times carbon structural steel with copper is equivalent to four times carbon structural steel without copper (Cu 0.02 maximum).” Because such statements relating the corrosion resistance of weathering steels to that of other steels are imprecise and, more importantly, lack significance to the user (1 and 2)4, the present guide was prepared to describe more meaningful methods of estimating the atmospheric corrosion resistance of weathering steels.
5.2 The first method of this guide is intended for use in estimating the expected long-term atmospheric corrosion losses of specific grades of low-alloy steels in various environments, utilizing existing short-term atmospheric corrosion data for these grades of steel.
5.3 The second method of this guide is intended for use in estimating the relative atmospheric corrosion resistance of a specific heat of low-alloy steel, based on its chemical composition.
5.4 It is important to recognize that the methods presented here are based on calculations made from test data for flat, boldly exposed steel specimens. Atmospheric corrosion rates can be much higher when the weathering steel remains wet for prolonged periods of time, or is heavily contaminated with salt or other corrosive chemicals. Therefore, caution must be exercised in the application of these methods for prediction of long-term performance of actual structures.
SCOPE
1.1 This guide presents two methods for estimating the atmospheric corrosion resistance of low-alloy weathering steels, such as those described in Specifications A242/A242M, A588/A588M, A606 Type 4, A709/A709M grades 50W, HPS 70W, and 100W, A852/A852M, and A871/A871M. One method gives an estimate of the long-term thickness loss of a steel at a specific site based on results of short-term tests. The other gives an estimate of relative corrosion resistance based on chemical composition.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
- Guide9 pagesEnglish language
- Guide9 pagesEnglish language
SIGNIFICANCE AND USE
4.1 This guide covers procedures for crevice-corrosion testing of iron-base and nickel-base stainless alloys in seawater. The guidance provided may also be applicable to crevice corrosion testing in other chloride containing natural waters and various laboratory prepared aqueous chloride environments.
4.2 This guide describes the use of a variety of crevice formers including the nonmetallic, segmented washer design referred to as the multiple crevice assembly (MCA) as described in 9.2.2.
4.3 In-service performance data provide the most reliable determination of whether a material would be satisfactory for a particular end use. Translation of laboratory data from a single test program to predict service performance under a variety of conditions should be avoided. Terms, such as immunity, superior resistance, etc., provide only a general and relatively qualitative description of an alloy's corrosion performance. The limitations of such terms in describing resistance to crevice corrosion should be recognized.
4.4 While the guidance provided is generally for the purpose of evaluating sheet and plate materials, it is also applicable for crevice-corrosion testing of other product forms, such as tubing and bars.
4.5 The presence or absence of crevice corrosion under one set of conditions is no guarantee that it will or will not occur under other conditions. Because of the many interrelated metallurgical, environmental, and geometric factors known to affect crevice corrosion, results from any given test may or may not be indicative of actual performance in service applications where the conditions may be different from those of the test.
SCOPE
1.1 This guide covers information for conducting crevice-corrosion tests and identifies factors that may affect results and influence conclusions.
1.2 These procedures can be used to identify conditions most likely to result in crevice corrosion and provide a basis for assessing the relative resistance of various alloys to crevice corrosion under certain specified conditions.
1.3 The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For a specific warning statement, see 7.1.
- Guide7 pagesEnglish language
- Guide7 pagesEnglish language
SIGNIFICANCE AND USE
3.1 This test method is capable of generating quantitative values of atmospheric chloride deposition specifying milligrams of chloride ions per square metre per day (or other units derived from such values).
Note 1: Chlorides in the atmosphere exist as a suspension of liquid droplets or solid particles. They are transported to solid surfaces by gravity, wind, or brownian motions. These transport mechanisms are direction-sensitive so that a vertical cylinder will not necessarily receive the same flux as a horizontal plate, or objects with different sizes and orientations. Therefore, the use of this approach to provide an indication of the deposition of chlorides on objects in atmospheric exposures may not be quantitatively accurate; however, this technique has been successful in classifying the severity of exposure in a variety of marine locations.
