ASTM D6378-08
(Test Method)Standard Test Method for Determination of Vapor Pressure (VPX) of Petroleum Products, Hydrocarbons, and Hydrocarbon-Oxygenate Mixtures (Triple Expansion Method)
Standard Test Method for Determination of Vapor Pressure (VP<inf>X</inf>) of Petroleum Products, Hydrocarbons, and Hydrocarbon-Oxygenate Mixtures (Triple Expansion Method)
SIGNIFICANCE AND USE
Vapor pressure is a very important physical property of volatile liquids for shipping and storage.
The vapor pressure of gasoline and gasoline-oxygenate blends is regulated by various government agencies.
Specifications for volatile petroleum products generally include vapor pressure limits to ensure products of suitable volatility performance.
In this test method, an air saturation procedure prior to the measurement is not required, thus eliminating losses of high volatile compounds during this step. This test method is faster and minimizes potential errors from improper air saturation. This test method permits VPX determinations in the field.
This test method can be applied in online applications in which an air saturation procedure prior to the measurement cannot be performed.
SCOPE
1.1 This test method covers the use of automated vapor pressure instruments to determine the vapor pressure exerted in vacuum by volatile, liquid petroleum products, hydrocarbons, and hydrocarbon-oxygenate mixtures. This test method is suitable for testing samples with boiling points above 0°C (32°F) that exert a vapor pressure between 7 and 150 kPa (1.0 and 21 psi) at 37.8°C (100°F) at a vapor-to-liquid ratio of 4:1. The liquid sample volume size required for analysis is dependent upon the vapor-to-liquid ratio chosen (see Note 1) and the measuring chamber volume capacity of the instrument (see 6.1.1 and Note 3).
Note 1—The test method is suitable for the determination of the vapor pressure of volatile, liquid petroleum products at temperatures from 0 to 100°C at vapor to liquid ratios of 4:1 to 1:1 (X = 4 to 1) and pressures up to 500 kPa (70 psi), but the precision statement (see Section 16) may not be applicable.
1.2 This test method also covers the use of automated vapor pressure instruments to determine the vapor pressure exerted in vacuum by aviation turbine fuels. This test method is suitable for testing aviation turbine fuel samples with boiling points above 0°C (32°F) that exert a vapor pressure between 0 and 110 kPa (0 and 15.5 psi) at a vapor-to-liquid ratio of 4:1, in the temperature range from 25 to 100°C (77 to 212°F).
1.3 The vapor pressure (VPX) determined by this test method at a vapor-liquid ratio of 4:1 (X = 4) of gasoline and gasoline-oxygenate blends at 37.8°C can be correlated to the dry vapor pressure equivalent (DVPE) value determined by Test Method D 5191 (see 16.3). This condition does not apply when the sample is aviation turbine fuel.
1.4 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific warning statements, see 7.2-7.8.
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Designation:D6378–08
Standard Test Method for
Determination of Vapor Pressure (VP ) of Petroleum
X
Products, Hydrocarbons, and Hydrocarbon-Oxygenate
1
Mixtures (Triple Expansion Method)
This standard is issued under the fixed designation D6378; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope* responsibility of the user of this standard to establish appro-
priate safety and health practices and determine the applica-
1.1 This test method covers the use of automated vapor
bility of regulatory limitations prior to use. For specific
pressureinstrumentstodeterminethevaporpressureexertedin
warning statements, see 7.2-7.8.
vacuum by volatile, liquid petroleum products, hydrocarbons,
and hydrocarbon-oxygenate mixtures. This test method is
2. Referenced Documents
suitable for testing samples with boiling points above 0°C
2
2.1 ASTM Standards:
(32°F) that exert a vapor pressure between 7 and 150 kPa (1.0
D323 Test Method for Vapor Pressure of Petroleum Prod-
and 21 psi) at 37.8°C (100°F) at a vapor-to-liquid ratio of 4:1.
ucts (Reid Method)
The liquid sample volume size required for analysis is depen-
D2892 Test Method for Distillation of Crude Petroleum
dent upon the vapor-to-liquid ratio chosen (see Note 1) and the
(15-Theoretical Plate Column)
measuring chamber volume capacity of the instrument (see
D4057 Practice for Manual Sampling of Petroleum and
6.1.1 and Note 3).
Petroleum Products
NOTE 1—The test method is suitable for the determination of the vapor
D4177 Practice for Automatic Sampling of Petroleum and
pressure of volatile, liquid petroleum products at temperatures from 0 to
Petroleum Products
100°C at vapor to liquid ratios of 4:1 to 1:1 (X = 4 to 1) and pressures up
D4953 Test Method for Vapor Pressure of Gasoline and
to 500 kPa (70 psi), but the precision statement (see Section 16) may not
Gasoline-Oxygenate Blends (Dry Method)
be applicable.
