Standard Practice for Handling, Transportation, and Storage of HFC-236fa, 1,1,1,3,3,3-Hexafluoropropane (CF<inf>3</inf>CH<inf>2</inf>CF<inf>3</inf>)

SIGNIFICANCE AND USE
4.1 This practice provides requirements for the handling, transportation, and storage of HFC-236fa encountered in distribution through both commercial and military channels. It is intended to ensure that HFC-236fa is handled, transported, and stored in such a way its physical properties are not degraded. Transport may be by various means, such as, but not limited to, highway, rail, water, and air.
SCOPE
1.1 This practice covers guidance and direction to suppliers, purchasers, and users in the handling, transportation, and storage of HFC-236fa.  
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

General Information

Status
Published
Publication Date
31-May-2021

Relations

Effective Date
01-Aug-2011
Effective Date
01-Jun-2005
Effective Date
10-Apr-2000

Overview

ASTM D6427-21 provides comprehensive guidance for the safe and effective handling, transportation, and storage of HFC-236fa (1,1,1,3,3,3-Hexafluoropropane, CF₃CH₂CF₃). As a halogenated hydrocarbon widely used as a fire suppressant and explosion hazard inerting agent, HFC-236fa requires careful management to preserve its physical integrity throughout commercial and military distribution channels. The standard supports quality, safety, and regulatory compliance across the entire supply chain by identifying essential requirements specific to HFC-236fa.

Key Topics

  • Scope of Application: The standard applies to suppliers, purchasers, users, distributors, recyclers, and reclaimers involved in the lifecycle of HFC-236fa.
  • Physical Integrity: Emphasizes maintaining the chemical and physical properties of HFC-236fa during all operations.
  • Personnel Training: Requires that employees are trained per applicable Compressed Gas Association (CGA) publications and U.S. Department of Transportation (DOT) regulations.
  • Container Handling:
    • Use of suitable, clean, and approved containers or cylinders.
    • Prohibition of overfilling and stringent controls on transfer processes.
  • Transportation:
    • Shipment in accordance with DOT regulations for hazardous materials, specifically addressing packaging, vessel pressure, and labeling requirements.
    • Suitable vehicle selection and protection of cylinders from vibration, temperature extremes, and physical shock.
  • Storage Recommendations:
    • Storing cylinders in environmentally protected, secure locations.
    • Use of pressure relief devices and routine inspection to ensure continued compliance and integrity.
    • Segregation and clear labeling, particularly when storing reclaimed or non-conforming materials.
  • Inspection and Reclamation:
    • Guidelines for testing and approving reclaimed HFC-236fa prior to reuse.
    • Requirements for processing non-conforming product in an environmentally responsible manner.

Applications

HFC-236fa is critical in various sectors, especially for:

  • Fire Suppression Systems: Used for inerting and suppressing fires or explosion hazards in sensitive environments.
  • Aerospace and Defense: Employed in military vehicles, aircraft, and installations where reliable extinguishing agents are crucial.
  • Industrial Safety: Deployed across manufacturing facilities and data centers requiring advanced fire protection.

Correct implementation of ASTM D6427-21 ensures:

  • Safe Operations: Minimizing risks associated with compressed liquefied gases.
  • Regulatory Compliance: Meeting CFR Title 49 and EPA regulatory mandates on hazardous materials.
  • Product Quality: Maintaining the purity and efficiency of HFC-236fa throughout storage, handling, and transport.

Related Standards

For a comprehensive approach, ASTM D6427-21 should be used in conjunction with related standards and regulations, including:

  • ASTM D6541: Specification for HFC-236fa, providing technical details for material compliance.
  • CGA Publications:
    • CGA P-1 - Safe Handling of Compressed Gases in Containers.
    • CGA C-1 - Pressure Testing Methods.
    • CGA C-6 - Visual Inspection of Cylinders.
    • CGA C-7 - Classification and Labeling Guidance.
    • CGA SB-1 and SB-18 - Safety bulletins on recovery cylinders.
  • U.S. Department of Transportation:
    • 49 CFR 173, 178, 180 - Shipping, packaging, marking, and maintenance of hazardous materials.
  • Environmental Protection Agency:
    • 40 CFR Part 82.106 - Warning statement requirements for ozone-depleting substances.

Practical Value

By adhering to ASTM D6427-21, organizations benefit from:

  • Enhanced workplace and environmental safety when handling hazardous refrigerants and fire suppressants.
  • Consistent product performance through preservation of HFC-236fa purity.
  • Efficient and compliant logistics for hazardous materials requiring multi-modal transportation.
  • Reduction in liability and risk due to adherence to internationally recognized best practices for storage and movement of compressed gases.

