Standard Specification for Copper and Copper-Alloy Seamless Condenser Tubes and Ferrule Stock

ABSTRACT
This specification establishes the requirements for seamless tube and ferrule stock of copper and various copper alloys of a specified range of diameters, for use in surface condensers, evaporators, and heat exchangers. The specified coppers and copper alloys are UNS No. C10100, C10200, C10300, C10800, C12000, C12200, C14200, C19200, C23000, C28000, C44300, C44400, C44500, C60800, C61300, C61400, C68700, C70400, C70600, C70620, C71000, C71500, C71520, C71640, and C72200. The product shall be produced by processes such as casting, extrusion, drawing, annealing, straightening, trimming, and other processes which may produce a seamless tube in the specified condition. The coppers and copper alloys shall be specifically furnished in any one of the following tempers: annealed, light-drawn, hard-drawn, or hard drawn and end annealed. Tubes for ferrule stock shall be annealed sufficiently to be fully crystallized. Some tubes are suggested to be subjected to a stress-relieving thermal treatment subsequent to straightening. The products shall be subjected to expansion, flattening, and residual stress tests. The tensile and expansion requirements for the products are specified in accordance with the temper designation. The products shall also be subjected to mercurous nitrate, ammonia vapor, Eddy-current, hydrostatic, and pneumatic tests.
SCOPE
1.1 This specification2 establishes the requirements for seamless tube and ferrule stock of copper and various copper alloys up to 31/8 in. [80 mm] inclusive, in diameter, for use in surface condensers, evaporators, and heat exchangers. The following coppers and copper alloys are specified:3    
Copper or Copper
Alloy UNS No.  
Previously Used
Designation  
Description  
C10100  
OFE  
Oxygen-free electronic  
C10200  
OFA  
Oxygen-free without residual deoxidants  
C10300  
. . .  
Oxygen-free, extra low phosphorus  
C10800  
. . .  
Oxygen-free, low phosphorus  
C12000  
DLPA  
Phosphorized, low residual phosphorus  
C12200  
DHPA  
Phosphorized, high residual phosphorus  
C14200  
DPAA  
Phosphorized, arsenical  
C15630  
. . .  
Nickel Phosphorus  
C19200  
. . .  
Phosphorized, 1 % iron  
C23000  
. . .  
Red Brass  
C28000  
. . .  
Muntz Metal  
C44300  
. . .  
Admiralty Metals, B, C, and D  
C44400  
. . .  
. . .  
C44500  
. . .  
. . .  
C60800  
. . .  
Aluminum Bronze  
C61300  
. . .  
. . .    
C61400  
. . .  
Aluminum Bronze, D  
C68700  
. . .  
Aluminum Brass, B  
C70400  
. . .  
95-5 Copper-Nickel  
C70600  
. . .  
90-10 Copper-Nickel  
C70620  
. . .  
90-10 Copper-Nickel—Welding Grade  
C71000  
. . .  
80-20 Copper-Nickel  
C71500  
. . .  
70-30 Copper-Nickel  
C71520  
. . .  
70-30 Copper-Nickel—Welding Grade  
Copper or Copper
Alloy UNS No.  
Previously Used
Designation  
Description  
C71640  
. . .  
Copper-nickel-iron-manganese  
C72200  
. . .  
. . .    
1.2 Units—The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in non-conformance with the standard.  
1.3 The following safety hazards caveat pertains only to the test methods portion, Section 19, of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. (Warning—Mercury has been designated by many regulatory agencies as a hazardous substance that can cause serious medical issues. Mercury, or its vapor, has be...

General Information

Status
Published
Publication Date
30-Sep-2018
Technical Committee
B05 - Copper and Copper Alloys
Drafting Committee
B05.04 - Pipe and Tube

Relations

Effective Date
01-Jan-2024
Effective Date
01-Aug-2019
Effective Date
15-Jun-2019
Effective Date
01-Jan-2019
Effective Date
01-Jun-2018
Effective Date
01-Mar-2018
Effective Date
15-Jul-2016
Effective Date
15-Oct-2015
Effective Date
01-May-2015
Effective Date
01-Feb-2015
Effective Date
01-Jul-2014
Effective Date
01-Dec-2013
Effective Date
01-Jun-2013
Effective Date
15-Nov-2012
Effective Date
01-Oct-2012

Overview

ASTM B111/B111M-18a, titled "Standard Specification for Copper and Copper-Alloy Seamless Condenser Tubes and Ferrule Stock," is an internationally recognized standard developed by ASTM International. This specification details the requirements for seamless tubes and ferrule stock made from copper and a broad range of copper alloys, for use in heat transfer applications such as surface condensers, evaporators, and heat exchangers. The standard covers tubes up to 80 mm (3 1/8 in) in diameter and includes specific requirements related to manufacturing methods, chemical composition, mechanical properties, temper, dimensions, and testing methods.

This standard is essential in ensuring the quality, durability, and performance of copper and copper-alloy tubes in demanding thermal and industrial environments.

Key Topics

  • Materials Covered: The standard includes a variety of copper and copper-alloy grades identified by Unified Numbering System (UNS) numbers such as C10100 (oxygen-free electronic copper), C12200 (high residual phosphorus copper), C23000 (red brass), C70600 (90-10 copper-nickel), C71500 (70-30 copper-nickel), among others.
  • Manufacturing Processes: Tubes must be produced by processes like casting, extrusion, drawing, annealing, straightening, and trimming to ensure a seamless structure.
  • Temper Designations: Products can be supplied in annealed, light-drawn, hard-drawn, or hard drawn and end-annealed tempers, depending on service requirements.
  • Testing Requirements: Tubes are subjected to rigorous expansion, flattening, tensile, and residual stress tests. Additional non-destructive testing methods include eddy-current, hydrostatic, and pneumatic tests.
  • Dimensional Tolerances: Strict tolerances are established for diameter, wall thickness, length, and cut squareness to ensure product uniformity and fit for purpose.
  • Safety Considerations: Sections on testing methods caution the user about the safe handling of hazardous substances (e.g., mercury in the mercurous nitrate test).

Applications

The ASTM B111/B111M-18a specification is widely used in industries where efficient heat transfer is critical:

  • Power Generation: Seamless copper and copper-alloy tubes are essential in power plant condensers and heat exchangers, ensuring efficient cooling and condenser performance.
  • HVAC and Refrigeration: Used in evaporators, chillers, and air conditioning systems where corrosion resistance and thermal conductivity are vital.
  • Desalination: Suitable for heat exchangers and multi-effect evaporators in desalination plants, especially where seawater exposure requires alloys with enhanced corrosion resistance (e.g., copper-nickel alloys).
  • Marine Applications: Tubes and ferrule stock produced to this standard are often used in shipboard heat exchangers and condensers due to their resistance to seawater-induced corrosion.
  • Industrial Processing: Used in chemical and petrochemical plants where reliable and durable tubular materials are required for heat transfer processes.

Related Standards

Several standards complement or are referenced by ASTM B111/B111M-18a, ensuring consistency and reliability across industries:

  • ASME SB-111: The ASME Boiler and Pressure Vessel Code adopts this specification for pressure-boundary applications.
  • ASTM B153: Test Method for Expansion (Pin Test) of Copper and Copper-Alloy Pipe and Tubing.
  • ASTM B154: Mercurous Nitrate Test for detecting susceptible stress corrosion in copper alloys.
  • ASTM B858: Ammonia Vapor Test for stress-corrosion cracking susceptibility.
  • ASTM E243: Electromagnetic (Eddy Current) Examination of Copper and Copper-Alloy Tubes.
  • ASTM E8/E8M: Test Methods for Tension Testing of Metallic Materials.
  • ASTM B846: Terminology for Copper and Copper Alloys.

Other linked references include international regulations for safety and environmental responsibility during testing and application, especially regarding hazardous substances.


By adhering to ASTM B111/B111M-18a, manufacturers and end users ensure the delivery of robust and reliable copper and copper-alloy condenser tubes and ferrule stock, suitable for diverse, high-performance heat transfer applications. This specification supports consistency, safety, and efficiency within critical industries worldwide.