D5191 Test Method for Vapor Pressure of Petroleum Prod-
1.2 This test method also covers the use of automated vapor
ucts (Mini Method)
pressureinstrumentstodeterminethevaporpressureexertedin
D5842 Practice for Sampling and Handling of Fuels for
vacuum by aviation turbine fuels. This test method is suitable
Volatility Measurement
for testing aviation turbine fuel samples with boiling points
D5854 PracticeforMixingandHandlingofLiquidSamples
above 0°C (32°F) that exert a vapor pressure between 0 and
of Petroleum and Petroleum Products
110 kPa (0 and 15.5 psi) at a vapor-to-liquid ratio of 4:1, in the
D6299 Practice for Applying Statistical Quality Assurance
temperature range from 25 to 100°C (77 to 212°F).
and Control Charting Techniques to Evaluate Analytical
1.3 The vapor pressure (VP ) determined by this test
X
Measurement System Performance
method at a vapor-liquid ratio of 4:1 (X = 4) of gasoline and
D6300 Practice for Determination of Precision and Bias
gasoline-oxygenate blends at 37.8°C can be correlated to the
Data for Use in Test Methods for Petroleum Products and
dry vapor pressure equivalent (DVPE) value determined by
Lubricants
Test Method D5191 (see 16.3). This condition does not apply
D6708 PracticeforStatisticalAssessmentandImprovement
when the sample is aviation turbine fuel.
of Expected Agreement Between Two Test Methods that
1.4 The values stated in SI units are to be regarded as the
Purport to Measure the Same Property of a Material
standard. The values given in parentheses are for information
only.
3. Terminology
1.5 This standard does not purport to address all of the
3.1 Definitions of Terms Specific to This Standard:
safety concerns, if any, associated with its use. It is the
3.1.1 dry vapor pressure equivalent (DVPE)—a value cal-
culated by a correlation equation from the total pressure (Test
1
This test method is under the jurisdiction of ASTM Committee D02 on
Petroleum Products and Lubricants and is the direct responsibility of Subcommittee
2
D02.08 on Volatility. For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Current edition approved Oct. 15, 2008. Published November 2008. Originally contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
´1
approved in 1999. Last previous edition approved in 2007 as D6378–07 . DOI: Standards volume information, refer to the standard’s Document Summary page on
10.1520/D6378-08. the ASTM website.
*A Summary of Changes section appears at the end of this standard.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1
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D6378–08
Metho
...
This document is not anASTM standard and is intended only to provide the user of anASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
An American National Standard
´1
Designation:D6378–07 Designation:D6378–08
Standard Test Method for
Determination of Vapor Pressure (VP ) of Petroleum
X
Products, Hydrocarbons, and Hydrocarbon-Oxygenate
1
Mixtures (Triple Expansion Method)
This standard is issued under the fixed designation D 6378; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1
´ NOTE—Removed apparatus sole source of supply footnote editorially in September 2007.
1. Scope*
1.1 This test method covers the use of automated vapor pressure instruments to determine the vapor pressure exerted in vacuum
by volatile, liquid petroleum products, hydrocarbons, and hydrocarbon-oxygenate mixtures.This test method is suitable for testing
sampleswithboilingpointsabove0°C(32°F)thatexertavaporpressurebetween7and150kPa(1.0and21psi)at37.8°C(100°F)
at a vapor-to-liquid ratio of 4:1. The liquid sample volume size required for analysis is dependent upon the vapor-to-liquid ratio
chosen (see Note 1) and the measuring chamber volume capacity of the instrument (see 6.1.1 and Note 3).
NOTE 1—The test method is suitable for the determination of the vapor pressure of volatile, liquid petroleum products at temperatures from 0 to 100°C
at vapor to liquid ratios of 4:1 to 1:1 (X=4to1)and pressures up to 500 kPa (70 psi), but the precision statement (see Section 16) may not be applicable.
1.2The vapor pressure (VP
1.2 This test method also covers the use of automated vapor pressure instruments to determine the vapor pressure exerted in
vacuum by aviation turbine fuels. This test method is suitable for testing aviation turbine fuel samples with boiling points above
0°C (32°F) that exert a vapor pressure between 0 and 110 kPa (0 and 15.5 psi) at a vapor-to-liquid ratio of 4:1, in the temperature
range from 25 to 100°C (77 to 212°F).
1.3 The vapor pressure (VP ) determined by this test method at a vapor-liquid ratio of 4:1 (X = 4) of gasoline and
X
gasoline–oxygenate blends at 37.8°C can be correlated to the dry vapor pressure equivalent (DVPE) value determined by Test
Method D5191 (see 16.2).
1.3
1.4) determined by this test method at a vapor-liquid ratio of 4:1 (X = 4) of gasoline and gasoline-oxygenate blends at 37.8°C
can be correlated to the dry vapor pressure equivalent (DVPE) value determined by Test Method D 5191 (see 16.3). This condition
does not apply when the sample is aviation turbine fuel.
1.4 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use. For specific warning statements, see 7.2-7.8.