Implementing this standard supports operational excellence and satisfies both industry and regulatory stakeholder expectations for the safe handling of HFC-236fa.

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ASTM D6427-21 - Standard Practice for Handling, Transportation, and Storage of HFC-236fa, 1,1,1,3,3,3-Hexafluoropropane (CF<inf>3</inf>CH<inf>2</inf>CF<inf>3</inf>)

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Frequently Asked Questions

ASTM D6427-21 is a standard published by ASTM International. Its full title is "Standard Practice for Handling, Transportation, and Storage of HFC-236fa, 1,1,1,3,3,3-Hexafluoropropane (CF<inf>3</inf>CH<inf>2</inf>CF<inf>3</inf>)". This standard covers: SIGNIFICANCE AND USE 4.1 This practice provides requirements for the handling, transportation, and storage of HFC-236fa encountered in distribution through both commercial and military channels. It is intended to ensure that HFC-236fa is handled, transported, and stored in such a way its physical properties are not degraded. Transport may be by various means, such as, but not limited to, highway, rail, water, and air. SCOPE 1.1 This practice covers guidance and direction to suppliers, purchasers, and users in the handling, transportation, and storage of HFC-236fa. 1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE 4.1 This practice provides requirements for the handling, transportation, and storage of HFC-236fa encountered in distribution through both commercial and military channels. It is intended to ensure that HFC-236fa is handled, transported, and stored in such a way its physical properties are not degraded. Transport may be by various means, such as, but not limited to, highway, rail, water, and air. SCOPE 1.1 This practice covers guidance and direction to suppliers, purchasers, and users in the handling, transportation, and storage of HFC-236fa. 1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ASTM D6427-21 is classified under the following ICS (International Classification for Standards) categories: 13.220.10 - Fire-fighting; 71.080.20 - Halogenated hydrocarbons. The ICS classification helps identify the subject area and facilitates finding related standards.

ASTM D6427-21 has the following relationships with other standards: It is inter standard links to ASTM D6541-11, ASTM D6541-05, ASTM D6541-00. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.

ASTM D6427-21 is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.

Standards Content (Sample)