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Frequently Asked Questions

ASTM B111/B111M-18a is a technical specification published by ASTM International. Its full title is "Standard Specification for Copper and Copper-Alloy Seamless Condenser Tubes and Ferrule Stock". This standard covers: ABSTRACT This specification establishes the requirements for seamless tube and ferrule stock of copper and various copper alloys of a specified range of diameters, for use in surface condensers, evaporators, and heat exchangers. The specified coppers and copper alloys are UNS No. C10100, C10200, C10300, C10800, C12000, C12200, C14200, C19200, C23000, C28000, C44300, C44400, C44500, C60800, C61300, C61400, C68700, C70400, C70600, C70620, C71000, C71500, C71520, C71640, and C72200. The product shall be produced by processes such as casting, extrusion, drawing, annealing, straightening, trimming, and other processes which may produce a seamless tube in the specified condition. The coppers and copper alloys shall be specifically furnished in any one of the following tempers: annealed, light-drawn, hard-drawn, or hard drawn and end annealed. Tubes for ferrule stock shall be annealed sufficiently to be fully crystallized. Some tubes are suggested to be subjected to a stress-relieving thermal treatment subsequent to straightening. The products shall be subjected to expansion, flattening, and residual stress tests. The tensile and expansion requirements for the products are specified in accordance with the temper designation. The products shall also be subjected to mercurous nitrate, ammonia vapor, Eddy-current, hydrostatic, and pneumatic tests. SCOPE 1.1 This specification2 establishes the requirements for seamless tube and ferrule stock of copper and various copper alloys up to 31/8 in. [80 mm] inclusive, in diameter, for use in surface condensers, evaporators, and heat exchangers. The following coppers and copper alloys are specified:3 Copper or Copper Alloy UNS No. Previously Used Designation Description C10100 OFE Oxygen-free electronic C10200 OFA Oxygen-free without residual deoxidants C10300 . . . Oxygen-free, extra low phosphorus C10800 . . . Oxygen-free, low phosphorus C12000 DLPA Phosphorized, low residual phosphorus C12200 DHPA Phosphorized, high residual phosphorus C14200 DPAA Phosphorized, arsenical C15630 . . . Nickel Phosphorus C19200 . . . Phosphorized, 1 % iron C23000 . . . Red Brass C28000 . . . Muntz Metal C44300 . . . Admiralty Metals, B, C, and D C44400 . . . . . . C44500 . . . . . . C60800 . . . Aluminum Bronze C61300 . . . . . . C61400 . . . Aluminum Bronze, D C68700 . . . Aluminum Brass, B C70400 . . . 95-5 Copper-Nickel C70600 . . . 90-10 Copper-Nickel C70620 . . . 90-10 Copper-Nickel—Welding Grade C71000 . . . 80-20 Copper-Nickel C71500 . . . 70-30 Copper-Nickel C71520 . . . 70-30 Copper-Nickel—Welding Grade Copper or Copper Alloy UNS No. Previously Used Designation Description C71640 . . . Copper-nickel-iron-manganese C72200 . . . . . . 1.2 Units—The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in non-conformance with the standard. 1.3 The following safety hazards caveat pertains only to the test methods portion, Section 19, of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. (Warning—Mercury has been designated by many regulatory agencies as a hazardous substance that can cause serious medical issues. Mercury, or its vapor, has be...

ABSTRACT This specification establishes the requirements for seamless tube and ferrule stock of copper and various copper alloys of a specified range of diameters, for use in surface condensers, evaporators, and heat exchangers. The specified coppers and copper alloys are UNS No. C10100, C10200, C10300, C10800, C12000, C12200, C14200, C19200, C23000, C28000, C44300, C44400, C44500, C60800, C61300, C61400, C68700, C70400, C70600, C70620, C71000, C71500, C71520, C71640, and C72200. The product shall be produced by processes such as casting, extrusion, drawing, annealing, straightening, trimming, and other processes which may produce a seamless tube in the specified condition. The coppers and copper alloys shall be specifically furnished in any one of the following tempers: annealed, light-drawn, hard-drawn, or hard drawn and end annealed. Tubes for ferrule stock shall be annealed sufficiently to be fully crystallized. Some tubes are suggested to be subjected to a stress-relieving thermal treatment subsequent to straightening. The products shall be subjected to expansion, flattening, and residual stress tests. The tensile and expansion requirements for the products are specified in accordance with the temper designation. The products shall also be subjected to mercurous nitrate, ammonia vapor, Eddy-current, hydrostatic, and pneumatic tests. SCOPE 1.1 This specification2 establishes the requirements for seamless tube and ferrule stock of copper and various copper alloys up to 31/8 in. [80 mm] inclusive, in diameter, for use in surface condensers, evaporators, and heat exchangers. The following coppers and copper alloys are specified:3 Copper or Copper Alloy UNS No. Previously Used Designation Description C10100 OFE Oxygen-free electronic C10200 OFA Oxygen-free without residual deoxidants C10300 . . . Oxygen-free, extra low phosphorus C10800 . . . Oxygen-free, low phosphorus C12000 DLPA Phosphorized, low residual phosphorus C12200 DHPA Phosphorized, high residual phosphorus C14200 DPAA Phosphorized, arsenical C15630 . . . Nickel Phosphorus C19200 . . . Phosphorized, 1 % iron C23000 . . . Red Brass C28000 . . . Muntz Metal C44300 . . . Admiralty Metals, B, C, and D C44400 . . . . . . C44500 . . . . . . C60800 . . . Aluminum Bronze C61300 . . . . . . C61400 . . . Aluminum Bronze, D C68700 . . . Aluminum Brass, B C70400 . . . 95-5 Copper-Nickel C70600 . . . 90-10 Copper-Nickel C70620 . . . 90-10 Copper-Nickel—Welding Grade C71000 . . . 80-20 Copper-Nickel C71500 . . . 70-30 Copper-Nickel C71520 . . . 70-30 Copper-Nickel—Welding Grade Copper or Copper Alloy UNS No. Previously Used Designation Description C71640 . . . Copper-nickel-iron-manganese C72200 . . . . . . 1.2 Units—The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in non-conformance with the standard. 1.3 The following safety hazards caveat pertains only to the test methods portion, Section 19, of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. (Warning—Mercury has been designated by many regulatory agencies as a hazardous substance that can cause serious medical issues. Mercury, or its vapor, has be...

ASTM B111/B111M-18a is classified under the following ICS (International Classification for Standards) categories: 23.040.15 - Non-ferrous metal pipes. The ICS classification helps identify the subject area and facilitates finding related standards.

ASTM B111/B111M-18a has the following relationships with other standards: It is inter standard links to ASTM E8/E8M-24, ASTM B846-19a, ASTM E2575-19, ASTM B846-19, ASTM E243-18, ASTM B858-06(2018), ASTM E8/E8M-16, ASTM B170-99(2015), ASTM B224-15, ASTM E8/E8M-15, ASTM B224-14, ASTM E243-13, ASTM E8/E8M-13, ASTM E112-12, ASTM B154-12e1. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.

ASTM B111/B111M-18a is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.

Standards Content (Sample)


