D02.02.08 - Sampling (API MPMS Chapter 8.0)

SIGNIFICANCE AND USE
4.1 Representative samples of petroleum and petroleum products are required for the determination of chemical and physical properties used to establish standard volumes, prices, and compliance with commercial and regulatory specifications. The treatment of samples from the time of collection until they are analyzed requires care and effort to maintain their compositional integrity. Samples of high RVP (unstabilized) hydrocarbons are required at many measurement points, for example offshore production, at the outlets of test separators or to allow calibration of a flowmeter. This practice also describes requirements associated with handling and mixing samples held within pressurized cylinders.  
4.2 Practice D4057 (API MPMS Chapter 8.1), Practice D4177 (API MPMS Chapter 8.2), Practice D5854 (API MPMS Chapter 8.3), Practice D5842 (API MPMS Chapter 8.4), and Practice D8009 (API MPMS Chapter 8.5). The primary purpose of this suite of standards, is to ensure proper sampling and handling for custody transfer applications. There are a significant number of test methods that may be used to analyze the samples taken by techniques described in API MPMS Chapter 8.1 and 8.2. For samples that are taken for test methods outside the general scope of custody transfer covered by this practice, the personnel assigned to take the sample are responsible to refer to the test methods for additional critical information that may impact the sampling process, that is, specific container selection, transport methods, storage times, etc. Those requirements should be found in the appropriate test method.
SCOPE
1.1 This practice covers handling, mixing, and conditioning procedures that are required to ensure that a representative sample of the liquid petroleum or petroleum product is delivered from the primary sample container or container or both into the analytical apparatus or into intermediate containers.  
1.2 Appendix X1 details the background information on the development of Table 1 used in performance testing. Appendix X2 provides guidance in the acceptance testing for water in crude oil. Appendix X3 provides a guide for materials of sample containers. Appendix X4 provides a summary of recommended mixing procedures. Appendix X5 provides a flow chart for sample container/mixing system acceptance test.  
1.3 For sampling procedures, refer to Practices D4057 (API MPMS Chapter 8.1) and D4177 (API MPMS Chapter 8.2). Practice D5842 (API MPMS Chapter 8.4) covers sampling and handling of light fuels for volatility measurement, and D8009 (API MPMS Chapter 8.5).  
1.4 It is recommended that the users of this practice perform the tests in Practice D4177 (API MPMS Chapter 8.2) before performing the test in this practice.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 The dry vapor pressure equivalent (DVPE) of volatile motor fuels is regulated by federal and state air pollution control agencies. In order to meet the letter of these regulations, it is necessary to sample, handle, and test these products in the precise manner as prescribed in this practice.
SCOPE
1.1 This practice covers procedures and equipment for obtaining, mixing, and handling representative samples of volatile fuels for the purpose of testing for compliance with the standards set forth for volatility related measurements applicable to light fuels. The applicable dry vapor pressure equivalent range of this practice is 13 to 105 kPa (2 to 16 psia).  
1.2 This practice is applicable to the sampling, mixing, and handling of reformulated fuels including those containing oxygenates.  
1.3 The values stated in SI units are to be regarded as the standard except in some cases where drawings may show inch-pound measurements which are customary for that equipment.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SIGNIFICANCE AND USE
Representative samples of petroleum and petroleum products are required for the determination of chemical and physical properties used to establish standard volumes, prices, and compliance with commercial and regulatory specifications. The treatment of samples from the time of collection until they are analyzed requires care and effort to maintain their compositional integrity.
SCOPE
1.1 This practice covers the handling, mixing, and conditioning procedures that are required to ensure that a representative sample of the liquid petroleum or petroleum product is delivered from the primary sample container/receiver into the analytical test apparatus or into intermediate containers.
1.2 Annex A2 covers acceptance test criteria for power mixer and sample container combinations, while Annex A3 and Annex A4 detail acceptance tests for mixing systems. Appendix X1 is a guide for selecting sample containers.