This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D6427 −21
Standard Practice for
Handling, Transportation, and Storage of HFC-236fa,
1,1,1,3,3,3-Hexafluoropropane (CF CH CF )
3 2 3
This standard is issued under the fixed designation D6427; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope P-1 Standard for Safe Handling of Compressed Gases in
Containers
1.1 This practice covers guidance and direction to suppliers,
SB-1 Hazards of Refilling or Reusing Compressed Refrig-
purchasers, and users in the handling, transportation, and
erant (Halogenated Hydrocarbon) Gas Cylinders
storage of HFC-236fa.
SB-18 Use of Refrigerant (Halogenated Hydrocarbons) Re-
1.2 The values stated in inch-pound units are to be regarded
covery Cylinders
as standard. The values given in parentheses are mathematical
2.3 U.S. Government Standards:
conversions to SI units that are provided for information only
49 CFR Part 172 Hazardous Materials Table, Special
and are not considered standard.
Provisions, Hazardous Materials Communications, Emer-
1.3 This standard does not purport to address all of the
gency Response Information, Training Requirements, and
safety concerns, if any, associated with its use. It is the
Security Plans
responsibility of the user of this standard to establish appro-
49 CFR Part 172.101 Purpose and Use of Hazardous Mate-
priate safety, health, and environmental practices and deter-
rials Table
mine the applicability of regulatory limitations prior to use.
49 CFR Part 173 Shippers—General Requirements for Ship-
1.4 This international standard was developed in accor-
ments and Packagings
dance with internationally recognized principles on standard-
49 CFR Part 178 Specifications for Packagings
ization established in the Decision on Principles for the
49 CFR Part 180 Continuing Qualification and Maintenance
Development of International Standards, Guides and Recom-
of Packagings
mendations issued by the World Trade Organization Technical
Barriers to Trade (TBT) Committee.
3. Terminology
2. Referenced Documents
3.1 Definitions of Terms Specific to This Standard:
3.1.1 containers, n—storage vessel for HFC-236fa.
2.1 ASTM Standard:
D6541 Specification for HFC-236fa, 1,1,1,3,3, 3.1.2 cylinders, n—containers of HFC-236fa.
3–Hexafluoropropane, (CF CH CF )
3 2 3
3.1.3 HFC-236fa, n—1,1,1,3,3,3-hexafluoropropane,acom-
2.2 CGA Standards:
pound used to inert or suppress a fire or explosion hazard.
C-1 Methods for Pressure Testing Compressed Gas Cylin-
3.1.4 insulated, adj—placed in an isolated situation to pro-
ders
tect and prevent the transfer of damage.
C-6 Standards for Visual Inspection of Steel Compressed
Gas Cylinders
4. Significance and Use
C-7 Guide to Classification and Labeling of Compressed
4.1 This practice provides requirements for the handling,
Gases
transportation, and storage of HFC-236fa encountered in dis-
tribution through both commercial and military channels. It is
This practice is under the jurisdiction of ASTM Committee D26 on Haloge-
intended to ensure that HFC-236fa is handled, transported, and
nated Organic Solvents and Fire Extinguishing Agents and is the direct responsi-
bility of Subcommittee D26.09 on Fire Extinguishing Agents.
stored in such a way its physical properties are not degraded.
Current edition approved June 1, 2021. Published June 2021. Originally
Transportmaybebyvariousmeans,suchas,butnotlimitedto,
approved in 1999. Last previous edition approved in 2016 as D6427-16. DOI:
highway, rail, water, and air.
10.1520/D6427-21.
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Standards volume information, refer to the standard’s Document Summary page on
the ASTM website. Code of Federal Regulations (CFR) documents are available from U.S.
Available from Compressed Gas Association (CGA), 8484 Westpark Drive, Government Publishing Office (GPO), 732 N. Capitol St., NW, Washington, DC
Suite 220, McLean, VA 22102, http://www.cganet.com. 20401, http://www.gpo.gov.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
D6427 − 21
5. Practice 5.3.1.2 The minimum design pressure requirements shall be
as stated in 49 CFR Part 173.301. The pressure inside the
5.1 To ensure safe handling, loading, unloading, storing,
container at 70 °F (21 °C) shall not exceed the service pressure
and transporting of material, personnel shall be trained in the
for which the container is marked. The pressure inside the
CGA publications and 49 CFR regulations as listed in 2.2 and
container at 130 °F (54 °C) shall not exceed ⁄4 the service
2.3, respectively.
pressure for which the container is marked. Fig. 1 illustrate the
5.2 Handling:
saturated vapor pressure of HFC-236fa. Fig. 2 and Fig. 3
5.2.1 Handling shall be in accordance with CGA Publica-
illustrate the effect of temperature on cylinders filled with
tion P-1.
HFC-236fa and super pressurized with nitrogen at 70 °F
5.2.1.1 Personnel who handle or store, or both, cylinders of
(21 °C) to 360 psig (25.8 bar) and 600 psig (42.4 bar),
HFC-236fa shall be trained properly to recognize and identify
respectively.
the characteristics of the product and the proper methods of
5.3.2 Transportation shall be in suitable vehicles to preclude
safely handling full, partly full, and empty cylinders.
cylinder damage by excessive mechanical vibration, shock,
5.2.2 All HFC-236fa transfers between storage containers
freezing,ordeleterioushightemperaturesthroughouttheentire
and recycling processes shall be performed by personnel
transport route.
trained in handling procedures.
5.3.2.1 If cylinders are expected to be subject to unaccept-
5.2.3 The HFC-236fa recycling and transfer processes shall
able transport con
...