This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: B111/B111M − 18a
Standard Specification for
Copper and Copper-Alloy Seamless Condenser Tubes and
Ferrule Stock
This standard is issued under the fixed designation B111/B111M; the number immediately following the designation indicates the year
of original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval.
A superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope*
Copper or Copper Previously Used
Description
Alloy UNS No. Designation
1.1 This specification establishes the requirements for
seamless tube and ferrule stock of copper and various copper C71640 . . . Copper-nickel-iron-manganese
C72200 . . . . . .
alloys up to 3 ⁄8 in. [80 mm] inclusive, in diameter, for use in
surface condensers, evaporators, and heat exchangers. The
A
Designations listed in Classification B224.
following coppers and copper alloys are specified:
1.2 Units—The values stated in either SI units or inch-
Copper or Copper Previously Used
Description
pound units are to be regarded separately as standard. The
Alloy UNS No. Designation
values stated in each system may not be exact equivalents;
C10100 OFE Oxygen-free electronic
therefore, each system shall be used independently of the other.
A
C10200 OF Oxygen-free without residual deoxidants
Combining values from the two systems may result in non-
C10300 . . . Oxygen-free, extra low phosphorus
C10800 . . . Oxygen-free, low phosphorus
conformance with the standard.
A
C12000 DLP Phosphorized, low residual phosphorus
A
1.3 The following safety hazards caveat pertains only to the
C12200 DHP Phosphorized, high residual phosphorus
A
C14200 DPA Phosphorized, arsenical
test methods portion, Section 19, of this specification: This
C15630 . . . Nickel Phosphorus
standard does not purport to address all of the safety concerns,
C19200 . . . Phosphorized, 1 % iron
if any, associated with its use. It is the responsibility of the user
C23000 . . . Red Brass
C28000 . . . Muntz Metal
of this standard to establish appropriate safety, health, and
C44300 . . . Admiralty Metals, B, C, and D
environmental practices and determine the applicability of
C44400 . . . . . .
regulatory limitations prior to use. (Warning—Mercury has
C44500 . . . . . .
C60800 . . . Aluminum Bronze
been designated by many regulatory agencies as a hazardous
C61300 . . . . . .
substance that can cause serious medical issues. Mercury, or its
C61400 . . . Aluminum Bronze, D
vapor, has been demonstrated to be hazardous to health and
C68700 . . . Aluminum Brass, B
C70400 . . . 95-5 Copper-Nickel
corrosive to materials. Use caution when handling mercury and
C70600 . . . 90-10 Copper-Nickel
mercury-containing products. See the applicable product
C70620 . . . 90-10 Copper-Nickel—Welding Grade
Safety Data Sheet (SDS) for additional information. The
C71000 . . . 80-20 Copper-Nickel
C71500 . . . 70-30 Copper-Nickel
potential exists that selling mercury or mercury-containing
C71520 . . . 70-30 Copper-Nickel—Welding Grade
products, or both, is prohibited by local or national law. Users
must determine legality of sales in their location.
1.4 This international standard was developed in accor-
1 dance with internationally recognized principles on standard-
This specification is under the jurisdiction of ASTM Committee B05 on Copper
and Copper Alloys and is the direct responsibility of Subcommittee B05.04 on Pipe ization established in the Decision on Principles for the
and Tube.
Development of International Standards, Guides and Recom-
Current edition approved Oct. 1, 2018. Published October 2018. Originally
mendations issued by the World Trade Organization Technical
approved in 1937. Last previous edition approved in 2018 as B111/B111M–18. DOI:
Barriers to Trade (TBT) Committee.
10.1520/B0111_B0111M–18A.
For ASME Boiler and Pressure Vessel Code applications, see related Specifi-
2. Referenced Documents
cation SB-111 in Section II of the Code.
The UNS system for copper and copper alloys (see Practice E527) is a simple
2.1 The following documents in the current issue of the
expansion of the former standard designation system accomplished by the addition
Annual Book of ASTM Standards form a part of this specifica-
of a prefix “C” and a suffix “00.” The suffix can be used to accommodate
composition variations of the base alloy.
tion to the extent referenced herein:
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
B111/B111M − 18a
2.2 ASTM Standards: 4.1.3 Temper (Section 7);
B153 Test Method for Expansion (Pin Test) of Copper and
4.1.4 Dimensions, outside diameter, and wall thickness,
Copper-Alloy Pipe and Tubing
whether minimum or nominal (Section 14);
B154 Test Method for Mercurous Nitrate Test for Copper
4.1.5 How furnished (tube or ferrule stock);
Alloys
4.1.6 Quantity—total weight or total length or number of
B170 Specification for Oxygen-Free Electrolytic Copper—
pieces of each size; and
Refinery Shapes
4.1.7 Intended application.
B224 Classification of Coppers
4.2 The following options are available but may not be
B846 Terminology for Copper and Copper Alloys
included unless specified at the time of placing of the order
B858 Test Method for Ammonia Vapor Test for Determining
when required:
Susceptibility to Stress Corrosion Cracking in Copper
4.2.1 Tension Test per ASME Boiler and Pressure Vessel
Alloys
Code (see Section 8).
B968/B968M Test Method for Flattening of Copper and
4.2.2 Hydrostatic or pneumatic test as an alternative to eddy
Copper-Alloy Pipe and Tube
current test (Section 13).
E8/E8M Test Methods for Tension Testing of Metallic Ma-
4.2.3 If the cut ends of the tubes do not need to be deburred
terials
(Section 15).
E29 Practice for Using Significant Digits in Test Data to
4.2.4 If the product is to be subsequently welded (Table 1,
Determine Conformance with Specifications
Footnotes G and H).
E53 Test Method for Determination of Copper in Unalloyed
Copper by Gravimetry (Withdrawn 2022) 4.2.5 Residual Stress Test—Ammonia Vapor Test or Mer-
curous Nitrate Test (Section 12).
E54 Test Methods for Chemical Analysis of Special Brasses
and Bronzes (Withdrawn 2002) 4.2.6 For Ammonia Vapor Test, risk level (pH value) if other
E62 Test Methods for Chemical Analysis of Copper and than 10.
Copper Alloys (Photometric Methods) (Withdrawn 2010)
4.2.7 Heat identification or traceability details.
E75 Test Methods for Chemical Analysis of Copper-Nickel
4.2.8 Certification (Section 23).
and Copper-Nickel-Zinc Alloys (Withdrawn 2010)
4.2.9 Test Report (Section 24).