3.2 The sites where samples are to be taken and the sampling time periods should be established. A continuous program of monthly or 30-day exposures is recommended for site characterization. Seasonal monitoring may be performed if there are specific periods of interest.
SCOPE
1.1 This test method covers a wet candle device and its use in measuring atmospheric chloride deposition (amount of chloride salts deposited from the atmosphere on a given area per unit time).
1.2 Data on atmospheric chloride deposition can be useful in classifying the corrosivity of a specific area, such as an atmospheric test site. Caution must be exercised, however, to take into consideration the season because airborne chlorides vary widely between seasons.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard4 pagesEnglish language
- Standard4 pagesEnglish language
SIGNIFICANCE AND USE
This practice provides a methodology for measuring the duration of wetness on a sensing element mounted on a surface in a location of interest. Experience has shown that the sensing element reacts to factors that cause wetness in the same manner as the surface on which it is mounted.
Surface moisture plays a critical role in the corrosion of metals and the deterioration of nonmetallics. The deposition of moisture on a surface can be caused by atmospheric or climatic phenomena such as direct precipitation of rain or snow, condensation, the deliquescence (or at least the hygroscopic nature) of corrosion products or salt deposits on the surface, and others. A measure of atmospheric or climatic factors responsible for moisture deposition does not necessarily give an accurate indication of the TOW. For example, the surface temperature of an object may be above or below both the ambient and the dew point temperatures. As a result condensation will occur without an ambient meteorological indication that a surface has been subjected to a condensation cycle.
Structural design factors and orientation can be responsible for temperature differences and the consequent effect on TOW as discussed in 4.2. As a result, some surfaces may be shielded from rain or snow fall; drainage may be facilitated or prevented from given areas, and so forth. Therefore various components of a structure can be expected to perform differently depending on mass, orientation, air flow patterns, and so forth. A knowledge of TOW at different points on large structures can be useful in the interpretation of corrosion or other testing results.
In order to improve comparison of data obtained from test locations separated on a macrogeographical basis, a uniform orientation of sensor elements boldly exposed in the direction of the prevailing wind, at an angle of 30° above the horizontal is recommended. Elevation of the sensor above ground level should be recorded.
Although this method does not develo...
SCOPE
1.1 This practice covers a technique for monitoring time-of-wetness (TOW) on surfaces exposed to cyclic atmospheric conditions which produce depositions of moisture.
1.2 The practice is also applicable for detecting and monitoring condensation within a wall or roof assembly and in test apparatus.
1.3 Exposure site calibration or characterization can be significantly enhanced if TOW is measured for comparison with other sites, particularly if this data is used in conjunction with other site-specific instrumentation techniques.
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard7 pagesEnglish language
SIGNIFICANCE AND USE
Atmospheric corrosion of metallic materials is a function of many weather and atmospheric variables. The effect of specific corrodants, such as sulfur dioxide, can accelerate the atmospheric corrosion of metals significantly. The sulfation plate method provides a simple technique to independently monitor the level of SO2 in the atmosphere to yield a weighted average result.
Sulfation plate results may be used to characterize atmospheric corrosion test sites regarding the effective average level of SO2 in the atmosphere at these locations.
Sulfation plate testing is useful in determining microclimate, seasonal, and long term variations in the effective average level of SO2.
The results of sulfation plate tests may be used in correlations of atmospheric corrosion rates with atmospheric data to determine the sensitivity of the corrosion rate to SO2 level.
The sulfation plate method may also be used with other methods to characterize the atmosphere at sites where buildings or other construction is planned in order to determine the extent of protective measures required for metallic materials.
SCOPE
1.1 This practice covers a weighted average effective SO2 level for a 30-day interval through the use of the sulfation plate method, a technique for estimating the effective SO2 content of the atmosphere, and especially with regard to the atmospheric corrosion of stationary structures or panels. This practice is aimed at determining SO2 levels rather than sulfuric acid aerosol or acid precipitation.
