Standard Specification for <emph type="bdit">n</emph>-Butyl Alcohol (Butanol)

ABSTRACT
This specification covers n-butyl alcohol (butanol). The apparent specific gravity, color, distillation range, non-volatile matter, water properties, and acidity shall be tested to meet the requirements prescribed.
SCOPE
1.1 This specification covers n-butyl alcohol (butanol).  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 The following applies to all specified limits in this standard: for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.4 For hazard information and guidance, see the supplier's Material Safety Data Sheets.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

General Information

Status
Published
Publication Date
31-Mar-2019

Relations

Effective Date
01-Apr-2019
Effective Date
01-Jun-2012
Effective Date
15-Nov-2011
Effective Date
01-Jan-2010
Effective Date
01-Jun-2009
Effective Date
01-Apr-2009
Effective Date
01-Oct-2008
Effective Date
01-Jun-2007
Effective Date
01-Jun-2007
Effective Date
01-Jun-2007
Effective Date
15-Nov-2006
Effective Date
15-Sep-2006
Effective Date
01-May-2006
Effective Date
01-Apr-2006
Effective Date
15-Oct-2005

Overview

ASTM D304-11(2019), titled Standard Specification for n-Butyl Alcohol (Butanol), is an internationally recognized standard developed by ASTM International. This specification defines the quality and properties required for n-butyl alcohol (butanol), ensuring consistency for its use in industrial applications. It provides requirements for major chemical and physical properties, including specific gravity, color, distillation range, non-volatile content, water content, and acidity, all measured in SI units.

n-Butyl alcohol, also known as 1-butanol or propyl carbinol, is a versatile chemical intermediate widely used in the production of paints, coatings, plasticizers, and solvents. Compliance with ASTM D304 enables industries to achieve product purity and performance standards, while aligning with global trade and regulatory frameworks.

Key Topics

  • Material Specification: The standard provides precise criteria for n-butyl alcohol, including specific gravity (measured at 20/20 °C or 25/25 °C), maximum allowed color (Pt-Co scale), and narrow distillation ranges to ensure material consistency.
  • Test Methods: Quality assurance relies on referenced ASTM test methods, covering:
    • Apparent specific gravity
    • Color determination
    • Distillation range
    • Non-volatile matter content
    • Water determination
    • Acidity testing
  • Sampling Practices: Guidance for representative sampling is provided, crucial for reliable verification of compliance.
  • Packaging and Labeling: The standard outlines general requirements for safe and agreed-upon packaging, including conformity with transport and federal specifications.
  • Conformance: Details on rounding and reporting data ensure uniform interpretation of quantitative limits across industries.

Applications

n-Butyl alcohol certified to ASTM D304-11(2019) is critical in a range of industries and technical applications:

  • Paints and Coatings: Used as a solvent and chemical intermediate for uniform formulation and processing.
  • Plasticizers and Chemical Synthesis: Ensures the input material quality required for the production of esters and other chemical products.
  • Solvent Manufacturing: Provides a benchmark for supply chain integrity in production of high-purity solvents.
  • Quality Assurance and Trade: Enables buyers and sellers to reference standardized material requirements, facilitating domestic and international commerce.
  • Research and Development: Offers a tested foundation for product development where material consistency and traceable properties are essential.

Adherence to ASTM D304 helps manufacturers, suppliers, and regulatory agencies ensure that n-butyl alcohol meets stringent performance, safety, and compatibility requirements.

Related Standards

ASTM D304-11(2019) references several related ASTM standards and federal specifications essential for testing and product verification, including:

  • ASTM D268: Guide for Sampling and Testing Volatile Solvents
  • ASTM D891, D4052: Test Methods for Specific Gravity and Density
  • ASTM D1078: Test Method for Distillation Range of Volatile Organic Liquids
  • ASTM D1209, D5386: Methods for Color Determination of Liquids
  • ASTM D1353: Test Method for Nonvolatile Matter in Solvents
  • ASTM D1364, D1476: Test Methods for Water Content in Volatile Solvents
  • ASTM D1613: Test Method for Acidity in Volatile Solvents
  • ASTM E29: Practice for Rounding-Off Test Data
  • ASTM E300: Practice for Sampling Industrial Chemicals
  • U.S. Fed. Spec. PPP-C-2020: Packaging specifications for chemicals

By following ASTM D304, organizations maintain high standards of quality, safety, and regulatory compliance in the sourcing and use of n-butyl alcohol (butanol) across industries.