E76 Test Methods for Chemical Analysis of Nickel-Copper
4.2.10 If a subsequent thermal treatment after straightening
Alloys (Withdrawn 2003)
is required (Section 7).
E112 Test Methods for Determining Average Grain Size
4.2.11 If product is purchased for agencies of the U.S.
E118 Test Methods for Chemical Analysis of Copper-
Government (see Supplementary Requirements section of this
Chromium Alloys (Withdrawn 2010)
specification for additional requirements, if required).
E243 Practice for Electromagnetic (Eddy Current) Examina-
tion of Copper and Copper-Alloy Tubes
5. Materials and Manufacture
E255 Practice for Sampling Copper and Copper Alloys for
5.1 Materials:
the Determination of Chemical Composition
5.1.1 The material of manufacture shall be a form of such
E478 Test Methods for Chemical Analysis of Copper Alloys
purity and soundness as to be suitable for processing into the
E527 Practice for Numbering Metals and Alloys in the
products prescribed herein.
Unified Numbering System (UNS)
5.1.2 When specified in the contract or purchase order that
E2575 Test Method for Determination of Oxygen in Copper
heat identification or traceability is required, the purchaser
and Copper Alloys by Inert Gas Fusion
shall specify the details desired.
3. Terminology
5.2 Manufacture:
3.1 Definitions:
5.2.1 The product shall be manufactured by such hot-
3.1.1 For definitions of terms relating to copper and copper
working, cold-working, annealing, straightening, trimming,
alloys, refer to Terminology B846.
and other processes as to produce a uniform seamless tube in
the finished product.
4. Ordering Information
5.2.2 The product shall be hot- or cold-worked to the
4.1 Include the following specified choices when placing
finished size, and subsequently annealed, when required, to
orders for product under this specification, as applicable:
meet the temper properties specified.
4.1.1 ASTM Designation and year of issue;
4.1.2 Copper or Copper Alloy UNS No. Designation (see
6. Chemical Composition
Table 1);
6.1 The product shall conform to the chemical composition
requirements specified in Table 1.
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Standards volume information, refer to the standard’s Document Summary page on
the ASTM website. Due to the discontinuous nature of the processing of castings into wrought
The last approved version of this historical standard is referenced on products, it is not always practical to identify a specific casting analysis with a
www.astm.org. specific quantity of finished material.
B111/B111M − 18a
TABLE 1 Chemical Requirements
Composition, %
Copper or
Copper
Nickel, Other
Lead,
Alloy UNS
Copper Tin Aluminum incl Iron Zinc Manganese Arsenic Antimony Phosphorus Chromium Named
max
No.
Cobalt Elements
A B C
C10100 99.99 min 0.0002 max . . . 0.0010 max 0.0005 max 0.0010 max 0.0001 0.00005 max 0.0005 0.0004 max 0.0003 max 0.0001 max
max max
C D C
C10200 99.95 min . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
D
C10300 99.95 min . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.001–0.005 . . . . . .
D
C10800 99.95 min . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.005–0.012 . . . . . .
E D
C12000 99.90 min . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.004–0.012 . . . . . .
D
C12200 99.9 min . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.015–0.040 . . . . . .
D
C14200 99.4 min . . . . . . . . . . . . . . . . . . . . . 0.15–0.50 . . . 0.015–0.040 . . . . . .
B
C15630 remainder . . . . . . 0.60–0.90 . . . . . . . . . . . . . . . . . . 0.015–0.040 . . . . . .
C19200 98.5 min . . . . . . . . . . . . 0.8–1.2 0.20 max . . . . . . . . . 0.01–0.04 . . . . . .
C23000 84.0–86.0 . . . . . . . . . 0.05 0.05 max remainder . . . . . . . . . . . . . . . . . .
C28000 59.0–63.0 . . . . . . . . . 0.09 0.07 max remainder . . . . . . . . . . . . . . . . . .
C44300 70.0–73.0 0.9–1.2 . . . . . . 0.07 0.06 max remainder . . . 0.02–0.06 . . . . . . . . . . . .
C44400 70.0–73.0 0.9–1.2 . . . . . . 0.07 0.06 max remainder . . . . . . 0.02–0.10 . . . . . . . . .
C44500 70.0–73.0 0.9–1.2 . . . . . . 0.07 0.06 max remainder . . . . . . . . . 0.02–0.10 . . . . . .
D
C60800 remainder . . . 5.0–6.5 . . . 0.10 0.10 max . . . . . . 0.02–0.35 . . . . . . . . . . . .
D F, G
C61300 remainder 0.20–0.50 6.0–7.5 0.15 max 0.01 2.0–3.0 0.10 max 0.20 max . . . . . . 0.015 max . . .
D
C61400 remainder . . . 6.0–8.0 . . . 0.01 1.5–3.5 0.20 max 1.0 max . . . . . . 0.015 max . . . . . .
D
C68700 76.0–79.0 . . . 1.8–2.5 . . . 0.07 0.06 max remainder . . . 0.02–0.06 . . . . . . . . . . . .
D
C70400 remainder . . . . . . 4.8–6.2 0.05 1.3–1.7 1.0 max 0.30–0.8 . . . . . . . . . . . . . . .
D
C70600 remainder . . . . . . 9.0–11.0 0.05 1.0–1.8 1.0 max 1.0 max . . . . . . . . . . . . . . .
D
C70620 86.5 min . . . . . . 9.0-11.0 0.02 1.0-1.8 0.50 max 1.0 max . . . . . . 0.02 max . . . C.05 max
S.02 max
D H H H H
C71000 remainder . . . . . . 19.0–23.0 0.05 0.50–1.0 1.0 max 1.0 max . . . . . . . . .
D
C71500 remainder . . . . . . 29.0–33.0 0.05 0.40–1.0 1.0 max 1.0 max . . . . . . . . . . . . . . .
D
C71520 65.0 min . . . . . . 29.0-33.0 0.02 0.40-1.0 0.50 max 1.0 max . . . . . . 0.02 max . . . C.05 max
S.02 max
D H H H
C71640 remainder . . . . . . 29.0–32.0 0.05 1.7–2.3 1.0 max 1.5–2.5 . . . . . . . . . C.06 max
S.03
H
max
D H H H
C72200 remainder . . . . . . 15.0–18.0 0.05 0.50–1.0 1.0 max 1.0 max . . . . . . 0.30–0.70 Si.03
max
Ti.03
H
max
A
This value is exclusive of silver and shall be determined by difference of “impurity total” from 100 %. “Impurity total” is defined as the sum of sulfur, silver, lead, tin, bismuth, arsenic, antimony, iron, nickel, mercury, zinc,
phosphorus, selenium, tellurium, manganese, cadmium, and oxygen present in the sample.
B
Not including Cobalt.
C
Additional impurity maximums in percent for alloy C10100 shall be: bismuth 0.0001, cadmium 0.0001, oxygen 0.0005, selenium 0.0003, sulfur 0.0015, tellurium 0.0002, mercury 0.0001. For C10200, oxygen should
be 0.0010 max.
D
Copper (including silver).
E
This includes oxygen-free Cu which contains P in an amount agreed upon.
F
Silicon shall be 0.10 % max.
G
When the product is for subsequent welding applications and is so specified by the purchaser, chromium shall be 0.05 % max, cadmium 0.05 % max, zinc 0.05 % max, and zirconium 0.05 % max.
H
When the product is for subsequent welding applications, and so specified by the purchaser, zinc shall be 0.50 % max, lead 0.02 % max, phosphorus 0.02 % max, sulfur 0.02 % max, and carbon 0.05 % max.