1.2 The results of this practice correlate approximately with volumetric SO2 concentrations, although the presence of dew or condensed moisture tends to enhance the capture of SO2 into the plate.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard6 pagesEnglish language
- Standard6 pagesEnglish language
SIGNIFICANCE AND USE
The procedures described herein can be used to evaluate the corrosion resistance of metals when exposed to the weather, as well as to evaluate the relative corrosivity of the atmosphere at specific locations. Because of the variability and complexity of weather effects and the industrial and natural factors influencing the atmospheric corrosivity of a test site, a multi-year exposure period should be considered to minimize their influence. Also, as corrosivity may vary at a site from season to season, exposures should be made either at the same time of the year to minimize variability or these differences should be established by multiple exposures.
Control specimens should always be employed in weathering tests. The control specimens should be from a material having established weathering characteristics. A substantial amount of corrosion data shall have been accumulated for the control specimens. It is also good practice to retain samples of all materials exposed so that possible effects of long-term aging can be measured.
SCOPE
1.1 This practice covers and defines conditions for exposure of metals and alloys to the weather. It sets forth the general procedures that should be followed in any atmospheric test. It is presented as an aid in conducting atmospheric corrosion tests so that some of the pitfalls of such testing may be avoided. As such, it is concerned mainly with panel exposures to obtain data for comparison purposes.
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of whoever uses this standard to consult and establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard6 pagesEnglish language
- Standard6 pagesEnglish language
SIGNIFICANCE AND USE
Atmospheric corrosion of metallic materials is a function of many weather and atmospheric variables. The effect of specific corrodants, such as sulfur dioxide, can accelerate the atmospheric corrosion of metals significantly. The sulfation plate method provides a simple technique to independently monitor the level of SO2 in the atmosphere to yield a weighted average result.
Sulfation plate results may be used to characterize atmospheric corrosion test sites regarding the effective average level of SO2 in the atmosphere at these locations.
Sulfation plate testing is useful in determining microclimate, seasonal, and long term variations in the effective average level of SO2.
The results of sulfation plate tests may be used in correlations of atmospheric corrosion rates with atmospheric data to determine the sensitivity of the corrosion rate to SO2 level.
The sulfation plate method may also be used with other methods to characterize the atmosphere at sites where buildings or other construction is planned in order to determine the extent of protective measures required for metallic materials.
SCOPE
1.1 This practice covers a weighted average effective SO2 level for a 30-day interval through the use of the sulfation plate method, a technique for estimating the effective SO2 content of the atmosphere, and especially with regard to the atmospheric corrosion of stationary structures or panels. This practice is aimed at determining SO2 levels rather than sulfuric acid aerosol or acid precipitation.
1.2 The results of this practice correlate approximately with volumetric SO2 concentrations, although the presence of dew or condensed moisture tends to enhance the capture of SO2 into the plate.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard5 pagesEnglish language
SIGNIFICANCE AND USE
This practice gives suggested procedures for characterization of atmospheric test sites. It can be useful to researchers, manufacturers, engineering firms, architects, and construction contractors to provide corrosion and environmental data, materials selection information, and a materials storage practice.
This practice does not give specific parameters for classifying the type of test site.
SCOPE
1.1 This practice gives suggested procedures for the characterization of atmospheric test sites. Continuous characterization can provide corrosion data, environmental data, or both which will signal changes in corrosivity of the atmospheric environment. This practice can also provide guidance for classification of future test sites.
1.2 Two methods are defined in this practice for the characterization of atmospheric test sites. The methods are identified as characterization Methods A and B. The preferred characterization technique would require using both Method A and B for concurrent data collection.
1.2.1 Method A is to be used when atmospheric corrosion is monitored on a continuing basis at a test site using specified materials and exposure configurations.
1.2.2 Method B is specified when atmospheric factors are monitored on a continuing basis.
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard5 pagesEnglish language
SIGNIFICANCE AND USE
Use of this practice will maximize the benefits to be gained from atmospheric testing of metallic-coated steel. It will also aid in comparing results from one location to another where similar tests have been conducted.
SCOPE
1.1 This practice covers a procedure for recording data of atmospheric corrosion tests of metallic-coated steel specimens. Its objective is the assurance of (1) complete identification of materials before testing, (2) objective reporting of material appearance during visual inspections, and (3) adequate photographic, micrographic, and chemical laboratory examinations at specific stages of deterioration, and at the end of the tests.