1.3 For sampling procedures, refer to Practices D4057 (API MPMS Chapter 8.1) and D4177 (API MPMS Chapter 8.2). Practice D5842 (API MPMS Chapter 8.4) covers sampling and handling of light fuels for volatility measurement.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SIGNIFICANCE AND USE
The dry vapor pressure equivalent (DVPE) of volatile motor fuels is regulated by federal and state air pollution control agencies. In order to meet the letter of these regulations, it is necessary to sample, handle, and test these products in a very precise manner.
SCOPE
1.1 This practice covers procedures and equipment for obtaining, mixing, and handling representative samples of volatile fuels for the purpose of testing for compliance with the standards set forth for volatility related measurements applicable to light fuels. The applicable dry vapor pressure equivalent range of this practice is 13 to 105 kPa (2 to 16 psia).
1.2 This practice is applicable to the sampling, mixing, and handling of reformulated fuels including those containing oxygenates.
1.3 The values stated in SI units are to be regarded as the standard except in some cases where drawings may show inch-pound measurements which are customary for that equipment.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SIGNIFICANCE AND USE
Representative samples of petroleum and petroleum products are required for the determination of chemical and physical properties used to establish standard volumes, prices, and compliance with commercial and regulatory specifications. The treatment of samples from the time of collection until they are analyzed requires care and effort to maintain their compositional integrity.
SCOPE
1.1 This practice covers the handling, mixing, and conditioning procedures that are required to ensure that a representative sample of the liquid petroleum or petroleum product is delivered from the primary sample container/receiver into the analytical test apparatus or into intermediate containers.
1.2 covers acceptance test criteria for power mixer and sample container combinations, while and detail acceptance tests for mixing systems. is a guide for selecting sample containers.
1.3 For sampling procedures, refer to Practices D 4057 (API MPMS Chapter 8.1) and D 4177 (API MPMS Chapter 8.2). Practice D 5842 (API MPMS Chapter 8.4) covers sampling and handling of light fuels for volatility measurement.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SIGNIFICANCE AND USE
The dry vapor pressure equivalent (DVPE) of volatile motor fuels is regulated by federal and state air pollution control agencies. In order to meet the letter of these regulations, it is necessary to sample, handle, and test these products in a very precise manner.
SCOPE
1.1 This practice covers procedures and equipment for obtaining, mixing, and handling representative samples of volatile fuels for the purpose of testing for compliance with the standards set forth for volatility related measurements applicable to light fuels. The applicable dry vapor pressure equivalent range of this practice is 13 to 105 kPa (2 to 16 psia).  
1.2 This practice is applicable to the sampling, mixing, and handling of reformulated fuels including those containing oxygenates.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.  
1.4 The values stated in acceptable metric units are to be regarded as the standard except in some cases where drawings may show English measurements which are customary for that equipment.

SCOPE
1.1 This test method covers the direct determination of water in the range of 10 to 25 000 mg/kg entrained water in petroleum products and hydrocarbons using automated instrumentation. This test method also covers the indirect analysis of water thermally removed from samples and swept with dry inert gas into the Karl Fischer titration cell. Mercaptan, sulfide (S- or H2S), sulfur, and other compounds are known to interfere with this test method (see Section 5).
1.2 This test method is intended for use with commercially available coulometric Karl Fischer reagents and for the determination of water in additives, lube oils, base oils, automatic transmission fluids, hydrocarbon solvents, and other petroleum products. By proper choice of the sample size, this test method may be used for the determination of water from mg/kg to percent level concentrations.
1.3 Values stated in SI units are to be regarded as the standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SCOPE
1.1 This test method covers the direct determination of water in the range of 10 to 25 000 mg/kg entrained water in petroleum products and hydrocarbons using automated instrumentation. This test method also covers the indirect analysis of water thermally removed from samples and swept with dry inert gas into the Karl Fischer titration cell. Mercaptan, sulfide (S- or H2S), sulfur, and other compounds are known to interfere with this test method (see Section 5).
1.2 This test method is intended for use with commercially available coulometric Karl Fischer reagents and for the determination of water in additives, lube oils, base oils, automatic transmission fluids, hydrocarbon solvents, and other petroleum products. By proper choice of the sample size, this test method may be used for the determination of water from mg/kg to percent level concentrations.