B111/B111M − 18a
6.2 These composition limits do not preclude the presence
Copper Plus Named
Copper Alloy UNS No.
Elements, % min
of other elements. By agreement between the manufacturer and
C23000 99.8
purchaser, limits may be established and analysis required for
C28000 99.7
unnamed elements.
C44300 99.6
C44400 99.6
6.2.1 Copper Alloy UNS No. C19200—Copper is the differ-
C44500 99.6
ence between the sum results of all the elements determined
C68700 99.5
and 100 %. When all the elements in Table 1 are determined,
their sum shall be 99.8 % minimum.
7. Temper
6.2.2 For alloys in which copper is listed as “remainder,”
7.1 Tubes shall be furnished in the temper designations
copper is the difference between the sum results of all the
identified in Tables 2 and 3.
elements determined and 100 %. When all elements in Table 1
7.1.1 Drawn tempers H55 and H80.
are determined, the sum of the results shall be as follows:
Copper Plus Named 7.1.2 Annealed temper O61.
Copper Alloy UNS No.
Elements, % min
7.1.3 Drawn and stress-relieved temper HR50.
C15630 99.5
C60800 99.5
7.2 Tubes for ferrule stock shall be annealed sufficiently to
C61300 99.8
C61400 99.5 be fully recrystallized.
C70400 99.5
C70600 & C70620 99.5 7.3 Optional Post-Straightening Thermal Treatment—Some
C71000 99.5
tubes, when subjected to aggressive environments, may have
C71500 & C71520 99.5
the potential for stress-corrosion cracking failure due to the
C71640 99.5
C72200 99.8
residual stresses induced during straightening processing. For
such applications, it is suggested that tubes of Copper Alloy
6.2.3 For alloys in which zinc is listed as the remainder,
either copper or zinc may be taken as the difference between UNS Nos. C23000, C28000, C44300, C44400, C44500,
C60800, C61300, C61400, and C68700 be subjected to a
the sum of all the elements determined and 100 %. When all
elements in Table 1 are determined, the sum of the results shall stress-relieving thermal treatment subsequent to straightening.
be as follows: If required, this must be specified on the purchase order or
TABLE 2 Tensile Requirements—Inch-Pound Values
NOTE 1—See Table 3 for tensile requirements—SI values.
Elongation
Temper Designation
B
Tensile Strength,
Yield Strength,
Copper or Copper Alloy UNS No. in 2 in.,
A
A
min ksi min ksi
Code Name
min %
C10100, C10200, C10300, C10800, C12000, C12200, H55 light-drawn 36 30 . . .
C14200
C10100, C10200, C10300, C10800, C12000, C12200, H80 hard-drawn 45 40 . . .
C14200
C15630 O61 annealed 30 8 40
C19200 H55 light-drawn 40 35 . . .
C19200 H80 hard-drawn 48 43 . . .
C19200 O61 annealed 38 12 . . .
C23000 O61 annealed 40 12 . . .
C28000 O61 annealed 50 20 . . .
C44300, C44400, C44500 O61 annealed 45 15 . . .
C60800 O61 annealed 50 19 . . .
C61300, C61400 O61 annealed 70 30 . . .
C68700 O61 annealed 50 18 . . .
C70400 O61 annealed 38 12 . . .
C70400 H55 light-drawn 40 30 . . .
C70600, C70620 O61 annealed 40 15 . . .
C70600, C70620 H55 light-drawn 45 35 . . .
C71000 O61 annealed 45 16 . . .
C71500, C71520 O61 annealed 52 18 . . .
C71500, C71520
Wall thicknesses up to 0.048 in., incl HR50 drawn and stress-relieved 72 50 12
Wall thicknesses over 0.048 in. HR50 drawn and stress-relieved 72 50 15
C71640 O61 annealed 63 25 . . .
C71640 HR50 drawn and stress relieved 81 58 . . .
C72200 O61 annealed 45 16 . . .
C72200 H55 light-drawn 50 45 . . .
A
ksi = 1000 psi.
B
At 0.5 % extension under load.
B111/B111M − 18a
TABLE 3 Tensile Requirements—SI Values
NOTE 1—See Table 2 for tensile requirements—inch-pound values.
Elongation
Temper Designation
A
Tensile Strength, Yield Strength,
Copper or Copper Alloy UNS No. in 50 mm,
min MPa
min MPa
Code Name
min %
C10100, C10200, C10300, C10800, C12000, C12200, H55 light-drawn 250 205 . . .
C14200
C10100, C10200, C10300, C10800, C12000, C12200, H80 hard-drawn 310 275 . . .
C14200
C15630 O61 annealed 205 55 40
C19200 H55 light-drawn 275 240 . . .
C19200 H80 hard-drawn 330 295 . . .
C19200 O61 annealed 260 85 . . .
C23000 O61 annealed 275 85 . . .
C28000 O61 annealed 345 140 . . .
C44300, C44400, C44500 O61 annealed 310 105 . . .
C60800 O61 annealed 345 130 . . .
C61300, C61400 O61 annealed 480 205 . . .
C68700 O61 annealed 345 125 . . .
C70400 O61 annealed 260 85 . . .
C70400 H55 light-drawn 275 205 . . .
C70600, C70620 O61 annealed 275 105 . . .
C70600, C70620 H55 light-drawn 310 240 . . .
C71000 O61 annealed 310 110 . . .
C71500, C71520 O61 annealed 360 125 . . .
C71500, C71520:
Wall thicknesses up to 1.2 mm incl HR50 drawn and stress-relieved 495 345 12
Wall thicknesses over 1.2 mm. HR50 drawn and stress-relieved 495 345 15
C71640 O61 annealed 435 170 . . .
C71640 HR50 drawn and stress relieved 560 400 . . .
C72200 O61 annealed 310 110 . . .
C72200 H55 light-drawn 345 310 . . .
A
At 0.5 % extension under load.
contract. Tolerances for roundness and length, and the condi- 10.3 Tubes for ferrule stock are not subject to the expansion
tion of straightness, for tube so ordered, shall meet the test.
requirements agreed upon by the manufacturer and the pur-
11. Flattening Test
chaser.
11.1 Test Method—Each test specimen shall be inspected
8. Mechanical Properties
per Test Method B968/B968M.
8.1 Material specified to meet the requirements of the ASME
11.2 During inspection, the flattened areas of the test-
Boiler and Pressure Vessel Code shall have tensile properties
specimen shall be free of defects, but blemishes of a nature that
as prescribed in Table 2 or Table 3.
do not interfere with the intended application are acceptable.
9. Grain Size for Annealed Tempers
11.3 Tubes for ferrule stock are not subject to flattening test.
9.1 Grain size shall be the standard requirement for all
12. Residual Stress Test
product in the annealed (O61) temper.
12.1 A residual stress test, when specified in the purchase
9.1.1 Other than Copper Alloy UNS Nos. C19200 and
order, is required only for Copper Alloy UNS Nos. C23000,
C28000, acceptance or rejection for all annealed products shall
C28000, C44300, C44400, C44500, C60800, C61300,
depend only on average grain size of the test specimen within
C61400, and C68700 and when not supplied in an annealed
the limits of 0.010 to 0.045 mm taken from each of two sample
temper.
portions, and each specimen shall be within the limits pre-
scribed herein when determined in accordance with Test
12.2 Unless otherwise specified, the producer shall have the
Methods E112.
option of testing the product to either the mercurous nitrate
test, Test Method B154, or the ammonia vapor test, Test
10. Performance Requirements
Method B858, as prescribed below.
10.1 Expansion Test:
12.2.1 Mercurous Nitrate Test:
10.1.1 Tube specimens selected for test shall withstand the
12.2.1.1 Warning—Mercury is a definite health hazard and
expansion shown in Table 4 when expanded in accordance with
therefore equipment for the detection and removal of mercury
Test Method B153. The expanded tube shall show no cracking
vapor produced in volatilization is recommended. The use of
or rupture visible to the unaided eye.
rubber gloves in testing is advisable.
10.2 Hard-drawn tubes not end annealed are not subject to 12.2.1.2 The test specimens, cut 6 in. [150 mm] in length,
this test. When tubes are specified end annealed, this test is shall withstand without cracking, an immersion in the standard
required and shall be performed on the annealed ends of the mercurous nitrate solution prescribed in Test Method B154.
sampled tubes. The test specimen shall include the finished tube end.
B111/B111M − 18a
TABLE 4 Expansion Requirements
Expansion of Tube Outside
Temper Designation
Copper or Copper Alloy UNS No. Diameter, in Percent of
Code Name
Original Outside Diameter
O61 annealed C15630 40
C19200 30
C23000 20
C28000 15
C44300, C44400, C44500 20
C60800 20
C61300, C61400 20
C68700 20
C70400 30
C70600, C70620 30
C71000 30
C71500, C71520 30
C71640 30
C72200 30
H55 light-drawn C10100, C10200, C10300, C10800, 20
C12000, C12200
C14200 20
C19200 20
C70400 20
C70600, C70620 20
C72200 20
HR50 drawn and stress relieved C71500, C71520 20
C71640 20
. . . hard-drawn and end annealed C10100, C10200, C10300, C10800, 30
C12000, C12200, C14200
TABLE 5 Notch Depth—Inch-Pound Values
12.2.2 Ammonia Vapor Test:
NOTE 1—See Table 6 for notch depth—SI values.
12.2.2.1 The test specimens, cut 6 in. [150 mm] in length,
Tube Outside Diameter, in.
shall withstand without cracking, the ammonia vapor test as
Tube Wall
Over 1 ⁄4
prescribed in Test Method B858. For the purposes of this
Thickness, 1 3 3 1
Over ⁄4 to ⁄4, Over ⁄4 to 1 ⁄4,
to 3 ⁄8,
in.
specification, unless otherwise agreed between purchaser and incl incl
incl
supplier, the risk level identified in the Annex of Method B858,
Over 0.017–0.032 0.005 0.006 0.007
shall be specified as risk level (pH value) of 10.
Incl 0.032–0.049 0.006 0.006 0.0075
Incl 0.049–0.083 0.007 0.0075 0.008
Incl 0.083–0.109 0.0075 0.0085 0.0095
13. Nondestructive Testing
Incl 0.109–0.120 0.009 0.009 0.011
13.1 Each tube shall be subjected to the eddy-current test in
13.1.1. Tubes may be tested in the final drawn, annealed, or
heat-treated temper or in the drawn temper before the final TABLE 6 Notch Depth—SI Values
anneal or heat treatment unless otherwise agreed upon by the
NOTE 1—See Table 5 for notch depth—inch-pound values.
supplier and the purchaser. The purchaser may specify either of
Tube Outside Diameter, mm
the tests in 13.1.2 or 13.1.3 as an alternative to the eddy-current Tube Wall
Over 32 to
Thickness,
Over 6 to 19, Over 19 to 32,
test.
80,
mm
incl incl
13.1.1 Eddy-Current Test—Each tube shall be passed incl
through an eddy-current testing unit adjusted to provide
Over 0.4–0.8 0.13 0.15 0.18
Incl 0.8–1.3 0.15 0.15 0.19
information on the suitability of the tube for the intended
Incl 1.3–2.1 0.18 0.19 0.20
application. Testing shall follow the procedures of Practice
Incl 2.1–2.8 0.19 0.22 0.24
E243. Incl 2.8–3.0 0.23 0.23 0.28
13.1.1.1 The depth of the round-bottom transverse notches
or the diameters of the drilled holes in the calibrating tube used
to adjust the sensitivity of the test unit are shown in Tables 5 irrelevant signals because of visible and identifiable handling
and 6, and Tables 7 and 8, respectively. Notches of less depth marks may be retested by the hydrostatic test prescribed in
and smaller diameter drilled holes are acceptable to meet this 13.1.2, or the pneumatic test prescribed in 13.1.3. Tubes
requirement. meeting requirements of either test shall be considered to
13.1.1.2 Tubes that d
...