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard3 pagesEnglish language
SIGNIFICANCE AND USE
In the past, ASTM specifications for low-alloy weathering steels, such as Specifications A242/A242M, A588/A588M, A606 Type 4, A709/A709M Grade 50W, HPS 70W, and 100W, A852/A852M, and A871/A871M stated that the atmospheric corrosion resistance of these steels is “approximately two times that of carbon structural steel with copper.” A footnote in the specifications stated that “two times carbon structural steel with copper is equivalent to four times carbon structural steel without copper (Cu 0.02 maximum).” Because such statements relating the corrosion resistance of weathering steels to that of other steels are imprecise and, more importantly, lack significance to the user (1 and 2) , the present guide was prepared to describe more meaningful methods of estimating the atmospheric corrosion resistance of weathering steels.
The first method of this guide is intended for use in estimating the expected long-term atmospheric corrosion losses of specific grades of low-alloy steels in various environments, utilizing existing short-term atmospheric corrosion data for these grades of steel.
The second method of this guide is intended for use in estimating the relative atmospheric corrosion resistance of a specific heat of low-alloy steel, based on its chemical composition.
It is important to recognize that the methods presented here are based on calculations made from test data for flat, boldly exposed steel specimens. Atmospheric corrosion rates can be much higher when the weathering steel remains wet for prolonged periods of time, or is heavily contaminated with salt or other corrosive chemicals. Therefore, caution must be exercised in the application of these methods for prediction of long-term performance of actual structures.
SCOPE
1.1 This guide presents two methods for estimating the atmospheric corrosion resistance of low-alloy weathering steels, such as those described in Specifications A242/A242M, A588/A588M, A606 Type 4, A709/A709M grades 50W, HPS 70W, and 100W, A852/A852M, and A871/A871M. One method gives an estimate of the long-term thickness loss of a steel at a specific site based on results of short-term tests. The other gives an estimate of relative corrosion resistance based on chemical composition.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
- Guide9 pagesEnglish language
SIGNIFICANCE AND USE
The small size of the wire compared to the short galvanic interaction distance in atmospheric exposures gives a large cathode-to-anode area ratio which accelerates the galvanic attack. The area between the wire and the threads creates a long, tight crevice, also accelerating the corrosion. For these reasons, this practice, with a typical exposure period of 90 days, is the most rapid atmospheric galvanic corrosion test, particularly compared to Test Method . The short duration of this test means that seasonal atmospheric variability can be evaluated. (If average performance over a 1-year period is desired, several staggered exposures are required with this technique.) Reproducibility of this practice is somewhat better than other atmospheric galvanic corrosion tests.
The major disadvantage of this test is that the anode material must be available in wire form and the cathodic material must be available in the form of a threaded rod. This should be compared to Test Method where plate or sheet material is used exclusively.
An additional limitation is that the more anodic material of the pair must be known beforehand (from information such as in Guide G82) or assemblies must be made with the material combinations reversed.
The morphology of the corrosion attack or its effect on mechanical properties of the base materials cannot be assessed by this practice. Test Method is preferable for this purpose.
This test has been used under the names CLIMAT and ATCORR to determine atmospheric corrosivity by exposing identical specimens made from 1100 aluminum (UNS A91100) wire wrapped around threaded rods of nylon, 1010 mild steel (UNS G10100 or G10080), and CA110 copper (UNS C11000). Atmospheric corrosivity is a function of the material that is corroding, however. The relative corrosivity of atmospheres could be quite different if a different combination of materials is chosen.
SCOPE
1.1 This practice covers the evaluation of atmospheric galvanic corrosion of any anodic material that can be made into a wire when in contact with a cathodic material that can be made into a threaded rod.
1.2 When certain materials are used for the anode and cathode, this practice has been used to rate the corrosivity of atmospheres.