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ASTM D304-11(2019) - Standard Specification for <emph type="bdit">n</emph>-Butyl Alcohol (Butanol)

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Frequently Asked Questions

ASTM D304-11(2019) is a technical specification published by ASTM International. Its full title is "Standard Specification for <emph type="bdit">n</emph>-Butyl Alcohol (Butanol)". This standard covers: ABSTRACT This specification covers n-butyl alcohol (butanol). The apparent specific gravity, color, distillation range, non-volatile matter, water properties, and acidity shall be tested to meet the requirements prescribed. SCOPE 1.1 This specification covers n-butyl alcohol (butanol). 1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.3 The following applies to all specified limits in this standard: for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29. 1.4 For hazard information and guidance, see the supplier's Material Safety Data Sheets. 1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT This specification covers n-butyl alcohol (butanol). The apparent specific gravity, color, distillation range, non-volatile matter, water properties, and acidity shall be tested to meet the requirements prescribed. SCOPE 1.1 This specification covers n-butyl alcohol (butanol). 1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.3 The following applies to all specified limits in this standard: for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29. 1.4 For hazard information and guidance, see the supplier's Material Safety Data Sheets. 1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ASTM D304-11(2019) is classified under the following ICS (International Classification for Standards) categories: 71.080.60 - Alcohols. Ethers. The ICS classification helps identify the subject area and facilitates finding related standards.

ASTM D304-11(2019) has the following relationships with other standards: It is inter standard links to ASTM D304-11, ASTM D1613-06(2012), ASTM D1078-11, ASTM D5386-10, ASTM D1353-09, ASTM D891-09, ASTM E29-08, ASTM D268-01(2007), ASTM D1476-02(2007), ASTM D1364-02(2007), ASTM E29-06b, ASTM E29-06a, ASTM E29-06, ASTM D1613-06, ASTM D5386-05. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.

ASTM D304-11(2019) is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.

Standards Content (Sample)


This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D304 −11 (Reapproved 2019)
Standard Specification for
n-Butyl Alcohol (Butanol)
This standard is issued under the fixed designation D304; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope D1353 Test Method for Nonvolatile Matter in Volatile Sol-
vents for Use in Paint, Varnish, Lacquer, and Related
1.1 This specification covers n-butyl alcohol (butanol).
Products
1.2 The values stated in SI units are to be regarded as
D1364 Test Method for Water in Volatile Solvents (Karl
standard. No other units of measurement are included in this
Fischer Reagent Titration Method)
standard.
D1476 Test Method for Heptane Miscibility of Lacquer
1.3 The following applies to all specified limits in this Solvents
D1613 Test Method for Acidity in Volatile Solvents and
standard: for purposes of determining conformance with this
standard, an observed value or a calculated value shall be Chemical Intermediates Used in Paint, Varnish, Lacquer,
and Related Products
rounded off “to the nearest unit” in the last right-hand digit
used in expressing the specification limit, in accordance with D4052 Test Method for Density, Relative Density, and API
Gravity of Liquids by Digital Density Meter
the rounding-off method of Practice E29.
D5386 Test Method for Color of Liquids Using Tristimulus
1.4 For hazard information and guidance, see the supplier’s
Colorimetry
Material Safety Data Sheets.
E29 Practice for Using Significant Digits in Test Data to
1.5 This international standard was developed in accor-
Determine Conformance with Specifications
dance with internationally recognized principles on standard-
E300 Practice for Sampling Industrial Chemicals
ization established in the Decision on Principles for the
2.2 U.S. Federal Specification:
Development of International Standards, Guides and Recom-
PPP-C-2020 Chemicals, Liquid, Dry, and Paste: Packaging
mendations issued by the World Trade Organization Technical
of
Barriers to Trade (TBT) Committee.
3. Properties
2. Referenced Documents
2 3.1 n-butyl alcohol (butanol) shall conform to the following
2.1 ASTM Standards:
requirements:
D268 Guide for Sampling and Testing Volatile Solvents and
Apparent specific gravity:
Chemical Intermediates for Use in Paint and Related
20/20 °C 0.810 to 0.813
Coatings and Material
or
D891 TestMethodsforSpecificGravity,Apparent,ofLiquid
25/25 °C 0.807 to 0.810
A
Color, Pt-Co scale, max 10
Industrial Chemicals
B
Distillation range, 760 mmHg
D1078 Test Method for Distillation Range of Volatile Or-
Nonvolatile matter, max, mg/100 mL 5
C
ganic Liquids
Water, max, weight % 0.1
D
Acidity, as acetic acid, max, weight % 0.005
D1209 Test Method for Color of Clear Liquids (Platinum-
______________
Cobalt Scale)
A
Instrumental Pt-Co color determined by Test Method D5386 has been shown to
have no statistically significant difference from Pt-Co color determined by Test
This specification is under the jurisdiction of the ASTM Committee D01 on
Method D1209. However, it is not known whether n-butyl alcohol was part of the
Paint and Related Coatings, Materials, and Applications and is the direct respons
...

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