This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: B111/B111M − 18 B111/B111M − 18a
Standard Specification for
Copper and Copper-Alloy Seamless Condenser Tubes and
Ferrule Stock
This standard is issued under the fixed designation B111/B111M; the number immediately following the designation indicates the year
of original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval.
A superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope*
1.1 This specification establishes the requirements for seamless tube and ferrule stock of copper and various copper alloys up
to 3 ⁄8 in. [80 mm] inclusive, in diameter, for use in surface condensers, evaporators, and heat exchangers. The following coppers
and copper alloys are specified:
Copper or Copper Previously Used
Description
Alloy UNS No. Designation
C10100 OFE Oxygen-free electronic
A
C10200 OF Oxygen-free without residual deoxidants
C10300 . . . Oxygen-free, extra low phosphorus
C10800 . . . Oxygen-free, low phosphorus
A
C12000 DLP Phosphorized, low residual phosphorus
A
C12200 DHP Phosphorized, high residual phosphorus
A
C14200 DPA Phosphorized, arsenical
C15630 . . . Nickel Phosphorus
C19200 . . . Phosphorized, 1 % iron
C23000 . . . Red Brass
C28000 . . . Muntz Metal
C44300 . . . Admiralty Metals, B, C, and D
C44400 . . . . . .
C44500 . . . . . .
C60800 . . . Aluminum Bronze
C61300 . . . . . .
C61400 . . . Aluminum Bronze, D
C68700 . . . Aluminum Brass, B
C70400 . . . 95-5 Copper-Nickel
C70600 . . . 90-10 Copper-Nickel
C70620 . . . 90-10 Copper-Nickel—Welding Grade
C71000 . . . 80-20 Copper-Nickel
C71500 . . . 70-30 Copper-Nickel
C71520 . . . 70-30 Copper-Nickel—Welding Grade
Copper or Copper Previously Used
Description
Alloy UNS No. Designation
C71640 . . . Copper-nickel-iron-manganese
C72200 . . . . . .
A
Designations listed in Classification B224.
1.2 Units—The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated
in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values
from the two systems may result in non-conformance with the standard.
This specification is under the jurisdiction of ASTM Committee B05 on Copper and Copper Alloys and is the direct responsibility of Subcommittee B05.04 on Pipe and
Tube.
Current edition approved March 1, 2018Oct. 1, 2018. Published April 2018October 2018. Originally approved in 1937. Last previous edition approved in 20162018 as
B111/B111M–16.–18. DOI: 10.1520/B0111_B0111M-18.10.1520/B0111_B0111M–18A.
For ASME Boiler and Pressure Vessel Code applications, see related Specification SB-111 in Section II of the Code.
The UNS system for copper and copper alloys (see Practice E527) is a simple expansion of the former standard designation system accomplished by the addition of a
prefix “C” and a suffix “00.” The suffix can be used to accommodate composition variations of the base alloy.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
B111/B111M − 18a
1.3 The following safety hazards caveat pertains only to the test methods portion, Section 19, of this specification: This standard
does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this
standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory
limitations prior to use. (Warning—Mercury has been designated by many regulatory agencies as a hazardous substance that can
cause serious medical issues. Mercury, or its vapor, has been demonstrated to be hazardous to health and corrosive to materials.
Caution should be taken Use caution when handling mercury and mercury containing mercury-containing products. See the
applicable product Safety Data Sheet (SDS) for additional information. Users should be aware The potential exists that selling
mercury and/or mercury containing products in your state or country may be prohibited by law.or mercury-containing products,
or both, is prohibited by local or national law. Users must determine legality of sales in their location.)
1.4 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents
2.1 The following documents in the current issue of the Annual Book of ASTM Standardsform form a part of this specification
to the extent referenced herein:
2.2 ASTM Standards:
B153 Test Method for Expansion (Pin Test) of Copper and Copper-Alloy Pipe and Tubing
B154 Test Method for Mercurous Nitrate Test for Copper Alloys
B170 Specification for Oxygen-Free Electrolytic Copper—Refinery Shapes
B224 Classification of Coppers
B846 Terminology for Copper and Copper Alloys
B858 Test Method for Ammonia Vapor Test for Determining Susceptibility to Stress Corrosion Cracking in Copper Alloys
B968/B968M Test Method for Flattening of Copper and Copper-Alloy Pipe and Tube
E8/E8M Test Methods for Tension Testing of Metallic Materials
E29 Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
E53 Test Method for Determination of Copper in Unalloyed Copper by Gravimetry
E54 Test Methods for Chemical Analysis of Special Brasses and Bronzes (Withdrawn 2002)
E62 Test Methods for Chemical Analysis of Copper and Copper Alloys (Photometric Methods) (Withdrawn 2010)
E75 Test Methods for Chemical Analysis of Copper-Nickel and Copper-Nickel-Zinc Alloys (Withdrawn 2010)
E76 Test Methods for Chemical Analysis of Nickel-Copper Alloys (Withdrawn 2003)
E112 Test Methods for Determining Average Grain Size
E118 Test Methods for Chemical Analysis of Copper-Chromium Alloys (Withdrawn 2010)
E243 Practice for Electromagnetic (Eddy Current) Examination of Copper and Copper-Alloy Tubes
E255 Practice for Sampling Copper and Copper Alloys for the Determination of Chemical Composition
E478 Test Methods for Chemical Analysis of Copper Alloys
E527 Practice for Numbering Metals and Alloys in the Unified Numbering System (UNS)
E2575 Standard Test Method for Determination of Oxygen in Copper and Copper Alloys (Withdrawn 2017)
3. Terminology
3.1 Definitions:
3.1.1 For definitions of terms relating to copper and copper alloys, refer to Terminology B846.
4. Ordering Information
4.1 Include the following specified choices when placing orders for product under this specification, as applicable:
4.1.1 ASTM Designation and year of issue;
4.1.2 Copper or Copper Alloy UNS No. Designation (see Table 1);
4.1.3 Temper (Section 7);
4.1.4 Dimensions, outside diameter, and wall thickness, whether minimum or nominal (Section 14);
4.1.5 How furnished (tube or ferrule stock);
4.1.6 Quantity—total weight or total length or number of pieces of each size; and
4.1.7 Intended application.
4.2 The following options are available but may not be included unless specified at the time of placing of the order when
required:
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
The last approved version of this historical standard is referenced on www.astm.org.
B111/B111M − 18a
TABLE 1 Chemical Requirements
Composition, %
Copper or
Copper
Nickel, Other
Lead,
Alloy UNS
Copper Tin Aluminum incl Iron Zinc Manganese Arsenic Antimony Phosphorus Chromium Named
max
No.
Cobalt Elements
A B C
C10100 99.99 min 0.0002 max . . . 0.0010 max 0.0005 max 0.0010 max 0.0001 0.00005 max 0.0005 0.0004 max 0.0003 max 0.0001 max
max max
C D C
C10200 99.95 min . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
D
C10300 99.95 min . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.001–0.005 . . . . . .
D
C10800 99.95 min . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.005–0.012 . . . . . .
E D
C12000 99.90 min . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.004–0.012 . . . . . .
D
C12200 99.9 min . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.015–0.040 . . . . . .
D
C14200 99.4 min . . . . . . . . . . . . . . . . . . . . . 0.15–0.50 . . . 0.015–0.040 . . . . . .
B
C15630 remainder . . . . . . 0.60–0.90 . . . . . . . . . . . . . . . . . . 0.015–0.040 . . . . . .
C19200 98.5 min . . . . . . . . . . . . 0.8–1.2 0.20 max . . . . . . . . . 0.01–0.04 . . . . . .
C23000 84.0–86.0 . . . . . . . . . 0.05 0.05 max remainder . . . . . . . . . . . . . . . . . .
C28000 59.0–63.0 . . . . . . . . . 0.09 0.07 max remainder . . . . . . . . . . . . . . . . . .
C44300 70.0–73.0 0.9–1.2 . . . . . . 0.07 0.06 max remainder . . . 0.02–0.06 . . . . . . . . . . . .
C44400 70.0–73.0 0.9–1.2 . . . . . . 0.07 0.06 max remainder . . . . . . 0.02–0.10 . . . . . . . . .
C44500 70.0–73.0 0.9–1.2 . . . . . . 0.07 0.06 max remainder . . . . . . . . . 0.02–0.10 . . . . . .
D
C60800 remainder . . . 5.0–6.5 . . . 0.10 0.10 max . . . . . . 0.02–0.35 . . . . . . . . . . . .
D F, G
C61300 remainder 0.20–0.50 6.0–7.5 0.15 max 0.01 2.0–3.0 0.10 max 0.20 max . . . . . . 0.015 max . . .
D
C61400 remainder . . . 6.0–8.0 . . . 0.01 1.5–3.5 0.20 max 1.0 max . . . . . . 0.015 max . . . . . .
D
C68700 76.0–79.0 . . . 1.8–2.5 . . . 0.07 0.06 max remainder . . . 0.02–0.06 . . . . . . . . . . . .
D
C70400 remainder . . . . . . 4.8–6.2 0.05 1.3–1.7 1.0 max 0.30–0.8 . . . . . . . . . . . . . . .
D
C70600 remainder . . . . . . 9.0–11.0 0.05 1.0–1.8 1.0 max 1.0 max . . . . . . . . . . . . . . .
D
C70620 86.5 min . . . . . . 9.0-11.0 0.02 1.0-1.8 0.50 max 1.0 max . . . . . . 0.02 max . . . C.05 max
S.02 max
D H H H H
C71000 remainder . . . . . . 19.0–23.0 0.05 0.50–1.0 1.0 max 1.0 max . . . . . . . . .
D
C71500 remainder . . . . . . 29.0–33.0 0.05 0.40–1.0 1.0 max 1.0 max . . . . . . . . . . . . . . .
D
C71520 65.0 min . . . . . . 29.0-33.0 0.02 0.40-1.0 0.50 max 1.0 max . . . . . . 0.02 max . . . C.05 max
S.02 max
D H H H
C71640 remainder . . . . . . 29.0–32.0 0.05 1.7–2.3 1.0 max 1.5–2.5 . . . . . . . . . C.06 max
S.03
H
max
D H H H
C72200 remainder . . . . . . 15.0–18.0 0.05 0.50–1.0 1.0 max 1.0 max . . . . . . 0.30–0.70 Si.03
max
Ti.03
H
max
A
This value is exclusive of silver and shall be determined by difference of “impurity total” from 100 %. “Impurity total” is defined as the sum of sulfur, silver, lead, tin, bismuth, arsenic, antimony, iron, nickel, mercury, zinc,
phosphorus, selenium, tellurium, manganese, cadmium, and oxygen present in the sample.
B
Not including Cobalt.
C
Additional impurity maximums in percent for alloy C10100 shall be: bismuth 0.0001, cadmium 0.0001, oxygen 0.0005, selenium 0.0003, sulfur 0.0015, tellurium 0.0002, mercury 0.0001. For C10200, oxygen should
be 0.0010 max.
D
Copper (including silver).
E
This includes oxygen-free Cu which contains P in an amount agreed upon.
F
Silicon shall be 0.10 % max.
G
When the product is for subsequent welding applications and is so specified by the purchaser, chromium shall be 0.05 % max, cadmium 0.05 % max, zinc 0.05 % max, and zirconium 0.05 % max.
H
When the product is for subsequent welding applications, and so specified by the purchaser, zinc shall be 0.50 % max, lead 0.02 % max, phosphorus 0.02 % max, sulfur 0.02 % max, and carbon 0.05 % max.