1.3 The wire-on-bolt test was first described in 1955 (1), and has since been used extensively with standard materials to determine corrosivity of atmospheres under the names CLIMAT Test (CLassify Industrial and Marine ATmospheres) (2-5) and ATCORR (ATmospheric CORRosivity) (6-9).
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard5 pagesEnglish language
SIGNIFICANCE AND USE
This test method is capable of generating quantitative values of atmospheric chloride deposition specifying milligrams of chloride ions per square metre per day (or other units derived from such values).
Note 1—Chlorides in the atmosphere exist as a suspension of liquid droplets or solid particles. They are transported to solid surfaces by gravity, wind, or brownian motions. These transport mechanisms are direction-sensitive so that a vertical cylinder will not necessarily receive the same flux as a horizontal plate, or objects with different sizes and orientations. Therefore, the use of this approach to provide an indication of the deposition of chlorides on objects in atmospheric exposures may not be quantitatively accurate; however, this technique has been successful in classifying the severity of exposure in a variety of marine locations.
The sites where samples are to be taken and the sampling time periods should be established. A continuous program of monthly or 30-day exposures is recommended for site characterization. Seasonal monitoring may be performed if there are specific periods of interest.
SCOPE
1.1 This test method covers a wet candle device and its use in measuring atmospheric chloride deposition (amount of chloride salts deposited from the atmosphere on a given area per unit time).
1.2 Data on atmospheric chloride deposition can be useful in classifying the corrosivity of a specific area, such as an atmospheric test site. Caution must be exercised, however, to take into consideration the season because airborne chlorides vary widely between seasons.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard4 pagesEnglish language
- Standard4 pagesEnglish language
SCOPE
1.1 This practice covers a technique for monitoring time-of-wetness (TOW) on surfaces exposed to cyclic atmospheric conditions which produce depositions of moisture.
1.2 The practice is also applicable for detecting and monitoring condensation within a wall or roof assembly and in test apparatus.
1.3 Exposure site calibration or characterization can be significantly enhanced if TOW is measured for comparison with other sites, particularly if this data is used in conjunction with other site-specific instrumentation techniques.
1.4 The values stated in SI units are to be regarded as the standard.
This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard7 pagesEnglish language
SIGNIFICANCE AND USE
The small size of the wire compared to the short galvanic interaction distance in atmospheric exposures gives a large cathode-to-anode area ratio which accelerates the galvanic attack. The area between the wire and the threads creates a long, tight crevice, also accelerating the corrosion. For these reasons, this practice, with a typical exposure period of 90 days, is the most rapid atmospheric galvanic corrosion test, particularly compared to Test Method G 104. The short duration of this test means that seasonal atmospheric variability can be evaluated. (If average performance over a 1-year period is desired, several staggered exposures are required with this technique.) Reproducibility of this practice is somewhat better than other atmospheric galvanic corrosion tests.
The major disadvantage of this test is that the anode material must be available in wire form and the cathodic material must be available in the form of a threaded rod. This should be compared to Test Method G 104 where plate or sheet material is used exclusively.
An additional limitation is that the more anodic material of the pair must be known beforehand (from information such as in Guide G 82) or assemblies must be made with the material combinations reversed.
The morphology of the corrosion attack or its effect on mechanical properties of the base materials cannot be assessed by this practice. Test Method G 104 is preferable for this purpose.
This test has been used under the names CLIMAT and ATCORR to determine atmospheric corrosivity by exposing identical specimens made from 1100 aluminum (UNS A91100) wire wrapped around threaded rods of nylon, 1010 mild steel (UNS G10100 or G10080), and CA110 copper (UNS C11000). Atmospheric corrosivity is a function of the material that is corroding, however. The relative corrosivity of atmospheres could be quite different if a different combination of materials is chosen.
SCOPE
1.1 This practice covers the evaluation of atmospheric galvanic corrosion of any anodic material that can be made into a wire when in contact with a cathodic material that can be made into a threaded rod.
1.2 When certain materials are used for the anode and cathode, this practice has been used to rate the corrosivity of atmospheres.