This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D6427 − 16 D6427 − 21
Standard Practice for
Handling, Transportation, and Storage of HFC-236fa,
1,1,1,3,3,3-Hexafluoropropane (CF CH CF )
3 2 3
This standard is issued under the fixed designation D6427; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1 This practice covers guidance and direction to suppliers, purchasers, and users in the handling, transportation, and storage of
HFC–236fa.HFC-236fa.
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical
conversions to SI units that are provided for information only and are not considered standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety safety, health, and healthenvironmental practices and determine the
applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents
2.1 ASTM Standards:
D6541 Specification for HFC-236fa, 1,1,1,3,3,3–Hexafluoropropane, (CF CH CF )
3 2 3
2.1 ASTM Standard:
D6541 Specification for HFC-236fa, 1,1,1,3,3,3–Hexafluoropropane, (CF CH CF )
3 2 3
2.2 CGA Standards:
C-1 Methods for Pressure Testing Compressed Gas Cylinders
C-6 Standards for Visual Inspection of Steel Compressed Gas Cylinders
C-7 Guide to Classification and Labeling of Compressed Gases
P-1 Standard for Safe Handling of Compressed Gases in Containers
SB-1 Safety Bulletin: Hazards of Refilling or Reusing Compressed Refrigerant (Halogenated Hydrocarbon) Gas Cylinders
SB-18 Use of Refrigerant (Halogenated Hydrocarbon)Hydrocarbons) Recovery Cylinders
This practice is under the jurisdiction of ASTM Committee D26 on Halogenated Organic Solvents and Fire Extinguishing Agents and is the direct responsibility of
Subcommittee D26.09 on Fire Extinguishing Agents.
Current edition approved July 1, 2016June 1, 2021. Published July 2016June 2021. Originally approved in 1999. Last previous edition approved in 20102016 as
D6427/D6427MD6427-10.-16. DOI: 10.1520/D6427-16.10.1520/D6427-21.
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’sstandard’s Document Summary page on the ASTM website.
Available from Compressed Gas Association (CGA), 14501 George Carter Way, Suite 103, Chantilly, VA 20151,8484 Westpark Drive, Suite 220, McLean, VA 22102,
http://www.cganet.com.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
D6427 − 21
2.3 U.S. Government Standards:
Code of Federal Regulations (CFR) Title 40, Part 82.106 Environmental Protection Agency, Warning Statement Requirements
49 CFR Title 49, Part 172 U.S. Department of Transportation (DOT), Hazardous Materials Table, Special Provisions, Hazardous
Materials Communications, Emergency Response Information, and Training RequirementsTraining Requirements, and
Security Plans
49 CFR Title 49, Part 172.101 U.S. DOT, TablesPurpose and Use of Hazardous Materials and Special ProvisionsTable
49 CFR Title 49, Part 173 U.S. DOT, Shippers-General Shippers—General Requirements for ShippingShipments and
Packagings
49 CFR Title 49, Part 178 U.S. DOT, Specifications for Packagings
49 CFR Title 49, Part 180 U.S. DOT, Continuing Qualification and Maintenance of PackagesPackagings
3. Terminology
3.1 Definitions of Terms Specific to This Standard:
3.1.1 containers, n—storage vessel for HFC-236fa.
3.1.2 cylinders, n—containers of HFC-236fa.
3.1.3 HFC-236fa, n—1,1,1,3,3,3-hexafluoropropane, a compound used to inert or suppress a fire or explosion hazard.
3.1.4 insulated, v—adj—placed in an isolated situation to protect and prevent the transfer of damage.
4. Significance and Use
4.1 This practice provides requirements for the handling, transportation, and storage of HFC–236faHFC-236fa encountered in
distribution through both commercial and military channels. It is intended to ensure that HFC-236fa is handled, transported, and
stored in such a way its physical properties are not degraded. Transport may be by various means, such as, but not limited to,
highway, rail, water, and air.
5. Practice
5.1 To ensure safe handling, loading, unloading, storing, and transporting of material, personnel shall be trained in the CGA
publications and Title 49 CFR regulations as listed in 2.2 and 2.3, respectively.
5.2 Handling:
5.2.1 Handling shall be in accordance with P-1, Safe Handling of Compressed Gases in Containers.CGA Publication P-1.
5.2.1.1 Personnel who handle or store, or both, cylinders of HFC-236fa shall be trained properly to recognize and identify the
characteristics of the product and the proper methods of safely handling full, partly full, and empty cylinders.
5.2.2 All HFC-236fa transfers between storage containers and recycling processes shall be performed by personnel trained in
handling procedures.
5.2.2.1 Facility personnel must be trained in applicable Code of Federal Regulations (CFR) Title 49, Part 173 and Code of Federal
Regulations (CFR) Title 49, Part 178, and the CGA documents referenced in 2.2.
5.2.3 The HFC-236fa recycling and transfer processes shall be in conjunction with the equipment specified by the manufacturer.
5.2.4 The handling of HFC-236fa shall be in nonsmoking, heater-free, ventilated areas to preclude product accumulation.
Provisions shall be made to ensure that service areas limit area HFC-236fa concentrations todo not exceed 15 % for 1 min and
0.1 % for 8 h.8 h.
5.2.5 Cylinders shall not be over filled. The liquid portion of the liquefied gases must not completely fill the container’s internal
Available Code of Federal Regulations (CFR) documents are available from U.S. Government Publishing Office, Office (GPO), 732 N. Capitol St., NW, Washington,
DC 20401-0001,20401, http://www.gpo.gov.
D6427 − 21
volume at any temperature up to and including 130°F (54°C).130 °F (54 °C). The maximum permitted filling density for
3 3
HFC-236fa shall be 78 lb/ft (1249 kg/m ). The maximum permitted filling density for HFC-236fa pressurized with nitrogen to
3 3
360 psig (25.8 bar)
...

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