B111/B111M − 18a
4.2.1 Tension Test per ASME Boiler and Pressure Vessel Code (see Section 8).
4.2.2 Hydrostatic or pneumatic test as an alternative to eddy current test (Section 13).
4.2.3 If the cut ends of the tubes do not need to be deburred (Section 15).
4.2.4 If the product is to be subsequently welded (Table 1, Footnotes G and H).
4.2.5 Residual Stress Test—Ammonia Vapor Test or Mercurous Nitrate Test (Section 12).
4.2.6 For Ammonia Vapor Test, risk level (pH value) if other than 10.
4.2.7 Heat identification or traceability details.
4.2.8 Certification (Section 23).
4.2.9 Test Report (Section 24).
4.2.10 If a subsequent thermal treatment after straightening is required (Section 7).
4.2.11 If product is purchased for agencies of the U.S. Government (see Supplementary Requirements section of this
specification for additional requirements, if required).
5. Materials and Manufacture
5.1 Materials:
5.1.1 The material of manufacture shall be a form of such purity and soundness as to be suitable for processing into the products
prescribed herein.
5.1.2 When specified in the contract or purchase order that heat identification or traceability is required, the purchaser shall
specify the details desired.
5.2 Manufacture:
5.2.1 The product shall be manufactured by such hot-working, cold-working, annealing, straightening, trimming, and other
processes as to produce a uniform seamless tube in the finished product.
5.2.2 The product shall be hot- or cold-worked to the finished size, and subsequently annealed, when required, to meet the
temper properties specified.
6. Chemical Composition
6.1 The product shall conform to the chemical composition requirements specified in Table 1.
6.2 These composition limits do not preclude the presence of other elements. By agreement between the manufacturer and
purchaser, limits may be established and analysis required for unnamed elements.
6.2.1 Copper Alloy UNS No. C19200—Copper is the difference between the sum results of all the elements determined and
100 %. When all the elements in Table 1 are determined, their sum shall be 99.8 % minimum.
Due to the discontinuous nature of the processing of castings into wrought products, it is not always practical to identify a specific casting analysis with a specific quantity
of finished material.
B111/B111M − 18a
6.2.2 For alloys in which copper is listed as “remainder,” copper is the difference between the sum results of all the elements
determined and 100 %. When all elements in Table 1 are determined, the sum of the results shall be as follows:
Copper Plus Named
Copper Alloy UNS No.
Elements, % min
C15630 99.5
C60800 99.5
C61300 99.8
C61400 99.5
C70400 99.5
C70600 & C70620 99.5
C71000 99.5
C71500 & C71520 99.5
C71640 99.5
C72200 99.8
6.2.3 For alloys in which zinc is listed as the remainder, either copper or zinc may be taken as the difference between the sum
of all the elements determined and 100 %. When all elements in Table 1 are determined, the sum of the results shall be as follows:
Copper Plus Named
Copper Alloy UNS No.
Elements, % min
C23000 99.8
C28000 99.7
C44300 99.6
C44400 99.6
C44500 99.6
C68700 99.5
7. Temper
7.1 Tubes shall be furnished in the temper designations identified in Tables 2 and 3.
7.1.1 Drawn tempers H55 and H80.
7.1.2 Annealed temper O61.
7.1.3 Drawn and stress-relieved temper HR50.
7.2 Tubes for ferrule stock shall be annealed sufficiently to be fully recrystallized.
7.3 Optional Post-Straightening Thermal Treatment—Some tubes, when subjected to aggressive environments, may have the
potential for stress-corrosion cracking failure due to the residual stresses induced during straightening processing. For such
TABLE 2 Tensile Requirements—Inch-Pound Values
NOTE 1—See Table 3 for tensile requirements—SI values.
Elongation
Temper Designation
B
Tensile Strength,
Yield Strength,
Copper or Copper Alloy UNS No. in 2 in.,
A
A
min ksi min ksi
Code Name
min %
C10100, C10200, C10300, C10800, C12000, C12200, H55 light-drawn 36 30 . . .
C14200
C10100, C10200, C10300, C10800, C12000, C12200, H80 hard-drawn 45 40 . . .
C14200
C15630 O61 annealed 30 8 40
C19200 H55 light-drawn 40 35 . . .
C19200 H80 hard-drawn 48 43 . . .
C19200 O61 annealed 38 12 . . .
C23000 O61 annealed 40 12 . . .
C28000 O61 annealed 50 20 . . .
C44300, C44400, C44500 O61 annealed 45 15 . . .
C60800 O61 annealed 50 19 . . .
C61300, C61400 O61 annealed 70 30 . . .
C68700 O61 annealed 50 18 . . .
C70400 O61 annealed 38 12 . . .
C70400 H55 light-drawn 40 30 . . .
C70600, C70620 O61 annealed 40 15 . . .
C70600, C70620 H55 light-drawn 45 35 . . .
C71000 O61 annealed 45 16 . . .
C71500, C71520 O61 annealed 52 18 . . .
C71500, C71520
Wall thicknesses up to 0.048 in., incl HR50 drawn and stress-relieved 72 50 12
Wall thicknesses over 0.048 in. HR50 drawn and stress-relieved 72 50 15
C71640 O61 annealed 63 25 . . .
C71640 HR50 drawn and stress relieved 81 58 . . .
C72200 O61 annealed 45 16 . . .
C72200 H55 light-drawn 50 45 . . .
A
ksi = 1000 psi.
B
At 0.5 % extension under load.
B111/B111M − 18a
TABLE 3 Tensile Requirements—SI Values
NOTE 1—See Table 2 for tensile requirements—inch-pound values.
Elongation
Temper Designation
A
Tensile Strength, Yield Strength,
Copper or Copper Alloy UNS No. in 50 mm,
min MPa
min MPa
Code Name
min %
C10100, C10200, C10300, C10800, C12000, C12200, H55 light-drawn 250 205 . . .
C14200
C10100, C10200, C10300, C10800, C12000, C12200, H80 hard-drawn 310 275 . . .
C14200
C15630 O61 annealed 205 55 40
C19200 H55 light-drawn 275 240 . . .
C19200 H80 hard-drawn 330 295 . . .
C19200 O61 annealed 260 85 . . .
C23000 O61 annealed 275 85 . . .
C28000 O61 annealed 345 140 . . .
C44300, C44400, C44500 O61 annealed 310 105 . . .
C60800 O61 annealed 345 130 . . .
C61300, C61400 O61 annealed 480 205 . . .
C68700 O61 annealed 345 125 . . .
C70400 O61 annealed 260 85 . . .
C70400 H55 light-drawn 275 205 . . .
C70600, C70620 O61 annealed 275 105 . . .
C70600, C70620 H55 light-drawn 310 240 . . .
C71000 O61 annealed 310 110 . . .
C71500, C71520 O61 annealed 360 125 . . .
C71500, C71520:
Wall thicknesses up to 1.2 mm incl HR50 drawn and stress-relieved 495 345 12
Wall thicknesses over 1.2 mm. HR50 drawn and stress-relieved 495 345 15
C71640 O61 annealed 435 170 . . .