1.3 The wire-on-bolt test was first described in 1955 (1), and has since been used extensively with standard materials to determine corrosivity of atmospheres under the names CLIMAT Test (CLassify Industrial and Marine ATmospheres) (2-5) and ATCORR (ATmospheric CORRosivity) (6-9).
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard4 pagesEnglish language
SIGNIFICANCE AND USE
Use of this practice will maximize the benefits to be gained from atmospheric testing of metallic-coated steel. It will also aid in comparing results from one location to another where similar tests have been conducted.
SCOPE
1.1 This practice covers a procedure for recording data of atmospheric corrosion tests of metallic-coated steel specimens. Its objective is the assurance of (1) complete identification of materials before testing, (2) objective reporting of material appearance during visual inspections, and ( 3) adequate photographic, micrographic, and chemical laboratory examinations at specific stages of deterioration, and at the end of the tests.
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard3 pagesEnglish language
SIGNIFICANCE AND USE
Atmospheric corrosion of metallic materials is a function of many weather and atmospheric variables. The effect of specific corrodants, such as sulfur dioxide, can accelerate the atmospheric corrosion of metals significantly. The sulfation plate method provides a simple technique to independently monitor the level of SO2 in the atmosphere to yield a weighted average result.
Sulfation plate results may be used to characterize atmospheric corrosion test sites regarding the effective average level of SO2 in the atmosphere at these locations.
Sulfation plate testing is useful in determining microclimate, seasonal, and long term variations in the effective average level of SO2.
The results of sulfation plate tests may be used in correlations of atmospheric corrosion rates with atmospheric data to determine the sensitivity of the corrosion rate to SO2 level.
The sulfation plate method may also be used with other methods to characterize the atmosphere at sites where buildings or other construction is planned in order to determine the extent of protective measures required for metallic materials.
SCOPE
1.1 This practice covers a weighted average effective SO2 level for a 30-day interval through the use of the sulfation plate method, a technique for estimating the effective SO2 content of the atmosphere, and especially with regard to the atmospheric corrosion of stationary structures or panels. This practice is aimed at determining SO2 levels rather than sulfuric acid aerosol or acid precipitation.
1.2 The results of this practice correlate approximately with volumetric SO2 concentrations, although the presence of dew or condensed moisture tends to enhance the capture of SO2 into the plate.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard5 pagesEnglish language
SCOPE
1.1 This guide presents two methods for estimating the atmospheric corrosion resistance of low-alloy weathering steels, such as those described in Specifications A 242/A 242M, A 588/A 588M, A 606 Type 4, A 709/A 709M grades 50W, HPS 70W, and 100W, A 852/A 852M, and A 871/A 871M. One method gives an estimate of the long-term thickness loss of a steel at a specific site based on results of short-term tests. The other gives an estimate of relative corrosion resistance based on chemical composition.
- Guide8 pagesEnglish language
SIGNIFICANCE AND USE
This test method is capable of generating quantitative values of atmospheric chloride deposition specifying milligrams of chloride ions per square metre per day (or other units derived from such values).
Note 1—Chlorides in the atmosphere exist as a suspension of liquid droplets or solid particles. They are transported to solid surfaces by gravity, wind, or brownian motions. These transport mechanisms are direction-sensitive so that a vertical cylinder will not necessarily receive the same flux as a horizontal plate, or objects with different sizes and orientations. Therefore, the use of this approach to provide an indication of the deposition of chlorides on objects in atmospheric exposures may not be quantitatively accurate; however, this technique has been successful in classifying the severity of exposure in a variety of marine locations.
The sites where samples are to be taken and the sampling time periods should be established. A continuous program of monthly or 30-day exposures is recommended for site characterization. Seasonal monitoring may be performed if there are specific periods of interest.
SCOPE
1.1 This test method describes a wet candle device and its use in measuring atmospheric chloride deposition (amount of chloride salts deposited from the atmosphere on a given area per unit time).