2. Referenced Documents
2
2.1 ASTM Standards:
D 323 Test Method for Vapor Pressure of Petroleum Products (Reid Method)
D 2892 Test Method for Distillation of Crude Petroleum (15-Theoretical Plate Column)
D 4057 Practice for Manual Sampling of Petroleum and Petroleum Products
D 4177 Practice for Automatic Sampling of Petroleum and Petroleum Products
D 4953 Test Method for Vapor Pressure of Gasoline and Gasoline-Oxygenate Blends (Dry Method)
D 5191 Test Method for Vapor Pressure of Petroleum Products (Mini Method)
D 5842 Practice for Sampling and Handling of Fuels for Volatility Measurement
D 5854 Practice for Mixing and Handling of Liquid Samples of Petroleum and Petroleum Products
1
This test method is under the jurisdiction ofASTM Committee D02 on Petroleum Products and Lubricants and is the direct responsibility of Subcommittee D02.08 on
Volatility.
Current edition approved May 1, 2007. Published July 2007. Originally approved in 1999. Last previous edition approved in 2006 as D6378–06.
´1
Current edition approved Oct. 15, 2008. Published November 2008. Originally approved in 1999. Last previous edition approved in 2007 as D 6378–07 .
2
For referencedASTM standards, visit theASTM website, www.astm.org, or contactASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
*A Summary of Changes section appears at the end of this standard.
C
...
This document is not anASTM standard and is intended only to provide the user of anASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
An American National Standard
´1
Designation:D6378–07 Designation:D6378–08
Standard Test Method for
Determination of Vapor Pressure (VP ) of Petroleum
X
Products, Hydrocarbons, and Hydrocarbon-Oxygenate
1
Mixtures (Triple Expansion Method)
This standard is issued under the fixed designation D 6378; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1
´ NOTE—Removed apparatus sole source of supply footnote editorially in September 2007.
1. Scope*
1.1 This test method covers the use of automated vapor pressure instruments to determine the vapor pressure exerted in vacuum
by volatile, liquid petroleum products, hydrocarbons, and hydrocarbon-oxygenate mixtures.This test method is suitable for testing
sampleswithboilingpointsabove0°C(32°F)thatexertavaporpressurebetween7and150kPa(1.0and21psi)at37.8°C(100°F)
at a vapor-to-liquid ratio of 4:1. The liquid sample volume size required for analysis is dependent upon the vapor-to-liquid ratio
chosen (see Note 1) and the measuring chamber volume capacity of the instrument (see 6.1.1 and Note 3).
NOTE 1—The test method is suitable for the determination of the vapor pressure of volatile, liquid petroleum products at temperatures from 0 to 100°C
at vapor to liquid ratios of 4:1 to 1:1 (X=4to1)and pressures up to 500 kPa (70 psi), but the precision statement (see Section 16) may not be applicable.
1.2The vapor pressure (VP
1.2 This test method also covers the use of automated vapor pressure instruments to determine the vapor pressure exerted in
vacuum by aviation turbine fuels. This test method is suitable for testing aviation turbine fuel samples with boiling points above
0°C (32°F) that exert a vapor pressure between 0 and 110 kPa (0 and 15.5 psi) at a vapor-to-liquid ratio of 4:1, in the temperature
range from 25 to 100°C (77 to 212°F).
1.3 The vapor pressure (VP ) determined by this test method at a vapor-liquid ratio of 4:1 (X = 4) of gasoline and
X
gasoline–oxygenate blends at 37.8°C can be correlated to the dry vapor pressure equivalent (DVPE) value determined by Test
Method D5191 (see 16.2).
1.3
1.4) determined by this test method at a vapor-liquid ratio of 4:1 (X = 4) of gasoline and gasoline-oxygenate blends at 37.8°C
can be correlated to the dry vapor pressure equivalent (DVPE) value determined by Test Method D 5191 (see 16.3). This condition
does not apply when the sample is aviation turbine fuel.
1.4 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use. For specific warning statements, see 7.2-7.8.
2. Referenced Documents
2
2.1 ASTM Standards:
D 323 Test Method for Vapor Pressure of Petroleum Products (Reid Method)
D 2892 Test Method for Distillation of Crude Petroleum (15-Theoretical Plate Column)
D 4057 Practice for Manual Sampling of Petroleum and Petroleum Products
D 4177 Practice for Automatic Sampling of Petroleum and Petroleum Products
D 4953 Test Method for Vapor Pressure of Gasoline and Gasoline-Oxygenate Blends (Dry Method)
D 5191 Test Method for Vapor Pressure of Petroleum Products (Mini Method)
D 5842 Practice for Sampling and Handling of Fuels for Volatility Measurement
D 5854 Practice for Mixing and Handling of Liquid Samples of Petroleum and Petroleum Products
1
This test method is under the jurisdiction ofASTM Committee D02 on Petroleum Products and Lubricants and is the direct responsibility of Subcommittee D02.08 on
Volatility.
Current edition approved May 1, 2007. Published July 2007. Originally approved in 1999. Last previous edition approved in 2006 as D6378–06.
´1
Current edition approved Oct. 15, 2008. Published November 2008. Originally approved in 1999. Last previous edition approved in 2007 as D 6378–07 .
2
For referencedASTM standards, visit theASTM website, www.astm.org, or contactASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
*A Summary of Changes section appears at the end of this standard.
C
...












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