C71640 HR50 drawn and stress relieved 560 400 . . .
C72200 O61 annealed 310 110 . . .
C72200 H55 light-drawn 345 310 . . .
A
At 0.5 % extension under load.
applications, it is suggested that tubes of Copper Alloy UNS Nos. C23000, C28000, C44300, C44400, C44500, C60800, C61300,
C61400, and C68700 be subjected to a stress-relieving thermal treatment subsequent to straightening. If required, this must be
specified on the purchase order or contract. Tolerances for roundness and length, and the condition of straightness, for tube so
ordered, shall meet the requirements agreed upon by the manufacturer and the purchaser.
8. Mechanical Properties
8.1 Material specified to meet the requirements of the ASME Boiler and Pressure Vessel Code shall have tensile properties as
prescribed in Table 2 or Table 3.
9. Grain Size for Annealed Tempers
9.1 Grain size shall be the standard requirement for all product in the annealed (O61) temper.
B111/B111M − 18a
9.1.1 Other than Copper Alloy UNS Nos. C19200 and C28000, acceptance or rejection for all annealed products shall depend
only on average grain size of the test specimen within the limits of 0.010 to 0.045 mm taken from each of two sample portions,
and each specimen shall be within the limits prescribed herein when determined in accordance with Test Methods E112.
10. Performance Requirements
10.1 Expansion Test:
10.1.1 Tube specimens selected for test shall withstand the expansion shown in Table 4 when expanded in accordance with Test
Method B153. The expanded tube shall show no cracking or rupture visible to the unaided eye.
10.2 Hard-drawn tubes not end annealed are not subject to this test. When tubes are specified end annealed, this test is required
and shall be performed on the annealed ends of the sampled tubes.
10.3 Tubes for ferrule stock are not subject to the expansion test.
11. Flattening Test
11.1 Test Method—Each test specimen shall be inspected per Test Method B968/B968M.
11.2 During inspection, the flattened areas of the test-specimen shall be free of defects, but blemishes of a nature that do not
interfere with the intended application are acceptable.
11.3 Tubes for ferrule stock are not subject to flattening test.
12. Residual Stress Test
12.1 A residual stress test, when specified in the purchase order, is required only for Copper Alloy UNS Nos. C23000, C28000,
C44300, C44400, C44500, C60800, C61300, C61400, and C68700 and when not supplied in an annealed temper.
12.2 Unless otherwise specified, the producer shall have the option of testing the product to either the mercurous nitrate test,
Test Method B154, or the ammonia vapor test, Test Method B858, as prescribed below.
12.2.1 Mercurous Nitrate Test:
12.2.1.1 Warning—Mercury is a definite health hazard and therefore equipment for the detection and removal of mercury vapor
produced in volatilization is recommended. The use of rubber gloves in testing is advisable.
12.2.1.2 The test specimens, cut 6 in. [150 mm] in length, shall withstand without cracking, an immersion in the standard
mercurous nitrate solution prescribed in Test Method B154. The test specimen shall include the finished tube end.
12.2.2 Ammonia Vapor Test:
TABLE 4 Expansion Requirements
Expansion of Tube Outside
Temper Designation
Copper or Copper Alloy UNS No. Diameter, in Percent of
Code Name
Original Outside Diameter
O61 annealed C19200 30
O61 annealed C15630 40
C19200 30
C23000 20
C28000 15
C44300, C44400, C44500 20
C60800 20
C61300, C61400 20
C68700 20
C70400 30
C70600, C70620 30
C71000 30
C71500, C71520 30
C71640 30
C72200 30
H55 light-drawn C10100, C10200, C10300, C10800, 20
C12000, C12200
C14200 20
C19200 20
C70400 20
C70600, C70620 20
C72200 20
HR50 drawn and stress relieved C71500, C71520 20
C71640 20
. . . hard-drawn and end annealed C10100, C10200, C10300, C10800, 30
C12000, C12200, C14200
B111/B111M − 18a
12.2.2.1 The test specimens, cut 6 in. [150 mm] in length, shall withstand without cracking, the ammonia vapor test as
prescribed in Test Method B858. For the purposes of this specification, unless otherwise agreed between purchaser and supplier,
the risk level identified in the Annex of Method B858, shall be specified as risk level (pH value) of 10.
13. Nondestructive Testing
13.1 Each tube shall be subjected to the eddy-current test in 13.1.1. Tubes may be tested in the final drawn, annealed, or
heat-treated temper or in the drawn temper before the final anneal or heat treatment unless otherwise agreed upon by the supplier
and the purchaser. The purchaser may specify either of the tests in 13.1.2 or 13.1.3 as an alternative to the eddy-current test.
13.1.1 Eddy-Current Test—Each tube shall be passed through an eddy-current testing unit adjusted to provide information on
the suitability of the tube for the intended application. Testing shall follow the procedures of Practice E243.
13.1.1.1 The depth of the round-bottom transverse notches or the diameters of the drilled holes in the calibrating tube used to
adjust the sensitivity of the test unit are shown in Tables 5 and 6, and Tables 7 and 8, respectively. Notches of less depth and smaller
diameter drilled holes are acceptable to meet this requirement.
13.1.1.2 Tubes that do not actuate the signaling device of the eddy-current tester shall be considered to conform to the
requirements of this test. Tubes causing irrelevant signals because of moisture, soil, and like effects may be reconditioned and
retested. Such tubes, when retested to the original test parameters, shall be considered to conform if they do not cause output
signals beyond the acceptable limits. Tubes causing irrelevant signals because of visible and identifiable handling marks may be
retested by the hydrostatic test prescribed in 13.1.2, or the pneumatic test prescribed in 13.1.3. Tubes meeting requirements of
either test shall be considered to conform if the tube dimensions are within the prescribed limits, unless otherwise agreed upon
between the manufacturer and the purchaser.
13.1.2 Hydrostatic Test—Each tube shall stand, without showing evidence of leakage, an internal hydrostatic pressure sufficient
to subject the material to a fiber stress of 7000 psi [48 MPa] as determined by the fol
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