1.2 Data on atmospheric chloride deposition can be useful in classifying the corrosivity of a specific area, such as an atmospheric test site. Caution must be exercised, however, to take into consideration the season because airborne chlorides vary widely between seasons.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard4 pagesEnglish language
SCOPE
1.1 This guide presents two methods for estimating the atmospheric corrosion resistance of low-alloy weathering steels, such as those described in Specifications A242/A242M, A588/A588M, A606 Type 4, A709/A709M grades 50W, HPS 70W, and 100W, A852/A852M, and A871/A871M. One method gives an estimate of the long-term thickness loss of a steel at a specific site based on results of short-term tests. The other gives an estimate of relative corrosion resistance based on chemical composition.
- Guide8 pagesEnglish language
SCOPE
1.1 This guide presents two methods for estimating the atmospheric corrosion resistance of low-alloy weathering steels, such as those described in Specifications A242/A242M, A588/A588M, A606 Type 4, A709/A709M grades 50W, HPS 70W, and 100W, A852/A852M, and A871/A871M. One method gives an estimate of the long-term thickness loss of a steel at a specific site based on results of short-term tests. The other gives an estimate of relative corrosion resistance based on chemical composition.
- Guide8 pagesEnglish language
SCOPE
1.1 This practice outlines a procedure for recording data of atmospheric corrosion tests of metallic-coated steel specimens. Its objective is the assurance of (1) complete identification of materials before testing, (2) objective reporting of material appearance during visual inspections, and (3) adequate photographic, micrographic, and chemical laboratory examinations at specific stages of deterioration, and at the end of the tests.
1.2 This standard may involve hazardous materials, operations, and equipment. This standard does not purport to address all of the safety problems associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard3 pagesEnglish language
SCOPE
1.1 This practice covers a technique for monitoring time-of-wetness (TOW) on surfaces exposed to cyclic atmospheric conditions which produce depositions of moisture.
1.2 The practice is also applicable for detecting and monitoring condensation within a wall or roof assembly and in test apparatus.
1.3 Exposure site calibration or characterization can be significantly enhanced if TOW is measured for comparison with other sites, particularly if this data is used in conjunction with other site-specific instrumentation techniques.
1.4 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard7 pagesEnglish language
SCOPE
1.1 This practice covers the evaluation of atmospheric galvanic corrosion of any anodic material that can be made into a wire when in contact with a cathodic material that can be made into a threaded rod.
1.2 When certain materials are used for the anode and cathode, this practice has been used to rate the corrosivity of atmospheres.
1.3 The wire-on-bolt test was first described in 1955 (1), and has since been used extensively under the name CLIMAT Test (CLassify Industrial and Marine ATmospheres) to determine corrosivity of atmospheres (2-4).
1.4 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard4 pagesEnglish language
SCOPE
1.1 This practice defines conditions for exposure of metals and alloys to the weather. It sets forth the general procedures that should be followed in any atmospheric test. It is presented as an aid in conducting atmospheric corrosion tests so that some of the pitfalls of such testing may be avoided. As such, it is concerned mainly with panel exposures to obtain data for comparison purposes.
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard5 pagesEnglish language
SCOPE
1.1 This practice gives suggested procedures for the characterization of atmospheric test sites. Continuous characteri- ization can provide corrosion data, environmental data, or both which will signal changes in corrosivity of the atmos- pheric environment. This practice can also provide guidance for classification of future test sites.
1.2 Two methods are defined in this practice for the char- acterization of atmospheric test sites. The methods are iden- tified as characterization Methods A and B. The preferred characterization technique would require using both Method A and B for concurrent data collection.
1.2.1 Method A is to be used when atmospheric corrosion is monitored on a continuing basis at a test site using specified materials and exposure configurations.
1.2.2 Method B is specified when atmospheric factors are monitored on a continuing basis.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard4 pagesEnglish language
SCOPE
1.1 This practice provides a weighted average effective SO2 level for a 30-day interval through the use of the sulfation plate method, a technique for estimating the effective SO2 content of the atmosphere, and especially with regard to the atmospheric corrosion of stationary structures or panels. This practice is aimed at determining SO2 levels rather than sulfuric acid aerosol or acid precipitation.