1.3 Values stated in SI units are to be regarded as the standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SCOPE
1.1 This test method covers the direct determination of water in the range of 10 to 25 000 mg/kg entrained water in petroleum products and hydrocarbons using automated instrumentation. This test method also covers the indirect analysis of water thermally removed from samples and swept with dry inert gas into the Karl Fischer titration cell. Mercaptan, sulfide (S  or H2S), sulfur, and other compounds are known to interfere with this test method (see Section ).
1.2 This test method is intended for use with commercially available coulometric Karl Fischer reagents and for the determination of water in additives, lube oils, base oils, automatic transmission fluids, hydrocarbon solvents, and other petroleum products. By proper choice of the sample size, this test method may be used for the determination of water from mg/kg to percent level concentrations.
1.3 Values stated in SI units are to be regarded as the standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SCOPE
1.1 This test method covers the direct determination of water in the range of 10 to 25 000 mg/kg entrained water in petroleum products and hydrocarbons using automated instrumentation. This test method also covers the indirect analysis of water thermally removed from samples and swept with dry inert gas into the Karl Fischer titration cell. Mercaptan, sulfide (S- or H2S), sulfur, and other compounds are known to interfere with this test method (see Section 5).
1.2 This test method is intended for use with commercially available coulometric Karl Fischer reagents and for the determination of water in additives, lube oils, base oils, automatic transmission fluids, hydrocarbon solvents, and other petroleum products. By proper choice of the sample size, this test method may be used for the determination of water from mg/kg to percent level concentrations.
1.3 Values stated in SI units are to be regarded as the standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SCOPE
1.1 This test method covers the direct determination of water in the range of 10 to 25 000 mg/kg entrained water in petroleum products and hydrocarbons using automated instrumentation. This test method also covers the indirect analysis of water thermally removed from samples and swept with dry inert gas into the Karl Fisher titration cell. Mercaptan, sulfide (S- or H2S), sulfur, and other compounds are known to interfere with this test method (see Section 5).
1.2 This test method is intended for use with commercially available coulometric Karl Fischer reagents and for the determination of water in additives, lube oils, base oils, automatic transmission fluids, hydrocarbon solvents, and other petroleum products. By proper choice of the sample size, this test method may be used for the determination of water from mg/kg to percent level concentrations.
1.3 Values stated in SI units are to be regarded as the standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SCOPE
1.1 This test method covers the direct determination of water in the range of 10 to 25 000 mg/kg entrained water in petroleum products and hydrocarbons using automated instrumentation. This test method also covers the indirect analysis of water thermally removed from samples and swept with dry inert gas into the Karl Fisher titration cell. Mercaptan, sulfide (S- or H2S), sulfur, and other compounds are known to interfere with this test method (see Section 5).
1.2 This test method is intended for use with commercially available coulometric Karl Fischer reagents and for the determination of water in additives, lube oils, base oils, automatic transmission fluids, hydrocarbon solvents, and other petroleum products. By proper choice of the sample size, this test method may be used for the determination of water from mg/kg to percent level concentrations.
1.3 Values stated in SI units are to be regarded as the standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SCOPE
1.1 This practice covers the handling, mixing, and conditioning procedures that are required to ensure that a representative sample of the liquid petroleum or petroleum product is delivered from the primary sample container/ receiver into the analytical test apparatus or into intermediate containers.  
1.2 Annex A2 covers acceptance test criteria for power mixer and sample container combinations, while Annexes A3 and A4 detail acceptance tests for mixing systems. Appendix X1 is a guide for selecting sample containers.  
1.3 For sampling procedures, refer to Practices D4057 and D4177. Practice D5842 covers sampling and handling of light fuels for volatility measurement.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SCOPE
1.1 This practice covers procedures and equipment for obtaining, mixing, and handling representative samples of volatile fuels for the purpose of testing for compliance with the standards set forth for volatility related measurements applicable to light fuels. The applicable dry vapor pressure equivalent range of this practice is 13 to 105 kPa (2 to 16 psia).  
1.2 This practice is applicable to the sampling, mixing, and handling of reformulated fuels including those containing oxygenates.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.  
1.4 The values stated in acceptable metric units are to be regarded as the standard except in some cases where drawings may show English measurements which are customary for that equipment.