1.2 The results of this practice correlate approximately with volumetric SO2 concentrations, although the presence of dew or condensed moisture tends to enhance the capture of SO2 into the plate.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard4 pagesEnglish language
SCOPE
1.1 This test method describes a wet candle device and its use in measuring atmospheric chloride deposition (amount of chloride salts deposited from the atmosphere on a given area per unit time).
1.2 Data on atmospheric chloride deposition can be useful in classifying the corrosivity of a specific area, such as an atmospheric test site. caution must be exercised, however, to take into consideration the season because airborne chlorides vary widely between seasons.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard4 pagesEnglish language
SIGNIFICANCE AND USE
This practice gives suggested procedures for characterization of atmospheric test sites. It can be useful to researchers, manufacturers, engineering firms, architects, and construction contractors to provide corrosion and environmental data, materials selection information, and a materials storage practice.
This practice does not give specific parameters for classifying the type of test site. PROCEDURES Top
SCOPE
1.1 This practice gives suggested procedures for the characterization of atmospheric test sites. Continuous characterization can provide corrosion data, environmental data, or both which will signal changes in corrosivity of the atmospheric environment. This practice can also provide guidance for classification of future test sites.
1.2 Two methods are defined in this practice for the characterization of atmospheric test sites. The methods are identified as characterization Methods A and B. The preferred characterization technique would require using both Method A and B for concurrent data collection.
1.2.1 Method A is to be used when atmospheric corrosion is monitored on a continuing basis at a test site using specified materials and exposure configurations.
1.2.2 Method B is specified when atmospheric factors are monitored on a continuing basis.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard5 pagesEnglish language
SIGNIFICANCE AND USE
The procedures described herein can be used to evaluate the corrosion resistance of metals when exposed to the weather, as well as to evaluate the relative corrosivity of the atmosphere at specific locations. Because of the variability and complexity of weather effects and the industrial and natural factors influencing the atmospheric corrosivity of a test site, a multi-year exposure period should be considered to minimize their influence. Also, as corrosivity may vary at a site from season to season, exposures should be made either at the same time of the year to minimize variability or these differences should be established by multiple exposures.
Control specimens should always be employed in weathering tests. The control specimens should be from a material having established weathering characteristics. A substantial amount of corrosion data shall have been accumulated for the control specimens. It is also good practice to retain samples of all materials exposed so that possible effects of long-term aging can be measured.
SCOPE
1.1 This practice defines conditions for exposure of metals and alloys to the weather. It sets forth the general procedures that should be followed in any atmospheric test. It is presented as an aid in conducting atmospheric corrosion tests so that some of the pitfalls of such testing may be avoided. As such, it is concerned mainly with panel exposures to obtain data for comparison purposes.
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of whoever uses this standard to consult and establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
- Standard5 pagesEnglish language
SCOPE
1.1 This practice covers the evaluation of atmospheric galvanic corrosion of any materials that can be made into washers.
1.2 The washer, or disk, test was used by H. O. teeple in 1949 for a series of exposures for ASTM Committee B03.08 on Corrosion of Non-Ferrous Metals and Alloys. Since that time, ASTM has refined the test and conducted other investigations using this practice.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
WITHDRAWN RATIONALE
This practice covers the evaluation of atmospheric galvanic corrosion of any materials that can be made into washers.
Formerly under the jurisdiction of Committee G02 on Wear and Erosion, this practice was withdrawn in October 2004 because the Washer Test for Atmospheric Galvanic Corrosion is no longer used as a measure of galvanic corrosion rates.
- Standard5 pagesEnglish language
Frequently Asked Questions
G01.04 is a Technical Committee within ASTM International. It is named "Corrosion of Metals in Natural Atmospheric and Aqueous Environments". This committee has published 45 standards.
G01.04 develops ASTM standards in the area of Information technology. Currently, there are 45 published standards from this technical committee.
ASTM is a standardization organization that develops and publishes standards to support industry, commerce, and regulatory requirements.
A Technical Committee (TC) in ASTM is a group of experts responsible for developing international standards in a specific technical area. TCs are composed of national member body delegates and work through consensus to create standards that meet global industry needs. Each TC may have subcommittees (SCs) and working groups (WGs) for specialized topics.